Bi2O3纳米晶玻璃三阶非线性光吸收性质的研究

doi:10.3724/SP.J.1077.2012.00317

无机材料学报 ›› 2012, Vol. 27 ›› Issue (3): 317-322.DOI: 10.3724/SP.J.1077.2012.00317 CSTR: 32189.14.SP.J.1077.2012.00317

Bi₂O₃纳米晶玻璃三阶非线性光吸收性质的研究

杨昕宇^1,2, 向卫东^1,2, 张希艳², 刘海涛¹, 赵海军¹, 梁晓娟¹

(1. 温州大学化学与材料工程学院, 温州325035; 2. 长春理工大学材料科学与工程学院, 长春 130022)

收稿日期:2011-03-01 修回日期:2011-05-05 出版日期:2012-03-20 网络出版日期:2012-02-16
作者简介:杨昕宇(1978-), 男, 博士研究生. E-mail: yangxinyu13@126.com
基金资助:
国家自然科学基金(50772075, 50972107); 浙江省自然科学基金(Y4100233); 浙江省科技创新团队项目(2009R50010)

Study on the Third-order Optical Nonlinear Absorption Properties of Bi₂O₃ Nanocrystals Glass

YANG Xin-Yu^1,2, XIANG Wei-Dong^1,2, ZHANG Xi-Yan², LIU Hai-Tao¹, ZHAO Hai-Jun¹, LIANG Xiao-Juan¹

(1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China; 2. College of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China)

Received:2011-03-01 Revised:2011-05-05 Published:2012-03-20 Online:2012-02-16
About author:YANG Xin-Yu. E-mail: yangxinyu13@126.com
Supported by:
National Natural Science Foundation of China (50772075, 50972107); Natural Science Foundation of Zhejiang(Y4100233); Zhejiang Province Key Scientific and Technological Innovations Team (2009R50010)

摘要/Abstract

摘要： 利用溶胶-凝胶法结合气氛控制方式合成了含Bi₂O₃纳米晶钠硼硅玻璃. 利用X射线粉末衍射仪(XRD)、X射线光电子能谱(XPS)、透射电子显微镜(TEM)、X射线能量色散谱(EDX)、扫描模式透射电子显微镜(STEM)、高分辨透射电子显微镜(HRTEM)以及选区电子衍射 (SAED)对掺杂在钠硼硅玻璃中Bi₂O₃纳米晶的形貌和微结构进行了表征, 同时, 利用飞秒开孔Z-scan技术详细地研究了Bi₂O₃纳米晶玻璃在800 nm处不同激发光强度下的三阶非线性光吸收性质. 结果表明, 在钠硼硅玻璃中形成了尺寸小于10 nm的Bi₂O₃单斜晶系纳米晶. 随着激发光强度的增强, 该玻璃的三阶非线性光吸收性质产生由饱和吸收向反饱和吸收的转变. 进一步, 计算得到的该玻璃三阶非线性极化率χ⁽³⁾的数量级范围在10^-19~10^-18 m²/V²之间. 这一结果说明该玻璃具有良好的非线性光学性能, 并且在光限幅器等非线性光学领域具有潜在的应用价值.

关键词: Bi₂O₃纳米晶, 钠硼硅玻璃, 溶胶-凝胶, 三阶非线性光吸收性质

Abstract: The sodium borosilicate glass containing Bi₂O₃ nanocrystals was synthesized by employing both Sol-Gel and atmosphere control methods. Morphology and microstructure of the Bi₂O₃ nanocrystals doped in the sodium borosilicate glass were characterized by means of X-ray powder diffraction (XRD), X-ray photoelectron spectroscope (XPS), transmission electron microscope (TEM), energy dispersion X-ray spectra (EDX), scanning transmission electron microscope (STEM), high-resolution transmission electron microscope (HRTEM), and selected-area electron diffraction (SAED). Meanwhile, the third-order nonlinear optical absorption properties of the Bi₂O₃ nanocrystals glass were investigated by means of the femtosecond open-aperture Z-scan technique under the different excited light intensities at a wavelength of 800 nm. The results show that the Bi₂O₃ nanocrystals are formed in the sodium borosilicate glass matrix, with dimension less than 10 nm. Moreover, the transformation from saturable absorption to reverse saturable absorption will occur with the increase of the excited light intensities in the glass. Furthermore, the calculated magnitude of the third-order nonlinear susceptibility χ⁽³⁾ ranges from 10^-19 to 10^-18 m²/V² in the glass. The results indicate that the glass exhibits the excellent nonlinear optical properties, which have potential application in the field of nonlinear optics such as optical limiters, etc.

Key words: Bi₂O₃ nanocrystals, sodium borosilicate glass, Sol-Gel, third-order optical nonlinear absorption properties

中图分类号:

TQ174

杨昕宇, 向卫东, 张希艳, 刘海涛, 赵海军, 梁晓娟. Bi₂O₃纳米晶玻璃三阶非线性光吸收性质的研究[J]. 无机材料学报, 2012, 27(3): 317-322.

YANG Xin-Yu, XIANG Wei-Dong, ZHANG Xi-Yan, LIU Hai-Tao, ZHAO Hai-Jun, LIANG Xiao-Juan. Study on the Third-order Optical Nonlinear Absorption Properties of Bi₂O₃ Nanocrystals Glass[J]. Journal of Inorganic Materials, 2012, 27(3): 317-322.

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Bi₂O₃纳米晶玻璃三阶非线性光吸收性质的研究

Study on the Third-order Optical Nonlinear Absorption Properties of Bi₂O₃ Nanocrystals Glass

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