浆料浸渍法制备C/C-SiC-ZrB2超高温复合材料及其烧蚀性能研究

doi:10.3724/SP.J.1077.2013.12731

无机材料学报 ›› 2013, Vol. 28 ›› Issue (9): 1014-1018.DOI: 10.3724/SP.J.1077.2013.12731 CSTR: 32189.14.SP.J.1077.2013.12731

浆料浸渍法制备C/C-SiC-ZrB₂超高温复合材料及其烧蚀性能研究

樊乾国¹, 崔红^1,2, 闫联生¹, 张强¹, 孟祥利¹, 杨星¹

(1. 西安航天复合材料研究所, 西安710025; 2. 高性能碳纤维制造及应用国家地方联合工程研究中心, 西安710089)

收稿日期:2012-12-03 修回日期:2013-02-04 出版日期:2013-09-20 网络出版日期:2013-08-14
作者简介:樊乾国(1985-), 男, 硕士, 工程师. E-mail:fanqianguo168@163.com

Ablation Resistance Properties of Ultra-high Temperature Composites C/C-SiC-ZrB₂ by Slurry Impregnation Method

FAN Qian-Guo¹, CUI Hong^1,2, YAN Lian-Sheng¹, ZHANG Qiang¹, MENG Xiang-Li¹, YANG Xing¹

(1. Xi’an Aerospace Composite Material Institute, Xi’an 710025, China; 2. National and Local Union Engineering Research Center of High-performance Carbon Fiber Manufacture and Application, Xi'an 710089, China)

Received:2012-12-03 Revised:2013-02-04 Published:2013-09-20 Online:2013-08-14
About author:FAN Qian-Guo. E-mail:fanqianguo168@163.com

摘要/Abstract

摘要： 采用浆料浸渍法引入ZrB₂微粉作为耐超高温相, 以炭纤维为增强体, 以热解炭和SiC为基体, 制备了ZrB₂含量不同的耐超高温C/C-SiC-ZrB₂复合材料; 通过电弧风洞考核材料的抗烧蚀性能, 通过XRD、SEM和EDS分析材料的烧蚀机理。结果表明: 在Ma 6电弧风洞条件下, C/C-SiC-ZrB₂复合材料的抗烧蚀性能优于C/C-SiC, 且随着ZrB₂含量的增加, 抗烧蚀性能随之提高; 在高温阶段形成的ZrO₂-SiO₂玻璃态熔融层起到了抗氧化烧蚀的作用。

关键词: 超高温复合材料, C/C-SiC-ZrB₂, 烧蚀性能, 烧蚀机理

Abstract: The ultra-high-temperature composites C/C-SiC-ZrB₂ were prepared by slurry impregnation method. The composites consist of the carbon fiber as the reinforced phase, C and SiC as the matrix, and the micro-particle ZrB₂ as the ultra high temperature phase. The ablation resistance properties of the composites were assessed by arc wind tunnel testing. The ablation mechanism was studied through XRD, SEM and EDS measurements. The results indicate that compared with C/C-SiC composites, the C/C-SiC-ZrB₂composites show better ablation resistance properties, and the properties increases with the content of ZrB₂increase. A ZrO₂-SiO₂ glassy melting layer formed at high temperature plays an important role in antioxidant ablation.

Key words: ultra-high-temperature composites, C/C-SiC-ZrB₂ increase, ablation resistance properties, ablation mechanism

中图分类号:

TB332

樊乾国, 崔红, 闫联生, 张强, 孟祥利, 杨星. 浆料浸渍法制备C/C-SiC-ZrB₂超高温复合材料及其烧蚀性能研究[J]. 无机材料学报, 2013, 28(9): 1014-1018.

FAN Qian-Guo, CUI Hong, YAN Lian-Sheng, ZHANG Qiang, MENG Xiang-Li, YANG Xing. Ablation Resistance Properties of Ultra-high Temperature Composites C/C-SiC-ZrB₂ by Slurry Impregnation Method[J]. Journal of Inorganic Materials, 2013, 28(9): 1014-1018.

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浆料浸渍法制备C/C-SiC-ZrB₂超高温复合材料及其烧蚀性能研究

Ablation Resistance Properties of Ultra-high Temperature Composites C/C-SiC-ZrB₂ by Slurry Impregnation Method

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