无机材料学报

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晶种对氢氧化铝转相和热压烧结氧化铝晶形变化的影响

易中周1,2; 肖冰3; 杨为佑1; 谢志鹏1   

  1. 1. 清华大学材料科学与工程系, 北京 100084; 2. 云南红河学院化学系, 云南 661100; 3. 中原工学院, 郑州 450007
  • 收稿日期:2003-11-07 修回日期:2004-01-05 出版日期:2004-11-20 网络出版日期:2004-11-20

Imfluence of α-Alumina Seeds on Transformation of Aluminium Hydroxide and Morphology of Alumina Grain in Hot-Pressing

YI Zhong-Zhou1,2; XIAO Bing3; YANG Wei-You1; XIE Zhi-Peng1   

  1. 1. Department of Materials Science and Engineering; Tsinghua University; Beijing 100084; China; 2. Chemistry Department of Honghe University; Yunnan 661100, China; 3. Zhongyuan Engineering College; Zhengzhou 450007; China
  • Received:2003-11-07 Revised:2004-01-05 Published:2004-11-20 Online:2004-11-20

摘要: 以氢氧化铝为初始原料,通过球磨过程中高纯氧化铝磨介的磨屑作为晶种引入氢氧化铝中.引入的α-Al2O3品种使氢氧化铝于1100℃×2h的条件下转变为α相氧化铝.而且随着α-Al2O3品种引入量的增加,煅烧后氧化铝颗粒的平均粒径减小,颗粒尺寸分布均匀.煅烧得到的氧化铝超细粉经热压烧结后,Al2O3晶粒形貌随品种的引入量的不同而发生变化.未引入α-Al2O3品种的条件下,晶粒形状主要为等轴状;晶种引入后,晶粒发育成六角片状;而且随着晶种引入量进一步增加时,六角片状晶粒尺寸减小,当晶种数量增加到20wt%以上时,晶粒发育生长为长柱状.

关键词: 氢氧化铝, α-Al2O3晶种, 氧化铝晶粒形貌

Abstract: Abrasives as seeds were introduced to the starting materials of aluminium hydroxide by wet-grinding of high-purity alumina milling balls. The phase transformation from aluminium hydroxide to
α-Al2O3 was completed at 1100℃ for 2h by seeds added. The size of alumina particle derived from calcined aluminium hydroxide was
reduced and narrow particle size distribution was obtained with increasing amount of the seeds. Alumina grain shapes changed with the amount of introduced
seeds: equiaxed grains were observed for the samples without seeds introduction, hexagonal platelets were developed after seeds addition. Finally the grain
shape showed a trend to elongated grains with seed concentration up to 20wt%.

Key words: aluminium hydroxide, α-Al2O3 seed, alumina grain morphology

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