Adv. Search
Journal of Inorganic Materials

Journal of Inorganic Materials >

2009 , Vol. 24 >Issue 3: 617 - 622

DOI: https://doi.org/10.3724/SP.J.1077.2009.00617

Research Paper

Stress Analysis in the Preparation of Bi-layer Membranes by Co-sintering Process

  • QIU Ming-Hui ,
  • FENG Jun ,
  • FAN Yi-Qun ,
  • XU Nan-Ping
Expand
  • State Key Laboratory of MaterialsOriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China

Received date: 2008-08-19

  Revised date: 2008-10-16

  Online published: 2009-05-20

Fold

Abstract

Based on the theory of “constrained sintering”, stress of the membrane exerted by a rigid substrate was calculated. Results show that the tensile stress from supports can decrease driving force and consequently increase the sintering temperature of supported membranes. The optimal sintering temperatures, 1350℃ and 1180℃ for α-Al2O3 and ZrO2 supported membranes respectively, are determined by combining membrane strength and sintering driving force. Meanwhile, a method is proposed to calculate the stress developed in the co-sintering process of the supported multilayer membrane. For ZrO2/α-Al2O3 bi-layer membrane, the calculated results show that due to the contribution of the compressive stress, the sintering driving force increases and the α-Al2O3 membranes can be sintered effectively after co-sintering at 1200℃. Moreover, the top-layer ZrO2 membrane should be thicker than 10μm so as to exert sufficient compressive stress on the sub-layer α-Al2O3 membrane with thickness of 15μm.

Key words： ceramic membrane; constrained sintering; co-sintering; sintering stress

Cite this article

QIU Ming-Hui , FENG Jun , FAN Yi-Qun , XU Nan-Ping . Stress Analysis in the Preparation of Bi-layer Membranes by Co-sintering Process[J]. Journal of Inorganic Materials, 2009 , 24(3) : 617 -622 . DOI: 10.3724/SP.J.1077.2009.00617

References

［1］Levnen E, Mntyl T A. Journal of the European Ceramic Society, 2002, 22(5):613-623.
［2］Lindqvist K, Liden E. Journal of the European Ceramic Society, 1997, 17(2-3):359-366.
［3］Chang Xianfeng, Zhang Chun, Jin Wanqing, et al. Journal of Membrane Science, 2006, 285(1-2):232-238.
［4］Feng Jun, Fan Yiqun, Qi Hong, et al. J. Membrane Science, 2007, 288(1-2):20-27.
［5］Scherer G W, Garino T. Journal of the American Ceramic Society, 1985, 68(4):216-220.
［6］Garino T J, Bowen H K. Journal of the American Ceramic Society, 1990, 73(2):251-257.
［7］Huang C C, Jean J H. Journal of the American Ceramic Society, 2004, 87(8):1454-1458.
［8］Mohanram A, Lee S H, Messing G L, et al. Journal of the American Ceramic Society, 2006, 89(6):1923-1929.
［9］Lin Y C, Jean J H. Journal of the American Ceramic Society, 2004，87(2): 187-191.
［10］Guillon O, Aulbach E, Rdel J, et al. Journal of the American Ceramic Society, 2007, 90(6):1733-1737.
［11］梁彤翔, 朱钧国, 杨 冰. 硅酸盐学报, 1998, 26(3): 286-291.
［12］Cai P Z, Green D J, Messing G L. Journal of the American Ceramic Society, 1997, 80(8):1929-1939.
［13］Bordia R K, Scherer G W. Acta Metall., 1988, 36(9):2393-2397.
［14］Bordia R K, Scherer G W. Acta Metall., 1988, 36(9):2411-2416.
［15］Bordia R K, Raj R. Journal of the American Ceramic Society, 1985, 68(6):287-293.
［16］冯 君. 多孔陶瓷膜的共烧结制备技术研究.南京: 南京工业大学博士论文, 2007.
［17］Suresh S, Giannakopoulos A E, Olsson M. Journal of the Mechanics and Physics of Solids, 1994, 42(6):979-1018.
［18］Ravi D, Green D J. Journal of the European Ceramic Society, 2005, 26(1-2):17-25.
［19］Cai P Z, Green D J, Messing G L. Journal of the American Ceramic Society, 1997, 80(8):1940-1948.
Options
Outlines

/

〈 〉