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Journal of Inorganic Materials

Journal of Inorganic Materials >

2025 , Vol. 40 >Issue 5: 457 - 465

DOI: https://doi.org/10.15541/jim20240413

RESEARCH ARTICLE

Iron-doped Nano-hydroxyapatite: Preparation and Ultraviolet Absorption Performance

  • AN Ran ,
  • LIN Si ,
  • GUO Shigang ,
  • ZHANG Chong ,
  • ZHU Shun ,
  • HAN Yingchao
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  • 1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
    2. Shandong Zhushi Pharmaceutical Group Co., Ltd., Heze 274300, China
AN Ran (2000-), male, Master candidate. E-mail: ar17864218908@163.com
HAN Yingchao, professor. E-mail: hanyingchao@whut.edu.cn

Received date: 2024-09-18

  Revised date: 2024-12-08

  Online published: 2024-12-27

Supported by

Shandong Provincial Development and Reform Commission Talent Program

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Abstract

Nano-hydroxyapatite (nHAP) possesses both biocompatibility and environmental friendliness, and holds the potential to become a novel ultraviolet (UV) absorbent material following iron doping modification. This study employed co-precipitation and hydrothermal methods to prepare iron-doped nano-hydroxyapatite (Fe-nHAP). Influence of the preparation process on UV absorption performance was investigated by adjusting reaction time, temperature, and iron doping ratio. The results indicate that with the increase of temperature from 37 ℃ to 150 ℃ or the extension of reaction time from 0.5 h to 3 h, both the crystallinity and the peak of UV absorption improve. It can be inferred that there is a certain positive correlation between the UV absorption performance and crystallinity of Fe-nHAP. Additionally, the UV absorption capacity is closely correlated to the iron doping ratio. As the iron doping molar ratio increases from 0 to 10%, the UV absorption capacity is gradually enhanced, with the maximum absorption value rising from 0.03 to 1.35. This phenomenon is attributed to the reduction in optical bandgap caused by iron doping. However, a high iron doping ratio leads to excessive reduction in material crystallinity, resulting in weakened enhancement of UV absorption performance. The safety assessment indicates that Fe-nHAP with an iron doping molar ratio of 7% does not demonstrate cytotoxicity, phototoxicity and skin irritation. In summary, Fe-nHAP has a suitable UV absorption performance. With its favorable biosecurity, it is anticipated to emerge as a new type of UV absorption material.

Key words： nano-hydroxyapatite; iron doping; ultraviolet absorption

Cite this article

AN Ran , LIN Si , GUO Shigang , ZHANG Chong , ZHU Shun , HAN Yingchao . Iron-doped Nano-hydroxyapatite: Preparation and Ultraviolet Absorption Performance[J]. Journal of Inorganic Materials, 2025 , 40(5) : 457 -465 . DOI: 10.15541/jim20240413

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