BIT-层状双金属氢氧化物纳米杂化物的制备及防霉性能研究

doi:10.3724/SP.J.1077.2013.12681

无机材料学报 ›› 2013, Vol. 28 ›› Issue (9): 1025-1032.DOI: 10.3724/SP.J.1077.2013.12681 CSTR: 32189.14.SP.J.1077.2013.12681

BIT-层状双金属氢氧化物纳米杂化物的制备及防霉性能研究

张译轩, 李松梅, 刘建华, 于美

(北京航空航天大学材料科学与工程学院, 空天材料与服役教育部重点实验室, 北京 100191)

收稿日期:2012-11-10 修回日期:2012-12-28 出版日期:2013-09-20 网络出版日期:2013-08-14
作者简介:张译轩(1986-), 女, 硕士研究生. E-mail: 15010981021@163.com
基金资助:
国家航空科学基金(20110251003)

Preparation of BIT-layered Double Hydroxide and the Study of Antifungal Properties

ZHANG Yi-Xuan, LI Song-Mei, LIU Jian-Hua, YU Mei

(Key Laboratory of Aerospace Materials and Performance, Ministry of Education, School of Materials Science and Engineering, Beihang University, Beijing 100191, China)

Received:2012-11-10 Revised:2012-12-28 Published:2013-09-20 Online:2013-08-14
About author:ZHANG Yi-Xuan. E-mail: 15010981021@163.com
Supported by:
National Aviation Science Foundation(20110251003)

摘要/Abstract

摘要： 采用共沉淀法将防霉剂1, 2-苯丙异噻唑啉-3-酮(BIT)成功插入到Mg-Al层状双金属氢氧化物层间(LDH), 合成Mg₂Al-BIT LDHs纳米杂化物。采用X射线衍射、傅里叶红外光谱、扫描电子显微镜进行表征。并在pH=4.8和7.2的介质中研究药物缓释动力学。结果显示BIT成功地插入到了LDH的层间, 载药量为44.35%, 释放动力学过程符合准二级动力学方程。将胶囊型防霉剂添加到醇酸树脂涂层中进行霉菌试验。结果表明Mg₂Al-BIT LDHs在耐耗、溶出、析出方面优于BIT, 后期防霉效果更好。

关键词: 层状双金属氢氧化物, BIT, 缓释, 防霉持久性

Abstract: Mg-Al layered double hydroxides, loaded with 1,2-benzisothiazolin-3-ketone(Mg₂Al-BIT LDH), were synthesized via coprecipitation method. The resulting compounds were characterized by X-ray diffraction, Fourier transform infrared spectroscope and scanning electron microscope. Drug release kinetics were studied in the medium with pH at 4.8 and 7.2. The results showed that BIT was successfully inserted into the LDH inter layers, with a drug loading rate of 44.35%。The release kinetics process was in line with the quasi-second-order equation. The results showed that the antifungal effects of BIT were worse than that of Mg₂Al-BIT LDHs in the final phase of the mold test due to its consumption, dissolution and precipitation, suggesting Mg₂Al-BIT LDHs nano-hybrid a better anti-mildew duration.

Key words: layered double hydroxides, BIT, sustained-release, anti-mildew duration

中图分类号:

TG172

张译轩, 李松梅, 刘建华, 于美. BIT-层状双金属氢氧化物纳米杂化物的制备及防霉性能研究[J]. 无机材料学报, 2013, 28(9): 1025-1032.

ZHANG Yi-Xuan, LI Song-Mei, LIU Jian-Hua, YU Mei. Preparation of BIT-layered Double Hydroxide and the Study of Antifungal Properties[J]. Journal of Inorganic Materials, 2013, 28(9): 1025-1032.

参考文献

[1] Gaylarde C C, Morton L H G, Shirakawa M. A, et al. Biodeterioration of external architectural paint ?lms. International Biodeterioration& Biodegradation, 2011, 65(8): 1189-1198.

[2] Zhao Xiao-yang. Characteristics and mold of aerospace coatings. Aviation Standardization and Quality, 2004, 1: 37-41.

