TiO2 纳滤膜的制备及其离子截留性能

doi:10.3724/SP.J.1077.2011.00305

无机材料学报 ›› 2011, Vol. 26 ›› Issue (3): 305-310.DOI: 10.3724/SP.J.1077.2011.00305 CSTR: 32189.14.SP.J.1077.2011.00305

TiO₂ 纳滤膜的制备及其离子截留性能

漆虹, 李世大, 江晓骆, 韩静

南京工业大学膜科学技术研究所,材料化学工程国家重点实验室, 南京210009

收稿日期:2010-05-13 修回日期:2010-08-04 出版日期:2011-03-20 网络出版日期:2011-02-18
作者简介:漆虹(1974-), 男, 博士, 副研究员.
基金资助:
国家自然科学基金青年基金(20906047);化学工程联合国家重点实验室开放基金 (SKL-ChE-09A01)

Preparation and Ions Retention Properties of TiO₂ Nanofiltration Membranes

QI Hong, LI Shi-Da, JIANG Xiao-Luo, HAN Jing

Membrane Scienceand Technology Research Center, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China

Received:2010-05-13 Revised:2010-08-04 Published:2011-03-20 Online:2011-02-18
Supported by:
National Natural Science Foundation of China(20906047);Foundation of State Key Laboratory of Chemical Enginee-ring (SKL-ChE-09A01)

摘要/Abstract

摘要： 以钛酸四异丙酯为前驱体,通过聚合溶胶路线制备出平均尺寸约1.2 nm的TiO₂溶胶.采用浸浆法, 经过一次涂膜,在平均孔径约为3nm的片状 g -Al₂O₃/ a -Al₂O₃支撑体上制备出完整无缺陷的TiO₂纳滤膜.详细考察了煅烧温度对非担载膜(TiO₂粉末)和TiO₂纳滤膜性能的影响.在350℃的煅烧温度下制备出孔径约为1.5nm的TiO₂纳滤膜,该膜对PEG的截留分子量为890,纯水渗透通量为5.3 L/(m² ? h)(8×10⁵Pa,20℃); 并详细考察了该膜对NaCl、CaCl₂、Na₂SO₄、MgCl₂和Ni(NO₃)₂5种溶液的截留性能.结果表明, 在pH＝4,压力5×10⁵Pa的条件下,Ti-350膜对0.025 mol/L CaCl₂和MgCl₂溶液的离子截留率分别达到96.5%和92.8 %.

关键词: 陶瓷纳滤膜, TiO₂, 溶胶-凝胶法, 离子截留

Abstract: A stable TiO₂ Solwith a mean particle size of 1.2 nm was synthesized with titanium is opropoxideas a precursor through polymeric Sol-Gel route. Diska -Al₂O₃ supported mesoporousg -Al₂O₃membrane with mean pore size of 3 nm was used as support for nanofiltration membranes deposition. Defect-free TiO₂ nanofiltration membranessuper imposed on these supports were fabricated via dip-coating method followed by drying and calcination. The effect of calcination temperature on properties of unsupported TiO₂membranes (powders) as well as supported TiO₂nanofiltration membranes was studied in detail. The MWCO, mean pore size and pure water fluxof TiO₂ nanofiltration membrane calcined at 350℃were 890, 1.5 nm and 5.3 L/(m²·h)(at 8×10⁵Pa,20℃), respectively. Ions retention properties of Ti-350 nanofiltration membrane towards five solutions like NaCl, CaCl₂, Na₂SO₄,MgCl₂ and Ni(NO₃)₂were characterized. Under apH value of 4.0 and transmembrane pressure of 5.0×10⁵Pa,the retention properties of Ti-350 membrane towards CaCl₂and MgCl₂solutions reach maximum values of 96.5% and 92.8%, respectively.

Key words: ceramic nanofiltration membranes, titania, Sol-Gel method, ions retention

中图分类号:

TQ028

漆虹, 李世大, 江晓骆, 韩静. TiO₂ 纳滤膜的制备及其离子截留性能[J]. 无机材料学报, 2011, 26(3): 305-310.

