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Journal of Inorganic Materials

Journal of Inorganic Materials >

2009 , Vol. 24 >Issue 2: 349 - 352

DOI: https://doi.org/10.3724/SP.J.1077.2009.00349

Research Paper

Synthesis and Performance of Cathode Material Li3V2(PO4)3/C by Spray Drying and Carbothermal Method （SDATM）

  • YU Feng ,
  • ZHANG Jing-Jie ,
  • YANG Yan-Feng ,
  • SONG Guang-Zhi
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  • 1.Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China; 2.Graduate University of the Chinese Academy of Sciences, Beijing 100049, China

Received date: 2008-05-19

  Revised date: 2008-07-21

  Online published: 2009-03-20

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Abstract

Li-ion battery cathode material Li3V2(PO4)3/C composite was successfully prepared by spray drying and carbothermal method(SDCTM). The effect of spray drying was carefully studied. The structural, morphological and electrochemical properties were investigated by means of XRD, SEM, TEM and constant current chargedischarge cycling. The results indicate that the sample prepared with spray drying twice at 260℃ and subsequent heat-treating at 750℃ for 12h has better performance. Its average particle size is under 0.5μm.It presents large reversible discharge capacity of 121.9, 114.6 and 104.6mAh·g-1 and excellent capacity retention rate closed to 100% after 50 cycles at C/5, 1C and 5C rate, respectively at the room temperature.

Key words： Li3V2(PO4)3/C; cathode material; spray drying; carbothermal method

Cite this article

YU Feng , ZHANG Jing-Jie , YANG Yan-Feng , SONG Guang-Zhi . Synthesis and Performance of Cathode Material Li3V2(PO4)3/C by Spray Drying and Carbothermal Method （SDATM）[J]. Journal of Inorganic Materials, 2009 , 24(2) : 349 -352 . DOI: 10.3724/SP.J.1077.2009.00349

References

［1］Scrosati B. Nature， 1995, 373(16):557-558.
［2］Whittingham M S. Chem. Rev., 2004, 104(10):4271-4301.
［3］Padhi A K, Nanjundaswamy K S, Goodenough J B. J. Electrochem. Soc., 1997, 144(4):1188-1194.
［4］刘素琴, 李世彩, 唐联兴,等(LIU Su-Qin, et al). 无机化学学报(Chinese Journal of Inorganic Chemistry), 2006, 22(4):645-650.
［5］Nanjundaswamy K S, Padhi A K, Goodenough J B, et al. Solid State Ionics， 1996, 92(1-2):1-10.
［6］Gaubicher J, Wurm C, Goward G, et al. Chem. Mater., 2000, 12(11):3240-3242.
［7］Yin S C, Grondey H, Strobel P, et al. J. Am. Chem. Soc., 2003, 125(34):10402-10411.
［8］Saidi M Y, Barker J, Huang H, et al. J. Power Sources, 2003, 119(SI):266-272.
［9］Barker J, Saidi M Y, Swoyer J L. J. Electrochem. Soc., 2003, 150(6):A684-A688.
［10］Fu P, Zhao Y M, Dong Y Z, et al. J. Power Sources, 2006, 162(1):651-657.
［11］Ren M M, Zhou Z, Li Y Z, et al. J. Power Sources， 2006, 162(2):1357-1362.
［12］刘素琴, 唐联兴, 黄可龙, 等(LIU Su-Qin, et al). 中国有色金属学报(The Chinese Journal of Nonferrous Metals), 2005, 15(8):1294-1299.
［13］Huang H, Yin S C, Kerr T, et al. Adv. Mater., 2002, 14(21):1525-1528.
［14］Li Y Z, Zhou Z, Ren M M, et al. Electrochim. Acta.， 2006, 51(28):6498-6502.
［15］Chen Q Q, Wang J M, Tang Z, et al. Electrochim. Acta., 2007, 52(16):5251-5257.
［16］Li Y Z, Zhou Z, Gao X P, et al. Electrochim. Acta., 2007, 52(15):4922-4926.
［17］Yu F, Zhang J J, Yang Y F, et al. Journal of Wuhan University of TechnologyMater. Sci. Ed., 2007, 22(B12):853-855.
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