Adv. Search
Journal of Inorganic Materials

Journal of Inorganic Materials >

2007 , Vol. 22 >Issue 2: 369 - 372

DOI: https://doi.org/10.3724/SP.J.1077.2007.00369

Research Paper

Novel Organic-inorganic Photochromic Film based on Mono-vacant Keggin-type Polyoxometalates

  • DONG Xiao-Wen ,
  • PAN Qing-Yi ,
  • HUANG Yan ,
  • HUANG Jia-Jun ,
  • WANG Si-Yuan
Expand
  • College of Science, Shanghai University, Shanghai 200436, China

Received date: 2006-03-22

  Revised date: 2006-08-07

  Online published: 2007-03-20

Fold

Abstract

A novel SiW11/SiO2/PVA hybrid film was fabricated by using a sol-gel method. Mono-vacant Keggin-type polyoxometalates [Xn+ W11O39] (12-n)- (SiW11) were introduced into SiO2 network. The IR spectrum indicates that the covalent bond of W--O--Si is formed between SiW11 and SiO2 network, and SiW11 anions still maintain Keggin structure basically in the hybrid film. However, the strong reaction between SiW11 and matrix brings big shape changes on SiW11 anions. The transparent film changes from colorless to dark blue under UV irradiation and shows a good photochromic havior.

Key words： organic-inorganic; hybrid; photochromic; polyoxometalates; sol-gel

Cite this article

DONG Xiao-Wen , PAN Qing-Yi , HUANG Yan , HUANG Jia-Jun , WANG Si-Yuan . Novel Organic-inorganic Photochromic Film based on Mono-vacant Keggin-type Polyoxometalates[J]. Journal of Inorganic Materials, 2007 , 22(2) : 369 -372 . DOI: 10.3724/SP.J.1077.2007.00369

References

[1] 柳士忠, 王峥, 库总军, 等. 无机化学学报, 1999, 15 (5): 652--656.
[2] 牛景杨, 王敬平, 陈瑶. 无机化学学报, 1999, 15 (3): 401--404.
[3] 靳素荣, 姚礼锋, 陈永熙. 无机化学学报, 2001, 17 (2): 289--291.
[4] 张铁锐, 冯威, 卢然, 等. 高等学校化学学报, 2002, 23 (2): 297--299.
[5] Zhang H Y, Xu L, Wang E B, et al. Materials Letters, 2003, 57 (8): 1417--1422.
[6] 冯威, 张铁锐, 刘延, 等. 高等学校化学学报, 2000, 21 (10): 1563--1565.
[7] 张铁锐, 金明, 冯威, 等. 高等学校化学学报, 2002, 23 (10): 1979-1981.
[8] Huang Yan, Pan Qing-Yi , Dong Xiao-Wen , et al. Materials Chemistry and Physics, 2006, 97: 431--436.
[9] Kim Je-Deok, Honma Itaru. Electrochimica Acta, 2003, 48 (24): 3633-3638.
[10] Li D F, Guo Y H, Hu C W, et al. Applied Catalysis A : General, 2002, 235 (1-2): 11--20.
[11] Sadakane M, Steckhan E. Chem. Rev., 1998, 98 (1): 219--237.
[12] Toshihiro Yamase. Chem. Rev., 1998, 98 (1): 307--325.
[13] Varga G M, Jr. Papaconstantinou E, Pope M T. Inorg. Chem., 1970, 9 (3): 662--667.
[14] 唐立昊, 岳斌, 朱思三. 高等学校化学学报, 1999, 20 (9): 1349-1351.
[15] 牛景扬, 党东宾, 柏艳, 等. 河南大学学报(自然科学版), 2000, 30 (1): 36--38.
Options
Outlines

/

〈 〉