[3] Zheludkevich M L, Shchukin D G, Yasakau K A, et al. Anticorrosion coatings with self-healing effect based on nanocontainers impregnated with corrosion inhibitor. Chemistry of Materials, 2007, 19(3): 402-411.

[4] Morimoto Kazuya, Tamura Kenji, Iyi Nobuo, et al. Adsorption and photodegradation properties of anionic dyes by layered double hydroxides. Journal of Physics and Chemistry of Solids, 2011, 72(9): 1037-1045.

[5] Nyambo Calistor, Chen Dan, Su Shengpei, et al. Does organic modi?cation of layered double hydroxides improve the ?re performance of PMMA? Polymer Degradation and Stability, 2009, 94(8): 1298-1306.

[6] Shen Yanming, Liu Dongbin, Fan Lihui, et al. Simultaneous incorporation of palladium and zirconium ions in Mg-Al layered double hydroxides by co-precipitation. Applied Clay Science, 2011, 54(2): 179-183.

[7] Ai Lunhong, Zhang Chunying, Meng Lanying, et al. Adsorption of methyl orange from aqueous solution on hydrothermal synthesized Mg-Al layered double hydroxid. Journal of Chemic al & Engineering Data, 2011, 56(11): 4217-4225.

[8] Wei Yan-Ping, Wei De-Quan, Gao Hong-Wen. Treatment of dye wastewater by in situ hybridization with Mg–Al layered double hydroxides and reuse of dye sludge. Chemical Engineering Journal, 2011, 172(2/3): 872-878.

[9] Morandi S, Manzoli M, Prinetto F, et al. Supported Ni catalysts prepared by intercalation of layered double hydroxides: investigation of acid-base properties and nature of Ni phases. Microporous and Mesoporous Materials, 2012, 147(1): 178-187.

[10] Xu Zhi Ping, Zhang Jia, Adebajo O, et al. Catalytic applications of layered double hydroxides and derivatives. Applied Clay Science, 2011, 53(2): 139-150.

[11] Furukawa Yoshihiro, Tadanaga Kiyoharu, Hayashi Akitoshi, et al. Evaluation of ionic conductivity for Mg-Al layered double hydroxide intercalated withinorganic anions. Solid State Ionics, 2011, 192(1): 185-187.

[12] Dutta Kingshuk, Das Somnath, Pramanik Amitava. Concomitant synthesis of highly crystalline Zn-Al layered double hydroxideand ZnO: phase interconversion and enhanced photocatalytic activity. Journal of Colloid and Interface Science, 2012, 366(1): 28-36.

[13] Hang To Thi Xuan, Truc Trinh Anh, Duong Nguyen Thuy, et al. Layered double hydroxides as containers of inhibitors in organic coatings for corrosion protection of carbon steel. Progress in Organic Coatings, 2012, 74(2): 343-348.

[14] Huang Shu, Cen Xi, Zhu Hong, et al. Facile preparation of poly(vinyl alcohol) nanocomposites with pristine layered double hydroxides. Materials Chemistry and Physics, 2011, 130(3): 890-896.

[15] Vega J M, Granizo N, de la Fuente D, et al. Corrosion inhibition of aluminum by coatings formulated with Al-Zn-vanadate Hydrotalcite. Progress in Organic Coatings, 2011, 70(4): 213-219.

[16] Li Dandan, Wang Fangyong, Yu Xiang, et al. Anticorrosion organic coating with layered double hydroxide loaded with corrosion inhibitor of tungstate. Progress in Organic Coatings, 2011, 71(3): 302-309.

[17] Zheludkevich M L, Poznyak S K, Rodrigues L M, et al. Active protection coatings with layered double hydroxide nanocontainers of corrosion inhibitor. Corrosion Science, 2010, 52(2): 602-611.

[18] TANG P G, FENG Y J, LI D Q. Fabrication and properties of acid blue 25 dye-intercalated layered double hydroxides ?lm on an anodic alumina/aluminum substrate. Journal of Physics and Chemistry of Solids, 2012, 73(12): 1505-1509.

[19] Poznyak S.K, Tedim J, Rodrigues L.M, et al. Novel inorganic host layered double hydroxides intercalated with guest organic inhibitors for anticorrosion applications. Meterials&Interfaces, 2009, 1(10): 2353-2362.

[20] LIU C X, HOU W G, LI L F, et al. Synthesis and characterization of 5-fluorocytosine intercalated Zn-Al layered double hydroxide. Journal of Solid State Chemistry, 2008, 181(8): 1792-1797．

[21] LI Y H, XU J, ZHANG S J, et al. Synthesis and characterization of floxuridine-layered double hydroxides nanohybrid. Chinese Journal of Inorganic Chemistry, 2009, 25(12): 2124-2128.

BIT-层状双金属氢氧化物纳米杂化物的制备及防霉性能研究

Preparation of BIT-layered Double Hydroxide and the Study of Antifungal Properties

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	郭小炜, 李玉妍, 陈南春, 王秀丽, 解庆林. 负载二甲酸钾缓释抗菌微球的构建[J]. 无机材料学报, 2021, 36(2): 181-187.
[2]	胡丽芳,刘柳,何杰,孙志鹏,陈小平. Ni-Ti-LDHs纳米片对阿司匹林的负载与缓释[J]. 无机材料学报, 2020, 35(2): 165-172.
[3]	黄长兴, 崔骏, 裴元生. B₂O₃-SiO₂-Na₂O缓释材料的合成工艺参数优化及其缓释机理[J]. 无机材料学报, 2019, 34(6): 653-659.
[4]	白家峰, 王希庆, 陈义昌, 邓勇辉, 李志华, 刘鸿, 刘绍华. 聚多巴胺修饰的介孔二氧化硅微球的合成及其用于负载左旋薄荷醇凉味剂[J]. 无机材料学报, 2017, 32(8): 845-850.
[5]	余素春, 喻莹, 戴红莲. 明胶微球/磷酸镁基骨水泥复合药物缓释体系的构建[J]. 无机材料学报, 2017, 32(6): 655-660.
[6]	史蕊蕊, 李萌, 裴元生. B₂O₃-SiO₂-Na₂O缓释抑菌剂的合成及性能表征[J]. 无机材料学报, 2017, 32(5): 529-534.
[7]	鲍艳, 王彤. 中空SiO₂微球的制备及其在缓/控释应用中的新进展[J]. 无机材料学报, 2016, 31(12): 1269-1278.
[8]	朱开平, 王德平, 范宏圆, 王会, 姚爱华, 叶松. 硼酸盐玻璃的原位转化及对浸泡液酸碱度的影响[J]. 无机材料学报, 2015, 30(10): 1069-1074.
[9]	李彦云, 李松梅, 刘建华, 于美. TPN-十二烷基磺酸钠-层状双金属氢氧化物纳米杂化物的制备及防霉性能研究[J]. 无机材料学报, 2014, 29(5): 515-522.
[10]	丁峰, 李楠, 李永生, 施剑林. 介孔生物玻璃/磷酸钙骨水泥多级孔复合支架的制备及其载药特性研究[J]. 无机材料学报, 2013, 28(1): 97-102.
[11]	杜宝中, 邰炜, 骆薇, 彭振国. 别嘌醇插层Zn/Al-NO₃-LDH复合材料的组装及缓释性能[J]. 无机材料学报, 2011, 26(12): 1293-1298.
[12]	刘浩怀, 张建华, 许庆陵, 张利, 李玉宝. 包埋载药微球的羟基磷灰石/聚氨酯复合组织工程支架的研究[J]. 无机材料学报, 2011, 26(10): 1073-1077.
[13]	姚礼峰,石燕,温丽丽,沈强,张联盟. TiO₂/SiO₂复合中空微球的选择性改性与药物缓释性能研究[J]. 无机材料学报, 2010, 15(2): 201-205.
[14]	杨晓玲,姚珂,朱以华. 纳米结构的空腔二氧化硅微球的制备与缓释行为[J]. 无机材料学报, 2005, 20(6): 1403-1408.
[15]	俞波,王芳. 复合金属离子抗菌沸石的制备及研究[J]. 无机材料学报, 2005, 20(4): 921-926.