机械合金化制备Mg-Ni合金氢化物电极材料的研究进展

摘要/Abstract

摘要： Mg-Ni系合金作为一种重要的Ni/MH电池负极材料, 一直受到电池工作者的广泛重视. 本文对机械合金化方法制备Mg-Ni系合金作为Ni/MH电池氢化物电极材料的研究现状进行了全面介绍, 综述了Mg-Ni系合金的电化学性能、微观结构、吸放氢机理以及合金的制备方法, 如二元合金化、多元合金化、复合合金化、表面改性等, 并就机械合金化方法制备Mg-Ni系合金作为Ni/MH电池负极材料的研究前景进行了分析和展望.

关键词: 机械合金化, Mg-Ni系合金, 非晶态, Ni/MH电池

Abstract: Mg-Ni based alloy has always been paid much attention as important negative electrode materials for Ni/MH battery. Recent research progress in Mg-Ni based alloy by mechanical
alloying for Ni/MH battery hydride electrode materials was reviewed with its focus on the electrochemical performance, micro-structural
characteristics, mechanism of hydriding and dehydriding and the main methods in preparation and modification of Mg-Ni based alloy electrodes such as
Mg-Ni based binary alloys, ternary alloys, composite alloying and surface modifications. Also the main direction of studies on Mg-Ni based alloy by
mechanical alloying for Ni/MH battery negative electrode materials was proposed.

Key words: mechanical alloying, Mg-Ni based alloy, amorphous, nickel-metal hydride battery

中图分类号:

TM912

乔玉卿,赵敏寿,朱新坚,曹广益. 机械合金化制备Mg-Ni合金氢化物电极材料的研究进展[J]. 无机材料学报.

QIAO Yu-Qing,ZHAO Min-Shou,ZHU Xin-Jian,CAO Guang-Yi. Progress of Research on Preparation of Mg-Ni Based Alloy by Mechanical Alloying for Hydride Electrode Materials[J]. Journal of Inorganic Materials.

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