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Journal of Inorganic Materials

Journal of Inorganic Materials >

2009 , Vol. 24 >Issue 1: 23 - 28

DOI: https://doi.org/10.3724/SP.J.1077.2009.00023

Research Paper

Synthesis of Ordered Mesoporous Carbons Using Resorcinol-Formaldehyde Sol as the Carbon Source and As-synthesized MCM-48 as the Template

  • WANG Chong-Qing ,
  • SONG Jun ,
  • YAO Jian-Feng ,
  • LI Qing ,
  • ZHANG Li-Xiong ,
  • LIU Xiao-Qin ,
  • LU Xian-Cai
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  • 1. State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China; 2. Department of Earth Sciences, Nanjing University, Nanjing 210093, China

Received date: 2008-01-18

  Revised date: 2008-05-16

  Online published: 2009-01-20

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Abstract

Ordered mesoporous carbons were synthesized by using as-synthesized MCM-48 as the template and resorcinol (R)-formaldehyde sol as the carbon precursor. By changing the molar ratio of resorcinol (R) to template (w(R)/w(MCM-48)) and resorcinol (R) to water(w(R)/w(H2O)), mesoporous carbons with different porosities were produced. The obtained samples were characterized by N2 adsorption-desorption, X-ray diffraction, scanning electron microscopye, transmission electron microscopye and thermogravimetric analysis. It is found that the optimized w(R)/w(MCM-48) and w(R)/w(H2O) ratios are in the rang from 0.50 to 0.65 and from0.15 to 0.35, respectively, and the resulting ordered mesoporous carbons has BET specific surface areas greater than 1125m2/g, mean pore sizes from 2.2 to 2.4nm, and high thermal stability.

Key words： mesoporous carbon; MCM-48; resorcinol; formaldehyde

Cite this article

WANG Chong-Qing , SONG Jun , YAO Jian-Feng , LI Qing , ZHANG Li-Xiong , LIU Xiao-Qin , LU Xian-Cai . Synthesis of Ordered Mesoporous Carbons Using Resorcinol-Formaldehyde Sol as the Carbon Source and As-synthesized MCM-48 as the Template[J]. Journal of Inorganic Materials, 2009 , 24(1) : 23 -28 . DOI: 10.3724/SP.J.1077.2009.00023

References

［1］Lee J, Han S J, Hyeon T. J. Mater. Chem., 2004, 14(4): 478-486.
［2］Ryoo R, Joo S H, Jun S. J. Phys. Chem. B, 1999, 103 (37): 7743-7746.
［3］Ryoo R, Joo S H, Kruk M. Adv. Mater., 2001, 13 (9): 677-681.
［4］Joo S H, Jun S, Ryoo R. Micropor. Mesopor. Mater., 2001, 44-45: 153-158.
［5］Kaneda M, Tsubakiyama T, Carlsson A, et al. J. Phys. Chem. B., 2002, 106 (6): 1256-1266.
［6］黄 莉，王重庆，李 青，等. 林产业化学与工业, 2007, 27 (2): 57-61.
［7］曾昌凤，李 青，王重庆，等. 林产业化学与工业, 2007, 27 (3): 87-92.
［8］Lee J, Yoon S, Hyeon T, et al. Chem. Commun., 1999: 2177-2178. ［9］Yoon S B, Kim J Y, Yu J S. Chem. Commun., 2001: 559-560.
［10］Lee J, Yoon S, Oh S M, et al. Adv. Mater., 2000, 12 (5): 359-362. ［11］Parmentier J, Saadhallah S, Reda M, et al. J. Phys. Chem. Solids., 2004, 65 (2-3): 139-146.
［12］Anhui L, Kiefer A, Schmidt W, et al. Chem. Mater., 2004, 16 (1), 100-103.
［13］Yoon S B, Kim J Y, Yu J S. Chem. Commun., 2002: 1536-1537.
［14］蔡 强，张慧波，林文勇，等. 高等学校化学学报, 1999, 20 (5): 675-678.
［15］王冬林，李 青，曾昌凤，等. 南京工业大学学报，2006, 28 (1): 89-92.
［16］Lee K T, Oh S M. Chem. Commun., 2002: 2722-2733.
［17］Tanaka S, Nishiyama N, Egashira Y, et al. Chem. Commun., 2005: 2125-2127.
［18］Kim S, Pinnavaia T J. Chem. Commun., 2001: 2418-2419.
［19］Sayari A. J. Am. Chem. Soc., 2002, 122 (22): 6504-6505.
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