Hydrothermal Synthesis and Characterization of Flowerlike YBO3∶Eu3+

doi:10.3724/SP.J.1077.2009.01064

Abstract

Abstract: YBO₃∶Eu³⁺ microspheres with flower-like structures were fabricated by a facile hydrothermal method. The composition, structure and morphology of obtained YBO₃∶Eu³⁺ were studied by means of XRD、EDX, HRTEM and SEM. The as-prepared YBO₃∶Eu³⁺ microspheres show hexagonal vaterite phase with the elements of Y, O, B, Eu to be found. The YBO₃ microspheres, with an average diameter of 1-2μm, are composed of nanosheets with thickness of 100nm. The formation mechanism of the flower-like structures is also proposed. The YBO₃∶Eu³⁺ samples have a strong red emission at 612nm and a high R/O ratio under ultraviolet excitation, which indicate lower symmetry of crystal field around Eu³⁺ in such flower-like structures.

Key words: hydrothermal synthesis, YBO₃∶Eu³⁺, photoluminescence, flower-like structure

CLC Number:

TB34

CHEN Ji-Tao,GU Feng,JIANG Hao,SHAO Wei,LI Chun-Zhong. Hydrothermal Synthesis and Characterization of Flowerlike YBO₃∶Eu³⁺[J]. Journal of Inorganic Materials, DOI: 10.3724/SP.J.1077.2009.01064.

References

［1］Xia Y N, Yang P D, Sun Y G, et al. Adv. Mater., 2003, 15(5): 353-389.
［2］Sun Y G, Xia Y N. Science, 2002, 298(5601): 2176-2179.
［3］Gou L F, Murphy C J. Nano Lett., 2003, 3(2): 231-234.
［4］Xu R, Zeng H C. J. Phys. Chem. B, 2003, 107(4): 926-930.
［5］Sun X M, Li Y D. Chem. Commun., 2003, 14: 1768-1769.
［6］Yin Y D, Lu Y, Sun Y G, et al. Nano Lett., 2002, 2(4): 427-430.
［7］Sun Y G, Xia Y N. Adv. Mater., 2002, 14(11): 833-837.
［8］Sun Y G, Yin Y D, Mayers B T, et al. Chem. Mater., 2002, 14(11): 4736-4745.
［9］Kim K N, Jung H K, Park H D. J. Mater. Res., 2002, 17(4): 907-910.
［10］Moine B, Mugnier J, Boyer D, et al. J. Alloy. Compd., 2001, 23(816): 323-324.
［11］Bertrand-Chadeyron G, El-Ghozzi M, Boyer D, et al. J. Alloy. Compd., 2001, 317-318: 183-185.
［12］Bertrand-Chadeyron G, El-Ghozzi M, Mahiou R, et al. J. Solid State Chem., 1997, 148(2): 229-235.
［13］Boyer D, Bertrand-Chadeyron G, Mahiou R, et al. J. Mater. Chem., 1999, 9(1): 211-214.
［14］Ren M, Lin J H, Dong Y, et al. Chem. Mater., 1999, 11(6): 1576-1580.
［15］吴雪艳，洪广言，曾小青，等. 高等学校化学学报， 2000, 21(11): 1658-1660.
［16］Li Y Y, Peng M L, Feng S H. Chin. Chem. Lett., 1996, 7(4): 387-388.
［17］Kim D S, Lee R Y. J. Mater. Sci., 2000, 35(19): 4777-4782.
［18］Jiang X C, Yan C H, Sun L D, et al. J. Solid State Chem., 2003, 175(2): 245-251.
［19］Jiang X C, Sun L D, Feng W, et al. Cryst. Growth Des., 2004, 4(3): 517-520.
［20］Jiang X C, Sun L D, Yan C H. J. Phys. Chem. B, 2004, 108(11): 3387-3390.
［21］Li Z H, Zeng J H, Li Y D. Small, 2007, 3(3): 438-443.
［22］Mullin J W. Crystallization, 3rd ed. Oxford: Butterworth-Heinemaan, 1997.
［23］Zhang J, Lin J. J. Cryst. Growth, 2004, 271(1-5): 207-215.
［24］Feldmann C, Justel T, Ronda C R, et al. J. Lumin., 2001, 92(3): 245-254.
［25］Wei Z G, Sun L D, Liao C S, et al. Appl. Phys. Lett., 2002, 80(8): 1447-1449.

