Research on the Inorganic Composite Membrane Catalyst by the Sol-gel Process

Abstract

Abstract: Fe-Si-O and Mo-O sols were prepared by sol-gel process by using Si(OC₂H₅)₄ (TEOS), Fe(NO₃)₃·9H₂O and (NH₄)₆·Mo₇O₂₄·4H₂O.
The Fe-Si-O membrane(on the microscope slide) and Mo-Fe-Si-O membrane (on the α-Al₂O₃ support) were obtained by diploid-circle-
dipping-coating. The effect of process conditions on the Fe-Si-O membrane and the influence of thermal treatment process on the Mo-Fe-Si-O membrane were studied
by DTA, XRD and SEM technique. The results indicated that the major factors affecting the Fe-Si-O membrane were sol viscosity, substrates,
dipping-coating time, withdrawal speed etc, and Mo-Fe-Si-O/α-Al₂O₃ membrane obtained by sol-gel method must be sintered at above 650℃
to form perfectly cubic phase structure. The membrane surfaces were crack-free after five times sintering at 700℃-cooling at 25℃
procedures.

Key words: sol-gel, Fe-Si-O sol, Mo-O sol, Mo-Fe-Si-O membrane

CLC Number:

O484

SHENG Mei,ZHU Yi-Qing,WU Ze-Biao,LIN Xi-Ping,LI Hong-Dao. Research on the Inorganic Composite Membrane Catalyst by the Sol-gel Process[J]. Journal of Inorganic Materials.

[1]	SHEN Bin, ZHANG Xu, XIONG Huai, LI Haiyuan, XIE Xinglong. Preparation and Optical Properties of Sol-Gel SiO₂ Antireflective Films [J]. Journal of Inorganic Materials, 2024, 39(5): 525-530.
[2]	DAI Le, LIU Yang, GAO Xuan, WANG Shuhao, SONG Yating, TANG Mingmeng, DMITRY V Karpinsky, LIU Lisha, WANG Yaojin. Self-polarization Achieved by Compositionally Gradient Doping in BiFeO₃ Thin Films [J]. Journal of Inorganic Materials, 2024, 39(1): 99-106.
[3]	JIA Yuna, CAO Xu, JIAO Xiuling, CHEN Dairong. Preparation of Alumina Ceramic Continuous Fibers with Inorganic Acidic Aluminum Sol as Precursor [J]. Journal of Inorganic Materials, 2023, 38(11): 1257-1264.
[4]	MAN Xin, WU Nan, ZHANG Mu, HE Hongliang, SUN Xudong, LI Xiaodong. Lu₂O₃-MgO Nano-powder: Synthesis and Fabrication of Composite Infrared Transparent Ceramics [J]. Journal of Inorganic Materials, 2021, 36(12): 1263-1269.
[5]	YANG Conggang, MI Le, FENG Aihu, YU Yang, SUN Dazhi, YU Yun. Synthesis and Performance of KH-560 Modified SiO₂ Insulation Coating [J]. Journal of Inorganic Materials, 2021, 36(12): 1343-1348.
[6]	ZHU Ben-Bi,ZHANG Wang,ZHANG Zhi-Jian,ZHANG Jian-Zhong,IMRAN Zada,ZHANG Di. Photothermal Enhanced Photocatalytic Properties of Titanium Dioxide (B)/Glass Fiber Cloth [J]. Journal of Inorganic Materials, 2019, 34(9): 961-966.
[7]	Shao-Dan ZHANG, Wei-Wei BAO, Hai-Ping MA. Near-infrared Reflective Pigments Based on Cu ²⁺ and Tb ³⁺ Codoped BaZrO₃: Preparation and Performance [J]. Journal of Inorganic Materials, 2019, 34(6): 599-604.
[8]	LIU Qian, ZHOU Zhen-Zhen. Progress in Activated-synthesis of Si-based Oxynitrides Materials at Low Temperatures [J]. Journal of Inorganic Materials, 2018, 33(2): 129-137.
[9]	ZHAO Hui-Yue, WANG Xiao-Dong, FENG Jian-Bin, LIU Yuan, HUANG Ji-Chen, SHEN Jun. Environmental Stable SiO₂Antireflective Coating Modified via NH₃/HTMS Vapor Phase Treatment [J]. Journal of Inorganic Materials, 2018, 33(11): 1219-1224.
[10]	HE Fei, LI Ya, LUO Jin, FANG Min-Han, HE Xiao-Dong. Development of SiO₂/C and SiC/C Composites Featuring Aerogel Structures [J]. Journal of Inorganic Materials, 2017, 32(5): 449-458.
[11]	LU Shu-Juan, WANG Chang, ZHAO Bo-Wen, WANG Hao, LIU Jing-Bing, YAN Hui. Electrochromic Properties of PEG-modified Tungsten Oxide Thin Films [J]. Journal of Inorganic Materials, 2017, 32(2): 185-190.
[12]	CHEN Ting, ZHA Jian-Rui, ZHANG Xiao-Jun, JIANG Wei-Hui, JIANG Wan, LIU Jian-Min, WU Qian. Silane Coupling Agent on Synthesis and Antioxidation Property of Zircon Film [J]. Journal of Inorganic Materials, 2017, 32(11): 1154-1158.
[13]	ZHENG Lei, LI Jin, LIU Hong-Bo. Carbon Aerogels Prepared Based on Sol-Gel Reaction of Cellulose Colloid with AEP and Its Adsorption of Copper Ions in Aqueous Solution [J]. Journal of Inorganic Materials, 2017, 32(11): 1159-1164.
[14]	MA Peng-Fei, LI Ri-Hong, ZHANG Long. Sol-Gel-derived Mesoporous Calcium Aluminum Phosphate Bioactive Glasses with High Surface Area [J]. Journal of Inorganic Materials, 2017, 32(1): 107-112.
[15]	HU Ya-Hua, GU Mu, ZHANG Zhi-Yuan, LIU Xiao-Lin, HUANG Shi-Ming, LIU Bo, ZHANG Juan-Nan. Fabrication and Characterization of Lu₂O₃ Nanowire Arrays by Sol-Gel Template Method Assisted with Ultrasonic Treatment [J]. Journal of Inorganic Materials, 2016, 31(8): 807-811.

Research on the Inorganic Composite Membrane Catalyst by the Sol-gel Process

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments