Nano-structured onion-like fullerenes (NSOFs) were synthesized from C2H2 carbon black/ferrocene by microwave plasma. High resolution transmission electron microscope (HRTEM), Raman and X-ray diffraction (XRD) techniques were used to characterize the morphologies and structures of the products. Results indicated that NSOFs could be prepared from C2H2 carbon black/ferrocene. The particles displayed a clear polyhedral or spherical morphology, with cores and waving out layers.
FU Dong-Ju
,
LIU Xu-Guang
,
DU Ai-Bing
,
HAN Pei-De
,
JIA Hu-Sheng
,
XU Bing-She
. Synthesis of Nano-structured Onion-like Fullerenes by MW Plasma[J]. Journal of Inorganic Materials, 2006
, 21(3)
: 576
-582
.
DOI: 10.3724/SP.J.1077.2006.00576
1 Kroto H W, Heath J R, Brien S C O, et al. Nature, 1985, 318: 162-164.
2 Kroto H W. Nature, 1992, 359: 670-671.
3 Xu B S, Tanaka S-I. Acta Mater., 1998, 46(15): 5249-5257.
4 Brunsman E M, Sutton R, Bortz E, et al. J. Appl. Phys., 1994, 75: 5882-5884.
5 Chen X H, Deng F M, Wang J X, et al. Chem. Phys. Lett., 2001, 336: 201-204.
6 Tsai S H, Lee C L, Chao C W, et al. Carbon, 2000, 38: 775-785.
7 石玉龙, 姜丰(Shi Yu-Long, et al). 无机材料学报(Journal of Inorganic Materials), 2004, 19(1): 253-256.
8 杜爱兵, 刘旭光, 许并社(Du Ai-Bing, et al). 无机材料学报(Journal of Inorganic Materials), 2005, 20(4): 779-784.
9 Donnet J B, Johnson M P, Norman D T, et al. Carbon, 2000, 38: 1885-1886.
10 Buchholz D B, Doherty S J, Chang R P H. Carbon, 2003, 41: 1625-1634.
11 Tuinstra F, Koenig J L. J. Chem. Phys., 1970, 53: 1126-1130.
12 Hiura H, Ebbesen T W, Tanigaki K, et al. Chem. Phys. Lett., 1993, 202: 509-512.
13 王晓敏, 刘旭光, 张艳, 等. 物理化学学报, 2004, 20(7): 731-734.
14 Ugarte D. Carbon, 1995, 33: 989-993.
15 李志飞, 罗国华, 魏飞, 等. 催化学报, 2002, 23: 173-178.