Adv. Search
Journal of Inorganic Materials

Journal of Inorganic Materials >

2007 , Vol. 22 >Issue 1: 148 - 152

DOI: https://doi.org/10.3724/SP.J.1077.2007.00148

Research Paper

Preparation, Characterization, and Gas Separation Properties of Polyimide/TiO2 Composite Membranes

  • WANG Mao-Gong ,
  • ZHONG Shun-He
Expand
  • College of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

Received date: 2006-01-04

  Revised date: 2006-04-24

  Online published: 2007-01-20

Fold

Abstract

A series of polyimide/TiO2 composite membranes supported on TiO2 /kieselguhr-mullite (K-M) were prepared via a sol-gel process. Their morphologies, chemical structures, thermal performances, pore distribution and gas permeability were characterized by transmission electron microscope (TEM), Fourier transform infrared (FTIR), solid-state 13C CP/MAS NMR, thermogravimetric analysis (TG/DTA), N2 adsorption and gas permeability measurement. The results show the TiO2 phase is well dispersed in the polyimide matrix. The TiO2 phase is connected with the polyimide through the pendant carboxyl along the polyimide chain. The polyimide/TiO2 composite membrane possesses finely thermal stability. The composite membranes show higher separation properties for H2, CO2, N2 and H2O when compared to pure polyimide. The separation factors of the polyimide/TiO2 composite membranes with 5wt% TiO2 contents for H2/N2, CO2/N2 and H2O/N2 are
64.2, 42.5 and 80.8, respectively.

Key words： polyimide/TiO2; composite materials; sol-gel; gas separation

Cite this article

WANG Mao-Gong , ZHONG Shun-He . Preparation, Characterization, and Gas Separation Properties of Polyimide/TiO2 Composite Membranes[J]. Journal of Inorganic Materials, 2007 , 22(1) : 148 -152 . DOI: 10.3724/SP.J.1077.2007.00148

References

[1] Mustoa P, Ragosta G, Scarinzi G, et al. Polymer, 2004, 45: 4265--4274.
[2] Lin B P, Tang J N, Liu H J, et al. J. Solid State Chem., 2005, 178: 650--654.
[3] Odegard G M, Clancy T C, Gates T S. Polymer, 2005, 46: 553--562.
[4] Joly C, Goizet S, Schrotter J C, et al. J. Membr. Sci., 1997, 130: 63--74.
[5] Kuntman A, Kuntman H. Microelectronics J., 2000, 31: 629--634.
[6] Chang C C, Chen W C. Chem. Mater., 2002, 14: 4242--4248.
[7] Kim H, Jang J. Polymer, 2000, 41: 6553--6561.
[8] Stefanini G. Nucl. Instr. and Meth. A, 2004, 530: 77--81.
[9] Moaddeb M, Koros W J. J. Membr. Sci., 1997, 125: 143--163.
[10] Li C F, Zhong S H. Catal. Today, 2003, 82: 83--90.
[11] Yano S, Iwata K. Mater. Sci. Eng., 1998, C6: 75--90.
[12] Xenopoulos C, Mascia L, Shaw S J. Mater. Sci. Eng., 1998, C6: 99--114.
[13] Ayala D, Lozano A E, de Abajo J, et al. J. Membr. Sci., 2003, 215: 61--73.
[14] Wang Y C, Huang S H, Hu C C, et al. J. Membr. Sci., 2005, 248: 15--25.
[15] Han H, Chung H, Gryte C C, et al. Polymer, 1999, 40: 2681--2685.
[16] Li F, Fang S. Polymer, 1999, 40: 4571--4583.
[17] Fujita H, Kishimoto A. J. Colloid Sci., 1958, 13: 418--428.
[18] Cornelius C J, Marand E. J. Membr. Sci., 2002, 202: 97--118.
[19] 张青红, 高濂, 郭景坤(ZHANG Qing-Hong, et al). 无机材料学报(Journal of Inorganic Materials), 2000, 15 (3): 556--560.
[20] Watanabea T, Nakajima A, Wang R, et al. Thin Solid Films, 1999, 351: 260--263.
[21] Fujishima A, Rao T N, Tryk D A. J. Photochem. Photobio1. C: Potochem. Reviews, 2000, 1: 1--21.
[22] 余家国, 赵修建, 赵青南(YU Jia-Guo, et al). 硅酸盐学报(Journal of the Chinese Ceramic Society), 2000, 28 (3): 245--250.
[23] 罗仲宽, 宋力昕, 李明, 等(LUO Zhong-Kuan, et al). 无机材料学报(Journal of Inorganic Materials), 2004, 19 (6): 1397--1401.
[24] Chiang P C, Whang W T, Tsai M H, et al. Thin Solid Films, 2004, 447-448: 359--364.
[25] Hu Q, Marand E, Dhingra S, et al. J. Membr. Sci., 1997, 135: 65--79.
[26] Liu L, Lu Q H, Yin J, et al. Mater. Chem. Phys., 2002, 74: 210--213.
[27] Chiang P C, Whang W T. Polymer, 2003, 44: 2249--2254.
[28] Hu Q, Marand E. Polymer, 1999, 40: 4833--4843.
[29] Kong Y, Du H W, Yang J R, et al. Desalination, 2002, 146: 49--55.
[30] Zhong S H, Li C F, Xiao X F. J. Membr. Sci., 2002, 199: 53--58.
[31] 李传峰, 钟顺和. 高分子学报, 2002, 3: 326--330.
[32] 郭俊宝, 钟顺和. 催化学报, 2004, 25 (10): 793--796.
[33] Li C F, Zhong S H. J. Membr. Sci., 2002, 204: 89--95.
[34] 李传峰, 钟顺和(LI Chuan-Feng, et al). 硅酸盐通报(Journal of the Chinese Ceramic Society), 2002, 2: 19--23.
[35] Lee L H, Chen W C. Chem. Mater., 2001, 13: 1137--1142.
[36] Guo H X, Zhao X P, Ning G H, et al. Langmuir, 2003, 19: 4884--4888.
[37] Sawada T, Ando S. Chem. Mater., 1998, 10: 3368--3378.
[38] Zhang J, Wang B J, Ju X, et al. Polymer, 2001, 42: 3697--3702.
Options
Outlines

/

〈 〉