A SiC/(ZrB2-SiC/SiC)4 coating was prepared by slurry painting and pulse CVD. The composition and structure of the coating were studied by using XRD,SEM and EDS analysis, then the anti-oxidation property of the coating was investigated. The results show that the thickness of obtained coating is about 100μm, ZrB2-SiC layer and Pulse CVD SiC layer are bonded to each other alternately. After oxidation at 1500℃ in air for 25h, the weight loss of the Pulse CVD coating is 5.1%, while weight gain of the SiC/(ZrB2-SiC/SiC)4 coating is about 2.5%. The SiC/(ZrB2-SiC/SiC)4 coating shows excellent antioxidation property.
WU Ding-Xing
,
DONG Shao-Ming
,
DING Yu-Sheng
,
ZHANG Xiang-Yu
,
WANG Zheng
,
ZHOU Hai-Jun
. Preparation and Property of SiC/(ZrB2-SiC/SiC)4 Anti-oxidation
Coatings for Cf/SiC Composites[J]. Journal of Inorganic Materials, 2009
, 24(4)
: 836
-840
.
DOI: 10.3724/SP.J.1077.2009.00836
[1]Tripp W D, Davis H H, Graham H C. Am. Ceram. Soc. Bull., 1973, 52(8): 612-616.
[2]Kaufman Boride L. Composites-A New Generation of Nose Cap and Leading Edge Materials for Reusable Lifting Re-entry Systems. AIAA Advanced Space Transportation Meeting AIAA Paper, NY, Feb. 1970: 70-278.
[3]Bull J D, Rasky D J, Karika C J C. Stability Characterization of Diboride Composites under HighVelocity Atmospheric Flight Conditions, in Proceedings of the 24th International SAMPE Technical Conference, Toronto, Oct. 1992: 1092-1105.
[4]Bull J, White M J, Kaufman L. Ablation Resistant Zirconium and Hafnium Ceramics. US, Patent 5750450. 1998.05.12.
[5]Bongiorno A, Frst C J, Kalia R K, et al. MRS Bulletin, 2006, 31(5): 410-418.
[6]Loehman R, Corral E, Dumm H P, et al. Ultra High Temperature Ceramics for. Hypersonic Vehicle Applications. Sandia Report: SAND 2006-2925, Printed June 2006. Prepared by Sandia National Laboratories. Albuquerque, New Mexico 87185 and Livermore, California 94550.
[7]Opeka M M, Talmy I G, Wuchina E J, et al. J. Eur. Cerm. Soc., 1999, 19(13/14): 2405-2414.
[8]Scatteia L. SHS-UHTC: Emissivity and catalitycity characterization of Ultra High Temperature Ceramics of space application, CIRA-Italian Aerospace Research Center, Capua (CE), Italy. SOLFACE. Joint Two-Day Event. CNRS-PROMES, April 4-5, 2006.
[9]Bartulia C, Valentea T, Tuluib M. Surf. & Coat. Technol., 2002, 155(2/3): 260-273.
[10]Tului M, Marino G, Valente T. Surf. & Coat. Technol., 2006, 201(5): 2103-2108.
[11]Monteverde F. Corros. Sci., 2005, 47(8): 2020-2033.
[12]陈 勇. ZrB2基超高温陶瓷材料性能的评价. 西安:西北工业大学硕士论文, 2006.
[13]Monteverde F, Bellosi A. J. Eur. Ceram. Soc., 2005, 25(7): 1025-1031.
[14]Fahrenholtz W G, Hilmas G H, Talmy I G, et al. J. Am. Ceram. Soc., 2007, 90(5): 1347-1364.
[15]Costello J A, Tressler R E. J. Am. Ceram. Soc., 1981, 64(6): 327-331.
[16]Ban’kovskaya I B, Zhabrev V A. Glass Phys. Chem., 2005, 31(4): 482-488.