High quality Nd∶Lu3Al5O12(Nd∶LuAG) crystal doped with 1at% Nd3+ was grown by the Czochralski method. The spectral properties of the crystal annealed in different atmosphere were characterized. The experiment indicates that the absorption band in 256nm, 467nm and 562nm are connected with Fe3+, O-, and F+, respectively. The absorption cross section at 809nm is 1.86×10-20 cm2. The spectral parameters are calculated by JuddOfelt theory, and the intensity parameters Ω2, Ω4 and Ω6 are estimated to be 0.71×10-20cm2, 1.13×10-20 cm2, and 4.36×10-20 cm2, respectively. The calculated radiative probabilities, branch ratios, radiative lifetime and emission cross section are evaluated for the 4F3/2 excited state by using the calculated intensity parameters. The results indicate that Nd∶LuAG crystal is a promising material for solidstate laser application.
WANG Xiao-Dan
,
XU Xiao-Dong
,
ZANG Tao-Chen
,
MA Chun-Lan
,
ZHAO Zhi-Wei
,
XU Jun
. Growth and Spectral Properties of Nd∶Lu3Al5O12 Crystal[J]. Journal of Inorganic Materials, 2010
, 25(4)
: 435
-440
.
DOI: 10.3724/SP.J.1077.2010.00435
[1]张怀金, 蒋民华(ZHANG Huai-Jin, et al). 新型激光晶体材料研究进展. 无机材料学报(Journal of Inorganic Materials), 2008, 23(3): 417-424.
[2]王晓丹, 赵志伟, 王静雅, 等(WANG Xiao-Dan, et al). 热键合制作Yb :Y3Al5O12/ Y3Al5O12复合晶体. 无机材料学报(Journal of Inorganic Materials), 2008, 23(1): 125-129.
[3]杨心波, 李红军, 毕群玉, 等(YANG Xin-Bo, et al). 导模法生长Al2O3:C晶体.无机材料学报(Journal of Inorganic Materials), 2009, 24(2): 255-258.
[4]Liu Fengqin, He Jingliang, Zhang Baitao, et al. Diodepumped passively Q-switched Nd:LuVO4 laser at 1.34μm with a V3+:YAG saturable absorber. Opt. Express, 2008, 16(16): 11759-11763.
[5]Chen F, Yu X, Gao J, et al. Efficient generation of 914nm laser with high beam quality in Nd∶YVO4 crystal pumped by πpolarized 808nm diodelaser. Laser Phys. Lett., 2008, 5(9): 655-658.
[6]任国光,黄裕年.二极管抽运固体激光器迈向100kW.激光与红外, 2006, 36(8): 617-622.
[7]Xu X D, Wang X D, Meng J Q, et al. Crystal growth, spectral and laser properties of Nd∶LuAG single crystal. Laser Phys. Lett., 2009, 6(9): 678-681.
[8]杨培志, 邓佩珍, 殷之文. Yb:YAG晶体中的荧光浓度猝灭现象. 发光学报, 1999, 20(4): 325-329.
[9]Ashurov M K, Rakov A F, Erzin R A. Luminescence of defect centers in yttriumaluminum garnet crystals. Solid State Commun., 2001, 120(12): 491-494.
[10]蒋成勇, 周国清, 姜雄伟, 等.飞秒脉冲激光对YAG晶体的辐照作用的研究.光学学报, 2003, 23(10):1273-1276.
[11]Mare J A, echov N, Nikl M, et al. Ceriumdoped RE3+AlO3 perovskite scintillators: Spectroscopy and radiation induced defects. Journal of Alloys and Compounds, 1998, 275-277: 200-204.
[12]Zeng Xionghui, Zhao Guangjun, Xu Jun, et al. Effects of annealing on the color, absorption spectra, and light yield of Ce:YAlO3 single crystal grown by the temperature gradient technique. Journal of Applied Physics, 2004, 95(2): 749-751.
[13]Wang Guofu. Opticaltransition probability of the Nd3+ ion in GdAl3(BO3)4 crystal. J.Opt. Soc. Am.B, 2001,18(2): 173-175.
[14]Krupke W F. Radiative transition probabilities within the 4f3 ground configuration of Nd:YAG. IEEE J. Quantum Electron, 1971, 7(4): 153-159.
[15]Cavalli E, Zannoni E, Belletti A, et al. Spectroscopic analysis and laser parameters of Nd3+ in Ca3Sc2Ge3O12 garnet crystals. Appl. Phys. B, 1999, 68(4): 677-681.
[16]Jaque D, Capmany J, Luo Z D, et al. Optical bands and energy levels of Nd3+ ion in the YAl3(BO3)4 nonlinear laser crystal. J. Phys.: Condens. Matter, 1997, 9(44): 9715-9729.
[17]Han X, Wang G F. Crystal growth and spectral properties of Nd3+:KY(WO4)2 crystal. J Cryst. Growth, 2003, 247(3/4): 551-554.
[18]Cavalli E, Zannoni E, Mucchino C, et al. Optical spectroscopy of Nd 3+ in KLa(MoO 4)2 crystals. J. Opt. Soc. Am. B, 1999, 16(11):1958-1965.
[19]冉栋刚, 夏海瑞, 吕英波, 等. Nd:LuVO4晶体光谱参数的计算及其分析.人工晶体学报, 2005, 34(1):17-20.
[20]Ermeneux F S, Goutaudier C, Monxorge R, et al. Multiphonon relaxation in YVO4 single crystals. Phys. Rev. B, 2000, 61(6): 3915-3921.