Research Paper

Synthesis and Characterizations of Lithium Vanadium Oxide Nanotubes

  • CUI Chao-Jun ,
  • WU Guang-Ming ,
  • ZHANG Ming-Xia ,
  • SUN Juan-Ping ,
  • YANG Hui-Yu ,
  • SHEN Jun
Expand
  • Pohl Institute of Solid State Physics, Shanghai Key Laboratory of Special Artificial Microstructure Materials and Technology, Tongji University, Shanghai 200092,China

Received date: 2008-11-18

  Revised date: 2009-01-06

  Online published: 2009-07-20

Abstract

Lithium vanadium oxide nanotubes as cathode materials for rechargeable lithium batteries were prepared via a sol-gel reaction followed by hydrothermal treatment, in which V2O5 and LiOH·H2O were used as raw materials and C16H33NH2 as structure-directing template. Structure and morphology of the nanotubes were investigated by SEM, TEM, XRD, FT-IR and XPS.Meantime, electrochemical behavior of the materials was researched by cyclic voltammetry. The results show that the inner and the outer diameters of the obtained nanotubes are of about 30nm and 70nm with length between 1μm to 3μm, respectively. It is also confirmed by XPS that the elements of the products are made up of various chemical states. The electrochemical performance indicates that the obtained nanotubes as cathode materials for rechargeable lithium batteries have good lithium-ion insertion/deinsertion reversibility.

Cite this article

CUI Chao-Jun , WU Guang-Ming , ZHANG Ming-Xia , SUN Juan-Ping , YANG Hui-Yu , SHEN Jun . Synthesis and Characterizations of Lithium Vanadium Oxide Nanotubes[J]. Journal of Inorganic Materials, 2009 , 24(4) : 787 -792 . DOI: 10.3724/SP.J.1077.2009.00787

References

[1]魏 晓, 韩高荣. 材料科学与工程学报, 2006, 24(1):118-123.
[2]叶乃清, 刘长久, 沈上越(YE Nai-Qing, et al). 无机材料学报(Journal of Inorganic Materials), 2004, 19(6):1217-1224.
[3]刘光明, 李美栓, 高 虹, 等. 电源技术, 2002, 26(1):9-10.
[4]岳鸿飞, 周 园. 有色金属与稀土应用, 2006(4):7-14.
[5]刘建睿, 王 猛, 尹大川, 等. 电源技术, 2001, 25(4):308-311.
[6]刘 景, 温兆银, 吴梅梅, 等(LIU Jing, et al). 无机材料学报(Journal of Inorganic Materials), 2002, 17(1):1-9.
[7]廖春发, 郭守玉, 陈辉煌. 江西有色金属, 2003, 17(2):34-37.
[8]Iijima S. Nature, 1991, 354(6348): 56-58.
[9]Spahr M E, Bitterli P, Nesper R, et al. Angew. Chem. Int. Ed., 1998, 37(9): 1263-1265.
[10]Ivanovskaya V V, Enyashin A N,Sofronov A A, et al. Solid State Commun., 2003, 126(9): 489-493.
[11]Liu A, Ichihara M, Honma I, et al. Electrochemistry Communications, 2007, 9(7): 1766-1771.
[12]Sediri F, Toiati F, Gharbi N. Materials Letters, 2007, 61(8/9): 1946-1950.
[13]Pillai K S, Krumeich F, Muhr H J, et al. Solid State Ionics, 2001, 141-142: 185-190.
[14]中西香尔, 所罗曼P H. 红外光谱分析100例.北京:科学出版社, 1984: 9-11.
[15]Vera-Robles L I, Naab F U, Campero A, et al. Nucl. Instr. and Meth. in Phys.Res.B, 2007, 261(1/2): 534-537.
[16]吴广明, 吴永刚, 倪星元, 等. 材料研究学报,2000, 14(2):210-214.
[17]吴广明, 夏长生, 杜开放, 等. 同济大学学报, 2003, 31(12):1501-1504.
[18]Mai Li-qiang, Chen Wen, Xu Qing, et al. Solid State Commun., 2003, 126(10): 541-543.
[19]Delichere P, Bere K E, Abon M. Applied Catalysis A, 1998, 172(2): 295-309.
[20]Casaletto M P, Kaciulis S, Lisi L, et al. Applied Catalysis A, 2001, 218(1/2): 129-137.
[21]Casaletto M P, Lisi L,Mattogno G, et al. Applied Catalysis A, 2002, 226(1/2): 41-48.
[22]吴广明, 吴永刚, 倪星元, 等. 功能材料, 1999, 30(4):404-406.
[23]朱泉峣, 陈 文, 徐 庆, 等. 武汉理工大学学报, 2002, 24(11):8-11.
[24]江少群, 马欣新, 孙明红, 等. 中国表面工程, 2005, 18(2):39-43.
[25]Benayad A, Martinez H, Gies A, et al. Journal of Electron Spectroscopy and Related Phenomena, 2006, 150(1): 1-10.
[26]Liu Aihua, Ichihara M, Honma I, et al. Electrochemistry Communications,2007, 9(7): 1766-1771.
[27]Bhuvaneswari M S, Selvasekarapandian S, Fujihara S, et al. Solid State Ionics,2006,177(1/2):121-127.
[28]裴先茹, 王晓冬, 张顺利, 等.无机化学学报, 2006, 22(12):2135-2140.
[29]胡勇胜, 陈 文, 徐 庆, 等.硅酸盐通报, 2001, 20(3):62-65.
[30]周 静, 陈 文, 徐 庆, 等.分子科学学报, 2001, 17(2):71-76.
[31]Jouanneau S, Verbaere A, Guyomard D, et al. Journal of Solid State Chemistry, 2005, 178(1): 22-27.
[32]叶尚云, 张平伟, 夏永姚, 等.中国稀土学报, 2006, 24(专辑):382-388.
Outlines

/