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Journal of Inorganic Materials

Journal of Inorganic Materials >

2007 , Vol. 22 >Issue 3: 395 - 399

DOI: https://doi.org/10.3724/SP.J.1077.2007.00395

Research Paper

Fabrication of Tin Dioxide Nanotubes by Anodic Oxidation

  • HAN Wei-Qing ,
  • ZHOU Gang ,
  • WANG Lian-Jun ,
  • SUN Xiu-Yun ,
  • LI Jian-Sheng
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  • School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Received date: 2006-06-07

  Revised date: 2006-09-07

  Online published: 2007-05-20

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Abstract

The formation of tin dioxide nanotubes on tin substrates anodizing in oxalic acid electrolytes and annealing in the air was investigated. Under optimized electrolyte, oxidation and anneal conditions, nanotubes of tin dioxide were fabricated. Topologies of the anodized tin change remarkably along with applied voltages, electrolyte concentration and oxidation time. Field emission scanning electron microscope (FE-SEM), X-ray diffraction (XRD) and poresizer indicate the nanotubes are formed due to the competition of tin monoxide formation and dissolution under the assistance of electric field. The formation mechanism of nanotubes agrees with the theoretic model of oxidation-dissolution.

Key words： anodization; tin dioxide; nanotube

Cite this article

HAN Wei-Qing , ZHOU Gang , WANG Lian-Jun , SUN Xiu-Yun , LI Jian-Sheng . Fabrication of Tin Dioxide Nanotubes by Anodic Oxidation[J]. Journal of Inorganic Materials, 2007 , 22(3) : 395 -399 . DOI: 10.3724/SP.J.1077.2007.00395

References

[1] Wang Y D, Wu X H, Li Y F, et al. J. Solid State Electro, 2004, 48 (5): 627--632.
[2] Michel H J, Leiste H, Halbritter J. J. Sens. ActuatorsB, 1995, 25 (1-3): 568--572.
[3] Pan Q Y, Xu J Q, Dong X W, et al. J. Sens. Actuators B, 2000, 66 (1-3): 237--239.
[4] Idota Y, Kubota T, Matsufuji A, et al. J. Science, 1997, 276: 1395--1397.
[5] Zhu Hongliang, Yang Deren, Yu Guixia, et al. J. Nanotechnology, 2006, 17: 2386--2389.
[6] 陈艳辉, 张兴堂, 薛中会, 等(CHEN Yan-Hui, et al). 无机材料学报(Journal of Inorganic Materials), 2005, 20 (1): 59--64.
[7] Xu C K, Xu G D, Liu Y K, et al. J. Scripta. Materialia, 2002, 46 (11): 789--794.
[8] Sieber I, Hildebrand H, Friedrich A, et al. J. Electrochemistry Communications, 2005, 7: 97--100.
[9] Keller F, Hunter M S, Robinson D L. Journal of the Electrochemical Society, 1953, 100: 411--419.
[10] Hideki Masuda, Kenji Fukuda. Science. 1995, (268): 1466--1468.
[11] Kim Lily, Yoon Seon Mi, Kim Jurea, et al. J. Synthetic Metals, 2004, 140: 135--138.
[12] Jung Sangsuh, Jin Seunglee, Kim Hoseong. J. Synthetic Metal, 2000, 123: 381--383.
[13] 王磊, 杜军, 刑光健, 等. 2004年腐蚀电化学及测试方法学术交流会, 2004. 273--275.
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