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无机材料学报

无机材料学报 ›› 2011, Vol. 26 ›› Issue (5): 477-480.DOI: 10.3724/SP.J.1077.2011.00477 CSTR: 32189.14.SP.J.1077.2011.00477

• 研究论文 • 上一篇    下一篇

MOD方法制备Y0.5Yb0.5BCO薄膜及其性能研究

吴紫平, 索红莉, 刘 敏, 叶 帅, 徐 燕   

  1. (北京工业大学 材料科学与工程学院, 国家教育部功能材料重点实验室, 北京100124)
  • 收稿日期:2010-07-17 修回日期:2010-09-30 出版日期:2011-05-20 网络出版日期:2011-06-07
  • 作者简介:吴紫平(1985-), 女, 硕士研究生. E-mail: wzpowen@emails.bjut.edu.cn
  • 基金资助:

    国家973计划(2006CB601005); 国家自然科学基金(50802004); 北京市自然科学基金(2092006)

Growth and Property of Y0.5Yb0.5BCO Films Prepared by MOD Method

WU Zi-Ping, SUO Hong-Li, LIU Min, YE Shuai, XU Yan   

  1. (The key Laboratory of Advanced Functional Materials, Ministry of Education, Beijing University of Technology, Beijing 100124, China)
  • Received:2010-07-17 Revised:2010-09-30 Published:2011-05-20 Online:2011-06-07
  • Supported by:

    National Basic Research Program of China (2006CB601005); National Natural Science Foundation of China (50802004); Beijing Municipal Natural Science Foundation (2092006)

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摘要： 采用低氟金属有机物沉积工艺, 通过将浓度相同的YBCO、YbBCO前驱溶液按1: 1的体积比混合, 使元素Yb部分取代Y, 成功制备了Y0.5Yb0.5BCO薄膜. 该薄膜成份单一, 具有很好的双轴织构; 薄膜表面平整致密, 没有裂纹和孔洞, 元素分布均匀. 虽然Yb部分取代Y降低了薄膜的临界转变温度(Tc), 但有效提高了薄膜在高场下的场性能, 如在77K, 3T磁场下, Y0.5Yb0.5BCO薄膜的Jc值提高了1.26倍. 为了进一步改善薄膜在低场下的性能, 通过在Y0.5Yb0.5BCO前驱溶液中再加入6 mol%的TaCl5, 成功地制备了Ta5+掺杂的Y0.5Yb0.5BCO薄膜, 提高了薄膜在整个磁场范围内的载流能力.  

关键词: Y0.5Yb0.5BCO薄膜, 元素替代, 纳米颗粒掺杂, 低氟MOD, 场性能

Abstract: Y0.5Yb0.5BCO film was successfully fabricated by fluorine-reduced metalorganic deposition (MOD) method through mixing the same concentrated YBCO and YbBCO precursor solution with 1:1 volume ratio. The film has strong (00l) peaks and well biaxial texture. The surface of the film is dense without any cracks and pores. Besides, the elemental distribution is well-proportioned. It is found that the Yb elemental substitution improves the in-field properties effectively, especially at high fields, although it decreases the critical transition temperature (Tc) of the Y0.5Yb0.5BCO film. For example, the Jc value of Y0.5Yb0.5BCO film is as higher as 1.26 times than that of the pure YBCO film at 77K and 3T applied field. In order to further improve the property at lower field, 6mol% TaCl5 is added to Y0.5Yb0.5BCO precursor solution to obtain the Ta5+-doped Y0.5Yb0.5BCO film. The current carrying ability of the Ta5+-doped Y0.5Yb0.5BCO film is enhanced within the measured fields.

Key words: Y0.5Yb0.5BCO film, elemental substitution, nanoparticle doping, fluorine-reduced MOD, Field-property

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