Progress in the Periodic Mesoporous Organosilicas

YANG Qi-Hua; LIU Jian; ZHONG Hua; WANG Pei-Yuan

doi:10.3724/SP.J.1077.2009.00641

Journal of Inorganic Materials >

2009 , Vol. 24 >Issue 4: 641 - 649

DOI: https://doi.org/10.3724/SP.J.1077.2009.00641

Invited Review

Progress in the Periodic Mesoporous Organosilicas

YANG Qi-Hua ,
LIU Jian ,
ZHONG Hua ,
WANG Pei-Yuan

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State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian116023, China

Received date: 2009-03-05

Revised date: 2009-03-13

Online published: 2009-07-20

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Abstract

The integration of organic and inorganic fragments within the pore wall of the periodic mesoporous organosilicas (PMOs) represents one of the recent breakthroughs in the fields of material science. The organic moieties distributed uniformly in the mesoporous framework will not block the pore, which is beneficial to the diffusion of guest molecule. The surface hydrophilicity/hydrophobicity, mechanical and hydrothermal stability of the PMOs could be easily tuned. The unique features of the PMOs make them attractive in many applications. The recent progresses in the synthesis, characterization and application of the PMOs are summarized, with special emphasis on their applications in catalysis, adsorption, separation, and photoelectricity. The future development of the PMOs is also prospected.

Key words： organic-inorganic; hybrid materials; mesoporous materials; applications

Cite this article

YANG Qi-Hua , LIU Jian , ZHONG Hua , WANG Pei-Yuan . Progress in the Periodic Mesoporous Organosilicas[J]. Journal of Inorganic Materials, 2009 , 24(4) : 641 -649 . DOI: 10.3724/SP.J.1077.2009.00641

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