Na-Ni掺杂对Bi2(Zn1/3Nb2/3)2O7陶瓷性能的影响

doi:10.3724/SP.J.1077.2010.00825

无机材料学报 ›› 2010, Vol. 25 ›› Issue (8): 825-828.DOI: 10.3724/SP.J.1077.2010.00825 CSTR: 32189.14.SP.J.1077.2010.00825

Na-Ni掺杂对Bi₂(Zn_1/3Nb_2/3)₂O₇陶瓷性能的影响

李在映, 丁士华, 宋天秀

(西华大学材料科学与工程学院, 成都 610039)

收稿日期:2009-12-15 修回日期:2010-01-27 出版日期:2010-08-20 网络出版日期:2010-07-19
基金资助:
四川省教育厅科技基金(2006C025); 西华大学人才基金(R0620109); 西华大学材料学重点学科建设基金(XZD0814-09-1)

Influence of Properties of Bi₂(Zn_1/3Nb_2/3)₂O₇ Ceramics Doped with Na-Ni

LI Zai-Ying, DING Shi-Hua, SONG Tian-Xiu

(College of Materials Science and Engineering, Xihua University, Chengdu 610039,China)

Received:2009-12-15 Revised:2010-01-27 Published:2010-08-20 Online:2010-07-19

摘要/Abstract

摘要：

采用传统固相反应法制备Bi₂(Zn_1/3Nb_2/3)₂O₇基陶瓷. 研究Na⁺、Ni²⁺分别替代Bi³⁺、Nb⁵⁺对Bi₂(Zn_1/3Nb_2/3)₂O₇陶瓷烧结特性和介电性能的影响. 替代后样品的烧结温度从960℃降低到870℃左右. 在-30℃~+130℃, 陶瓷样品的温谱中出现明显的介电弛豫现象, 弛豫峰所在温区较宽; 当Ni²⁺替代量增加到0.2时出现双弛豫峰. 随着Ni²⁺替代量增加, 弛豫峰值温度向高温移动, 弛豫激活能增加, 两弛豫峰之间距增加. 用缺陷偶极子和晶格畸变解释了Na-Ni掺杂Bi₂(Zn_1/3Nb_2/3)₂O₇的介电弛豫现象.

关键词: 锌铌酸铋基陶瓷, 介电弛豫, 离子替代, 晶格畸变, 缺陷偶极子

Abstract:

Bi₂(Zn_1/3Nb_2/3)₂O₇ based ceramics were prepared by a traditional solid phase reaction method. The effects of substitution Na⁺ for Bi³⁺ and Ni²⁺ for Nb³⁺ on the sintering and dielectric properties of Bi₂(Zn_1/3Nb_2/3)₂O₇ based ceramics were investigated. The sintering temperature of the substituted samples dropped to 870℃ from 960℃. At -30℃-+130℃, the dielectric relaxation peak with a broad temperature region is obviously observed and two relaxation peaks appear when the substitution of Ni²⁺ reaches 0.2. Then, with the increasing of substitution, the temperature of the permittivity maximum shifts to higher temperature and the activation energy involved in the relaxation processes increases and the distance between two relaxation peaks become longer. Defect dipole and distortion of crystal lattice theories are used to explain the dielectric relaxation of Na-Ni doped Bi₂(Zn_1/3Nb_2/3)₂O₇ ceramics.

Key words: Bi₂(Zn_1/3Nb_2/3)₂O₇ based ceramic, dielectric relaxation, ion substitution, distortion of crystal lattice, defect dipole

中图分类号:

TB303

李在映, 丁士华, 宋天秀. Na-Ni掺杂对Bi₂(Zn_1/3Nb_2/3)₂O₇陶瓷性能的影响[J]. 无机材料学报, 2010, 25(8): 825-828.

LI Zai-Ying, DING Shi-Hua, SONG Tian-Xiu. Influence of Properties of Bi₂(Zn_1/3Nb_2/3)₂O₇ Ceramics Doped with Na-Ni[J]. Journal of Inorganic Materials, 2010, 25(8): 825-828.

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Na-Ni掺杂对Bi₂(Zn_1/3Nb_2/3)₂O₇陶瓷性能的影响

Influence of Properties of Bi₂(Zn_1/3Nb_2/3)₂O₇ Ceramics Doped with Na-Ni

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