Bi2S3 纳米晶掺杂钠硼硅玻璃的三阶非线性光学性质

doi:10.3724/SP.J.1077.2011.00290

无机材料学报 ›› 2011, Vol. 26 ›› Issue (3): 290-294.DOI: 10.3724/SP.J.1077.2011.00290 CSTR: 32189.14.SP.J.1077.2011.00290

Bi₂S₃ 纳米晶掺杂钠硼硅玻璃的三阶非线性光学性质

杨昕宇¹,², 向卫东¹,², 赵海军², 张希艳¹, 梁晓娟², 刘海涛²

1. 长春理工大学材料科学与工程学院,长春130022; 2. 温州大学化学与材料工程学院, 温州325035

收稿日期:2010-06-01 修回日期:2010-07-13 出版日期:2011-03-20 网络出版日期:2011-02-18
作者简介:杨昕宇(1978-), 男, 博士研究生, 助理研究员.
基金资助:
国家自然科学基金(50772075, 50972107); 浙江省自然科学基金(Y4100233); 浙江省教育厅项目(Y200804258); 浙江省科技创新团队项目(2009R50010)

Third-order Nonlinear Optical Properties of Bi₂S₃ Nanocrystals Embedded inSodium Borosilicate Glass

YANG Xin-Yu¹,² , XIANG Wei-Dong¹,² , ZHAO Hai-Jun²,ZHANG Xi-Yan¹, LIANG Xiao-Juan², LIU Hai-Tao²

1. College of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022,China; 2. College of Chemistry and Materials Engineering, WenzhouUniversity, Wenzhou 325035, China

Received:2010-06-01 Revised:2010-07-13 Published:2011-03-20 Online:2011-02-18
Supported by:
National Nature Science Foundation of China (50772075,50972107); Natural Science Foundation of Zhejiang Province (Y4100233); Zhejiang Province Education Foundation of China(Y200804258); Zhejiang Province Key Scientific and Technological InnovationsTeam of China (2009R50010)

摘要/Abstract

摘要： 利用溶胶-凝胶方法制备了1 wt% Bi₂S₃纳米晶掺杂钠硼硅玻璃. 利用X射线粉末衍射仪(XRD), X射线光电子能谱(XPS), 透射电子显微镜(TEM), X射线能量色散谱(EDX), 扫描模式透射电子显微镜(STEM)以及高分辨透射电子显微镜(HRTEM)对Bi₂S₃纳米晶在钠硼硅玻璃中的形貌和微结构进行了表征, 同时, 利用飞秒 Z 扫描技术在波长为770 nm对该玻璃的三阶非线性光学性能进行了分析测试. 结果表明, 尺寸为10~30 nm的Bi₂S₃正交晶系纳米晶在钠硼硅玻璃中形成, 该玻璃的三阶非线性光学折射率 γ 、三阶非线性吸收率 β 和三阶非线性极化率 χ ⁽³⁾分别为5.90×10 ^-¹⁶m²/W、7.35×10 ^-⁹m/W 和4.55×10 ^-¹⁸m²/V².其中, 该玻璃的三阶非线性极化率值比未经掺杂的钠硼硅玻璃(χ⁽³⁾=1.09×10 ^-²²m²/V²)高出4个数量级, 这表明, 随着Bi₂S₃纳米晶的引入, 该玻璃的三阶非线性光学性能将得到显著的提高.

关键词: Bi₂S₃纳米晶, 钠硼硅玻璃, 溶胶-凝胶, 三阶光学非线性性质

Abstract: Bi₂S₃nanocrystals( 1wt%) embedded in sodium borosilicate glass were synthesized through Sol-Gel process. The morphology and microstructure of Bi₂S₃nanocrystals in sodium borosilicate glass were characterized by means of X-ray powder diffraction (XRD), X-rayphotoelectron spectroscope (XPS), transmission electron microscope (TEM),energy dispersion X-ray spectra (EDX), scanning transmission electronmicroscope (STEM) and high-resolutions TEM (HRTEM). Furthermore, the third-order nonlinear optical properties of the glass were measured by femtosecondZ -scan technique at a wavelength of 770 nm. The results show that the size of Bi₂S₃nanocrystals in sodium borosilicate glass usually ranges from 10 to 30 nm, and the Bi₂S₃ nanocrystals are determined to be of the orthorhombic phase. The third-order nonlinear optical refractive index γ, absorption coefficient β and susceptibility χ⁽³⁾ of the glass are determined to be 5.90×10 ^-¹⁶m²/W, 7.35×10 ^-⁹m/W and 4.55×10 ^-¹⁸m²/V², respectively. There into, the third-order optical nonlinear susceptibility χ⁽³⁾ of the glass is four orders of magnitude greaterthan un-doped glass (χ⁽³⁾= 1.09×10 ^-²²m²/V²). It is clear that the third-order nonlinearoptical properties of the glass will be improved greatly with an increase of the Bi₂S₃ content.

Key words: Bi₂S₃ nanocrystals, sodium borosilicate glass, Sol-Gel, third-order optical nonlinear properties

中图分类号:

TQ174

杨昕宇, 向卫东, 赵海军, 张希艳, 梁晓娟, 刘海涛. Bi₂S₃ 纳米晶掺杂钠硼硅玻璃的三阶非线性光学性质[J]. 无机材料学报, 2011, 26(3): 290-294.

YANG Xin-Yu, , XIANG Wei-Dong, , ZHAO Hai-Jun,ZHANG Xi-Yan, LIANG Xiao-Juan, LIU Hai-Tao. Third-order Nonlinear Optical Properties of Bi₂S₃ Nanocrystals Embedded inSodium Borosilicate Glass[J]. Journal of Inorganic Materials, 2011, 26(3): 290-294.

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Bi₂S₃ 纳米晶掺杂钠硼硅玻璃的三阶非线性光学性质

Third-order Nonlinear Optical Properties of Bi₂S₃ Nanocrystals Embedded inSodium Borosilicate Glass

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