[1]	LI Qianli, LI Naixin, LI Yucheng, LIU Shenye, CHENG Shuai, YANG Guang, REN Kuan, WANG Feng, ZHAO Jingtai. Research Progress of Radio-photoluminescence Materials and Their Applications [J]. Journal of Inorganic Materials, 2023, 38(7): 731-749.
[2]	LIU Qi, ZHU Can, XIE Guizhen, WANG Jun, ZHANG Dongming, SHAO Gangqin. Optical Absorption and Photoluminescence Spectra of Ce-doped SrMgF₄Polycrystalline with Superlattice Structure [J]. Journal of Inorganic Materials, 2022, 37(8): 897-902.
[3]	GUAN Xufeng, LI Guifang, WEI Yunge. Microstructure and Thermal Quenching Characteristics of Na_1-_xM_xCaEu(WO₄)₃ (M=Li, K) Red Phosphor [J]. Journal of Inorganic Materials, 2022, 37(6): 676-682.
[4]	ZHANG Guoqing, QIN Peng, HUANG Fuqiang. Reversible Conversion between Space-confined Lead Ions and Perovskite Nanocrystals for Confidential Information Storage [J]. Journal of Inorganic Materials, 2022, 37(4): 445-451.
[5]	DU Aochen, DU Qiyuan, LIU Xin, YANG Yimin, XIA Chenyang, ZOU Jun, LI Jiang. Ce:YAG Transparent Ceramics Enabling High Luminous Efficacy for High-power LEDs/LDs [J]. Journal of Inorganic Materials, 2021, 36(8): 883-892.
[6]	WANG Tingting, SHI Shumei, LIU Chenyuan, ZHU Wancheng, ZHANG Heng. Synthesis of Hierarchical Porous Nickel Phyllosilicate Microspheres as Efficient Adsorbents for Removal of Basic Fuchsin [J]. Journal of Inorganic Materials, 2021, 36(12): 1330-1336.
[7]	SONG Keke, HUANG Hao, LU Mengjie, YANG Anchun, WENG Jie, DUAN Ke. Hydrothermal Preparation and Characterization of Zn, Si, Mg, Fe Doped Hydroxyapatite [J]. Journal of Inorganic Materials, 2021, 36(10): 1091-1096.
[8]	ZHANG Zhijie,HUANG Hairui,CHENG Kun,GUO Shaoke. High Efficient Carbon Quantum Dots/BiOCl Nanocomposite for Photocatalytic Pollutant Degradation [J]. Journal of Inorganic Materials, 2020, 35(4): 491-496.
[9]	DAI Yan-Nan, YANG Shuai, SHEN Yang, SHAN Yong-Kui, YANG Fan, ZHAO Qing-Biao. Intense Yellow Emission from Gd_0.5-_yTb_1.5RE_yW₃O₁₂ (RE=Eu, Sm) Phosphors Tuned through Full Range Doping [J]. Journal of Inorganic Materials, 2019, 34(11): 1210-1216.
[10]	WANG Shu-Jiang, YANG Yong-Heng, WEN Chun-Yang, ZHANG Guo-Kui, YUAN Chun-Hui. Preparation and Property of Nano-Ag/illite Composite Material [J]. Journal of Inorganic Materials, 2018, 33(5): 570-576.
[11]	JIA Si-Qi, JIANG Zheng, CHI Li-Na, YE Ying, HU Shuang-Shuang. Synthesis and Photoelectrocatalytic Performance of Sb₂S₃ Nanorods from Natural Stibnite [J]. Journal of Inorganic Materials, 2018, 33(11): 1213-1218.
[12]	LI Gui-Fang, YANG Qian, WEI Yun-Ge. Synthesis and Photoluminescence Properties of Double Perovskite NaLaMgWO₆: Eu³⁺Red Phosphor [J]. Journal of Inorganic Materials, 2017, 32(9): 936-942.
[13]	YANG Kun-Kun, YANG Shao-Hua, ZHAO Ping, ZHAO Yan-Long. Hydrothermal Synthesis of FeS₂/Reduced Graphene Oxide Nanocomposite with Enhanced Discharge Performance for Thermal Battery [J]. Journal of Inorganic Materials, 2017, 32(7): 691-698.
[14]	GUO Yu, LI Dong-Xin, WU Hong-Mei, JIN Yu-Jia, ZHOU Li-Dai, CHEN Qiang-Qiang. Preparation, Characterization and Catalytic Performance of Supported Titanium Silicalite-1 Zeolite Membrane Catalyst [J]. Journal of Inorganic Materials, 2017, 32(6): 631-636.
[15]	ABUBAKER Abutartour, LOTFIA El-Majdoub, SHI Ya-Sai, LI Ni-Li, XU Qing-Hong. A New Porous Zirconium Phosphonate Hybride Material and Its Adsorption Properties [J]. Journal of Inorganic Materials, 2017, 32(3): 305-312.

Hydrothermal Synthesis and Characterization of Flowerlike YBO₃∶Eu³⁺

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments