酸碱处理对磷酸盐激光玻璃表面的侵蚀研究

doi:10.3724/SP.J.1077.2012.00627

无机材料学报 ›› 2012, Vol. 27 ›› Issue (6): 627-632.DOI: 10.3724/SP.J.1077.2012.00627 CSTR: 32189.14.SP.J.1077.2012.00627

酸碱处理对磷酸盐激光玻璃表面的侵蚀研究

张磊^1,2, 黄利^1,2, 丁佳^1,2, 陈辉宇¹, 陈伟¹, 胡丽丽¹

(1. 中国科学院上海光学精密机械研究所, 上海201800; 2. 中国科学院研究生院, 北京100049)

收稿日期:2011-07-13 修回日期:2011-09-28 出版日期:2012-06-20 网络出版日期:2012-05-07
基金资助:
国家高技术研究发展计划(863-804)

Effect of Both Acid and Base Etching on Phosphate Laser Glass Surfaces

ZHANG Lei^{1, 2}, HUANG Li^{1, 2}, DING Jia^1,2, CHEN Hui-Yu¹, CHEN Wei¹, HU Li-Li¹

(1. Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China; 2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China)

Received:2011-07-13 Revised:2011-09-28 Published:2012-06-20 Online:2012-05-07
Supported by:
Hi-Tech Research and Development Program of China(863-804)

摘要/Abstract

摘要： 通过添加重金属钡的酸碱溶液, 在不同外界条件下, 研究了磷酸盐激光玻璃表面结构在酸碱侵蚀过程的反应机理. 结果表明, 酸碱对磷酸盐激光玻璃的侵蚀过程主要包括金属阳离子析出和[PO₄]网络结构破坏等两个重要过程. 金属阳离子的析出主要是非桥氧结构P-O-M(M为K⁺、Ba²⁺、Al³⁺等阳离子)在酸碱作用下生成P-O-H基团, 而[PO₄]网络结构的破坏则是指玻璃网络原有的Q²结构在酸碱的侵蚀下逐渐向Q¹和Q⁰转变. 据此, 推导了磷酸盐激光玻璃在酸碱侵蚀过程中的反应模型.

关键词: 磷酸盐玻璃, 酸碱侵蚀, 拉曼光谱, X射线光电子能谱

Abstract: The effect of chemical etching processes on phosphate laser glass surfaces was investigated. Under different process conditions (e.g. sonication and agitation), conventionally polished and subsequently washed phosphate glass plates were treated by submerging in both HCl and KOH solution either with or without BaCl₂. Subsequently, Raman spectra and X-ray photoelectron spectroscope (XPS) of the treated surfaces were measured. The precipitation of metal cations and depolymerization of the glass network structure are the two main chemical reactions in both solutions: One refers to the substitution of P-O-H for P-O-M, the other is that the Q² tetrahedra, the basic structural unit of the original metaphosphate glass, has gradually been replaced by the Q¹ or Q⁰ tetrahedra. Finally, the reaction models of phosphate laser glasses dissolved in both HCl and KOH solution are proposed.

Key words: phosphate glass, etching, Raman spectra, XPS

中图分类号:

TQ171

张磊, 黄利, 丁佳, 陈辉宇, 陈伟, 胡丽丽. 酸碱处理对磷酸盐激光玻璃表面的侵蚀研究[J]. 无机材料学报, 2012, 27(6): 627-632.

ZHANG Lei, HUANG Li, DING Jia, CHEN Hui-Yu, CHEN Wei, HU Li-Li. Effect of Both Acid and Base Etching on Phosphate Laser Glass Surfaces[J]. Journal of Inorganic Materials, 2012, 27(6): 627-632.

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酸碱处理对磷酸盐激光玻璃表面的侵蚀研究

Effect of Both Acid and Base Etching on Phosphate Laser Glass Surfaces

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