Polycarbonate (PC) nanofiber reinforced polymethyl methacrylate (PMMA) transparent composites were developed by combination of co-axial electrospinning and hot-press technique. PMMA shell and PC core composite nanofibers were obtained through the coaxial-electrospinning and the nanofiber membranes were hot pressed into PC nanofiber reinforced PMMA transparent composites. TiO2 nano-particles of different contents were introduced into the shell (PMMA) and the core (PC) part of the composite nanofibers to shield ultraviolet transmittance of the resulting transparent composite. Distributions of the nano-particles in different parts of the core-shell structure of the composite nanofibers were observed, and the nanoparticle influences of different contents and locations on visible light transmittance, ultraviolet radiation shielding and mechanical properties of the composites were analyzed. The results show that the ultraviolet radiation shielding capacity and tensile properties can be enhanced when the nanoparticles are located within the shell part, with a little drop in the visible light transmittance. The nano-particles introduced into the core part induce significant improvement in mechanical performance without obvious impact on the visible light transmittance.
CHEN Lu-Song
,
HUANG Zheng-Ming
,
XUE Cong
. PC Nanofiber Reinforced PMMA Transparent Composites Incorporated with TiO2 NanoParticles[J]. Journal of Inorganic Materials, 2009
, 24(3)
: 469
-474
.
DOI: 10.3724/SP.J.1077.2009.00469
[1]夏和生,王 琪.化学研究与应用,2001,12(6):7-14.
[2]Nussbaumer Rene′ J, Caseri Walter R, Smith Paul, et al. Macromol. Mater. Eng., 2003, 288(1): 44-49.
[3]Liu Xuan-yong, Zhao Xiao-bing, Li Bao-e. Acta Biomaterialia, 2008, 4(3): 544-552.
[4]Kim Jung-Kon, Choi Kyungho, Cho II-Hyoung.Journal of Hazardous Materials, 2007, 148(2): 281-286.
[5]Xiao Guangcan, Wang Xinchen, Li Danzhen. Journal of Photochemistry and Photobiology A: Chemistry, 2007, 193(3): 213-221.
[6]Sakamoto Masashi, Okuda Haruo. Jpn. Soc. Colour Mater., 1995, 168(4): 203-206.
[7]Furusawa Takeshi, Honda Kozue, Ukaji Emi. Materials Research Bulletin, 2008, 43(4):946-957.
[8]Xu Li-xin, Yang Mu-jie. Materials Letters, 2008, 62(17): 2607-2610.
[9]韩晓建,黄争鸣,何创龙(HAN Xiao-Jian, et al). 无机材料学报(Journal of Inorganic Materials),2007,22(3):407-412.
[10]黄争鸣,张彦中. 共轴复合连续纳/微米材料及其制备方法. 中国发明专利:ZL 200310108130.9
[11]陈卢松,黄争鸣,董国华. 航空材料学报,2008,28(1):59-64.
[12]Fong H, Chun I, Reneker D H. Polymer, 1999, 40(16): 4585-4592.
[13]童玉清,田 明,徐瑞芬. 复合材料学报,2003,20(5):88-94.