Research Paper

Preparation, Characterization and Catalysis Properties of Ag/SBA-15 Nanocomposite by Supercritical Fluid Deposition

  • YIN Jian-Zhong ,
  • ZHANG Chuan-Jie ,
  • XU Qin-Qin ,
  • WANG Ai-Qin
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  • 1. School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China; 2. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China

Received date: 2008-03-27

  Revised date: 2008-06-30

  Online published: 2009-01-20

Abstract

Ag/SBA-15 nanocomposite was prepared by supercritical fluid deposition (SCFD) method, with AgNO3 as the precursor and ethanol or glycol as the cosolvent. AgNO3 was firstly deposited onto the SBA-15 support at 50℃, 23-25MPa, and reacted for 3-24h. The resultant composite was then subjected to calcination and reduction treatment for obtaining Ag/SBA-15 nanocomposite. Characterizations with XRD and TEM show that Ag nanoparticles (with sizes of 3-7nm) or nanowires (5-9nm in width and tens of nanometers to several micrometers in length) are formed in the nanochannels of SBA-15 support. It is demonstrated that SCFD is a green and effective method for preparation of nanocomposite. With the aid of cosolvent, the supercritical carbon dioxide can dissolve the inorganic metallic salts. Moreover, the morphologies of the nanocomposite can be controlled to some extent by selecting the deposition conditions. A catalytic test on the Ag/SBA-15 nanocomposite shows that the sample has a moderate activity, with the complete conversion of CO at 300℃.

Cite this article

YIN Jian-Zhong , ZHANG Chuan-Jie , XU Qin-Qin , WANG Ai-Qin . Preparation, Characterization and Catalysis Properties of Ag/SBA-15 Nanocomposite by Supercritical Fluid Deposition[J]. Journal of Inorganic Materials, 2009 , 24(1) : 129 -132 . DOI: 10.3724/SP.J.1077.2009.00129

References

1]Watkins J J, McCarthy T J. Chem. Mater., 1995, 7(11): 1991-1994.
[2]徐琴琴,银建中,肖 敏,等.化学通报,2007, 70(3):188-194.
[3]Saquing C, Cheng T T, Aindow M, et al. J. Phys. Chem. B, 2004, 108(23): 7716-7722.
[4]Zhang Y, Kang D, Saquing C, et al. Ind. Eng. Chem. Res.,2005, 44(11): 4161-4164.
[5]Zhang Y, Erkey C. Ind. Eng. Chem. Res.,2005, 44 (14): 5312-5317.
[6]Zhang Y, Kang D, Aindow M, et al. J. Phys. Chem. B, 2005, 109(7):2617-2624.
[7]Haji S, Zhang Y, Kang D, et al. Catal. Today, 2005, 99 (3-4): 365-373.
[8]Yoda S, Takebayashi Y, Sugeta T, et al. J. Non-Cryst. Solids, 2004, 350(15): 320-325.
[9]Ye X R, Lin Y H, Wang C M, et al. J. Mater. Chem.,2004, 14(5): 908-913.
[10]Ye X R, Lin Y H, Wai C M. Chem. Commun., 2003, 9(5):642-643.
[11]Yen C H, Shimizu K, Lin Y Y, et al. Energy Fuels.,2007, 21(4):2268-2271.
[12]徐琴琴. 超临界流体沉积法制备纳米复合材料. 大连理工大学硕士论文, 2007.
[13]Huang M H, Choudrey A, Yang P D. Chem. Commun., 2000, 6(12): 1063–1064.
[14]天津市化工研究院等编. 无机盐工业手册, 第一版.北京, 化学工业出版社, 1979:878-884.
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