L-半胱氨酸辅助合成AgInS2微球

doi:10.3724/SP.J.1077.2011.11207

无机材料学报 ›› 2011, Vol. 26 ›› Issue (11): 1221-1226.DOI: 10.3724/SP.J.1077.2011.11207 CSTR: 32189.14.SP.J.1077.2011.11207

L-半胱氨酸辅助合成AgInS₂微球

刘海涛¹, 钟家松², 梁晓娟¹, 张景峰¹, 向卫东^1,2

(1. 温州大学化学与材料工程学院, 温州 325035; 2. 同济大学材料科学与工程学院, 上海 200092)

收稿日期:2011-04-06 修回日期:2011-05-07 出版日期:2011-11-20 网络出版日期:2011-11-11
作者简介:LIU Hai-Tao(1963-), male, PhD, associate professor.
基金资助:
National Natural Sciences Foundation of China (50772075, 50972107)

L-cysteine-assisted Synthesis of AgInS₂ Microspheres

LIU Hai-Tao¹, ZHONG Jia-Song², LIANG Xiao-Juan¹, ZHANG Jing-Feng¹, XIANG Wei-Dong^1,2

(1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China; 2. School of Materials Science and Engineering, Tongji University, Shanghai 200092, China)

Received:2011-04-06 Revised:2011-05-07 Published:2011-11-20 Online:2011-11-11
About author:LIU Hai-Tao(1963-), male, PhD, associate professor.
Supported by:
National Natural Sciences Foundation of China (50772075, 50972107)

摘要/Abstract

摘要： 通过简单的生物分子辅助溶剂热法, 成功地合成出了AgInS₂微球. 在反应过程中, 生物分子L-半胱氨酸既作为硫源也作为络合剂. 利用X射线衍射(XRD)、能量色散谱(EDS)、X射线光电子能谱(XPS)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)等分别对所合成的AgInS₂的表面形貌、组成和晶型结构等进行了表征. 结果表明, 所合成的产物为典型的AgInS₂正交结构, 平均直径约为2μm. 讨论了不同温度对AgInS₂的形成及其形貌的影响, 并根据实验结果对所合成的AgInS₂微球可能的形成机理进行了简单的探讨.

关键词: AgInS₂, L-半胱氨酸, 生物分子, 半导体

Abstract: AgInS₂ microspheres were synthesized via a simple solvothermal route using biomolecule L-cysteine-assisted methods. The L-cysteine both as sulfur source and complexing agent plays an important role in the formation of AgInS₂ microspheres. The morphology, structure, and phase composition of the as-prepared AgInS₂ products were studied through X-ray diffraction, field emission scanning electron microscope, energy dispersive X-ray spectroscope, X-ray photoelectron spectroscope, transmission electron microscope, and high-resolution transmission electron microscope. The Results showed that the as-prepared AgInS₂ microspheres were orthorhombic phase with average diameters of about 2 μm. In addition, the effect of reaction temperature on morphology of the product was investigated, and a possible growth mechanism of the AgInS₂ microspheres was also determined based on electron microscope.

Key words: AgInS₂, L-cysteine, biomolecule, semiconductor

中图分类号:

O611
TB383

刘海涛, 钟家松, 梁晓娟, 张景峰, 向卫东. L-半胱氨酸辅助合成AgInS₂微球[J]. 无机材料学报, 2011, 26(11): 1221-1226.

LIU Hai-Tao, ZHONG Jia-Song, LIANG Xiao-Juan, ZHANG Jing-Feng, XIANG Wei-Dong. L-cysteine-assisted Synthesis of AgInS₂ Microspheres[J]. Journal of Inorganic Materials, 2011, 26(11): 1221-1226.

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L-半胱氨酸辅助合成AgInS₂微球

L-cysteine-assisted Synthesis of AgInS₂ Microspheres

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