Cu/SiO2 composite thin films were deposited on n-type Si(111) substrates by radio frequency (RF) magnetron cosputtering method, annealed at high temperature in N2 atmosphere, then cooling and oxidation in the air to fabricate low-dimensionality CuO nanostructure. The microstructure and photo luminescent properties were studied. The main phase of sample is cubic CuO(200) crystal face and sample forms nanoline structure with Cu, O elements as the main components to form CuO/SiO2 composite thin film in the sample surface after annealing at 1100℃. The ultraviolet light and purplelight appear in photoluminescence (PL) spectra, which is abscribed to the electron transition from the defect level,resulting from the Cu vacancies to the conductor band of CuO composite thin films.
SHI Feng
,
LI Yu-Guo
,
SUN Qin-Jun
. Analysis to Microstructure and PhotoLuminescent Properties of CuO/SiO2 Composite Thin Films[J]. Journal of Inorganic Materials, 2009
, 24(2)
: 234
-238
.
DOI: 10.3724/SP.J.1077.2009.00234
[1]王文亮,李东升,王振军,等.无机化学学报,2002,18(8):823-826.
[2]罗元香,李 丹,杨 娟,等.火炸药学报,2002,25(3):53-55.
[3]洪良伟,赵凤起,刘剑洪,等.火炸药学报,2000,23(3):7-9.
[4]Liu X Q, Zhang J, Zhi J Y, et al. Mater.Phys.Mech., 2001,4(1): 85-88.
[5]胥 荣,张桂兰,赵淑玉,等.辽宁大学学报(自然科学版),1999,26(1):48-51.
[6]Liu Z Q, Wang W J, Wang T M,et al. Thin Solid Films,1998, 325(1-2):55-59.
[7]吴志国,张伟伟,白利峰,等.物理学报,2005,54(4):1687-1692.
[8]Chen Y,Zhang L F,Lin J F, et al. Catalytic Science and Technology,1991, 62(8):291-298.
[9]Vijaya Kumar R, Diamant Y, Gedanken A, et al. Chem.Mater., 2000,12(8): 2301-2305.
[10]朱俊武,张维光,王恒志,等.无机化学学报,2004,20(7):864-867.
[11]Ding R Q, Wang H. Chemistry and Physics, 2002,77(3): 841-843.
[12]Wu Dangxin, Zhang Qiming,Tao Meng. Physical Review B,2006, 73: 235206-1-6.