QI Hong, LI Shi-Da, JIANG Xiao-Luo, HAN Jing. Preparation and Ions Retention Properties of TiO₂ Nanofiltration Membranes[J]. Journal of Inorganic Materials, 2011, 26(3): 305-310.

参考文献

[1] Mallada R, Menéndez M.Inorganic Membranes Synthesis,Characterization and Application. Amsterdam: Elsevier Press, 2008: 177-215.
[2] Vandezande P, Gevers L E M, VankelecomI F J. Solvent resistant nanofiltration: separating on a molecular level. Chem. Soc. Rev., 2008,37(2) : 365-405.
[3] Koros B. The Journal of Membrane Science celebrates its 30^thyear and looks to the future.J. Membr. Sci. , 2006,278(1/2) : 1-2.
[4] Puhlfürβ P, Voigt A, Weber R, et al. Microporous TiO₂ membranes with a cut off <500Da. J.Membr. Sci ., 2000,174(1) : 123-133.
[5] van Gestel T, Kruidhof H, Blank D H A, et al. ZrO₂and TiO₂ membranes for nanofiltration and pervaporation Part1.Preparation and characteration of a corrosion-resistant ZrO₂nanofiltration membrane with a MWCO<300.J. Membr. Sci. , 2006,284(1/2) : 128-136.
[6] van Gestel T, Vandecasteele C, BuekenhoudtA, et al.Alumina and titania multilayer membranes for nanofiltration: preparation, characterization and chemicalstability .J. Membr. Sci. , 2002,207(1) : 73-89.
[7] van Gestel T, Vandecasteele C, Buekenhoudt A, et al. Salt retention in nanofiltration with multilayer ceramic TiO₂membranes. J. Membr. Sci., 2002,209(2) : 379-389.
[8] Sekulic J, ten Elshof J E,Blank D H A. A microporous titania membrane for nanofiltration andpervaporation. Adv. Mater. , 2004,16(17) : 1546-1550.
[9] Tsuru T, Hironaka D, Yoshioka T,et al. Titania membranes for liquidphase separation: effect of surface charge on flux. Sep. Purif. Technol., 2001,25(1/2/3) : 307-314.
[10] Tsuru T,Takezoe H, Asaeda M. Ion separation by porous silica-zirconia nanofiltration membranes. AIChE J., 1998,44(3) : 765 -768.
[11]SaffajN, Persin M, Younssi S A.et al . Removal of salts and dyes by low ZnAl₂O₄–TiO₂ultrafiltration membrane deposited on support made from raw clay.Sep. Purif. Technol. , 2005,47(1/2) : 36-42.
[12] Sekulic J, ten Elshof J E, Blank D H A. Synthesis and characterization of microporous titania membranes. Journal of Sol-Gel Science and Technology.2004,31(1/2/3) : 201-204.
[13]Sekulic J. Mesoporous and Microporous Titania Membranes.PhD Thesis, The Netherlands (Enschede): University ofTwente, 2004: 69-74.
[14]Agoudjil N, Benkacem T. Synthesis of porous titaniumdioxide membranes. Desalination , 2007,206(1/2/3) : 531-537.
[15]漆虹, 邢卫红, 范益群. γ-Al₂O₃中孔陶瓷膜的制备及表征. 化工学报, 2009,60(10) : 2628-2632.
[16]漆虹, 江晓骆, 韩静, 等. ZrO₂中孔膜的制备及其耐腐蚀性能. 过程工程学报, 2009,9(6) : 1216-1221.
[17]Kumar K P N. Nanostructured Ceramic Membranes. The Netherlands (Enschede): University of Twente, 1993: 62.
[18]SingK S W, Everett D H, Haul R A W, et al.Reporting physisorption data for gas/solid systems ? with special reference to the determinationof surface area and porosity (Recommendations 1984).Pure Appl. Chem. , 1985,57(4) : 603-619.
[19]汪伟宁, 王大新, 王晓琳, 等. 无机盐水溶液体系的纳滤膜分离实验研究. 高校化学工程学报, 2002,16(3) : 257-262.
[20]Schaep J, Vandecasteele C, Peeters B, et al. Characteristics and retention properties of amesoporousg -Al₂O₃membranefor nanofiltration. J. Membr. Sci., 1999, 163(2) : 229-237.
[21]Peeters J M M, Mulder M H V, Strathmann H. Streaming potential measurements as acharacterization method for nanofiltration membranes. Colloids Surf. A: Physico. Eng. Asp., 1999,150(1/2/3) : 247-259.

TiO₂ 纳滤膜的制备及其离子截留性能

Preparation and Ions Retention Properties of TiO₂ Nanofiltration Membranes

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	马彬彬, 钟婉菱, 韩涧, 陈椋煜, 孙婧婧, 雷彩霞. ZIF-8/TiO₂复合介观晶体的制备及光催化活性[J]. 无机材料学报, 2024, 39(8): 937-944.
[2]	戴乐, 刘洋, 高轩, 王书豪, 宋雅婷, 唐明猛, 刘丽莎, 汪尧进. 浓度梯度掺杂实现BiFeO₃薄膜自极化[J]. 无机材料学报, 2024, 39(1): 99-106.
[3]	贾玉娜, 曹旭, 焦秀玲, 陈代荣. 无机酸铝体系氧化铝连续纤维的制备技术研究[J]. 无机材料学报, 2023, 38(11): 1257-1264.
[4]	贾鑫, 李晋宇, 丁世豪, 申倩倩, 贾虎生, 薛晋波. Pd纳米颗粒协同氧空位增强TiO₂光催化CO₂还原性能[J]. 无机材料学报, 2023, 38(11): 1301-1308.
[5]	安琳, 吴淏, 韩鑫, 李耀刚, 王宏志, 张青红. 非贵金属Co_5.47N/N-rGO助催化剂增强TiO₂光催化制氢性能[J]. 无机材料学报, 2022, 37(5): 534-540.
[6]	吕庆洋, 张玉亭, 顾学红. 超声辅助溶胶-凝胶法制备中空纤维TiO₂超滤膜[J]. 无机材料学报, 2022, 37(10): 1051-1057.
[7]	肖翔, 郭少柯, 丁成, 张志洁, 黄海瑞, 徐家跃. CsPbBr₃@TiO₂核壳结构纳米复合材料用作水稳高效可见光催化剂[J]. 无机材料学报, 2021, 36(5): 507-512.
[8]	席文, 李海波. TiO₂/Ti₃C₂T_x复合材料的制备及其杂化电容脱盐特性的研究[J]. 无机材料学报, 2021, 36(3): 283-291.
[9]	满鑫, 吴南, 张牧, 贺红亮, 孙旭东, 李晓东. Lu₂O₃-MgO纳米粉体合成及其复相红外透明陶瓷制备[J]. 无机材料学报, 2021, 36(12): 1263-1269.
[10]	杨丛纲, 米乐, 冯爱虎, 于洋, 孙大志, 于云. KH-560改性SiO₂绝缘薄膜的制备及性能研究[J]. 无机材料学报, 2021, 36(12): 1343-1348.
[11]	刘彩, 刘芳, 黄方, 王晓娟. 海藻基CDs-Cu-TiO₂复合材料的制备及其光催化性能[J]. 无机材料学报, 2021, 36(11): 1154-1162.
[12]	李翠霞, 孙会珍, 金海泽, 史晓, 李文生, 孔文慧. 3D多级孔rGO/TiO₂复合材料的构筑及其光催化性能研究[J]. 无机材料学报, 2021, 36(10): 1039-1046.
[13]	王苹,李心宇,时占领,李海涛. Ag与Ag₂O协同增强TiO₂光催化制氢性能的研究[J]. 无机材料学报, 2020, 35(7): 781-788.
[14]	季邦, 赵文锋, 段洁利, 马立哲, 付兰慧, 杨洲. 泡沫镍网负载TiO₂/WO₃薄膜对乙烯的光催化降解[J]. 无机材料学报, 2020, 35(5): 581-588.
[15]	王旭聪, 邓浩, 姜忠义, 袁立永. 不同N源无定形TiO₂/g-C₃N₄光催化还原Re(VII)性能[J]. 无机材料学报, 2020, 35(12): 1340-1348.