Research Paper

Effect of Content of Poly(aniline-co-o-anisidine) on Structure and Properties of Intercalated Graphite Oxide Composites

  • YE Jian-Kun ,
  • WANG Geng-Chao ,
  • YAO Bin ,
  • LI Xing-Wei
Expand
  • School of Materials Science & Engineering, Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science & Technology, Shanghai 200237, China

Received date: 2007-09-28

  Revised date: 2007-11-22

  Online published: 2008-09-20

Abstract

Aniline/o-anisidine copolymer (P(An-co-oAs)) intercalated graphite oxide (GO) composites were synthesized through the delamination/reassembling method using GO as host and conducting P(An-co-oAs) as guest. FTIR spectra indicate that the hydrogen bonds are formed between the amino groups of P(An-co-oAs) and the carbonyl groups on the internal layers of GO. XRD and TEM results show that the P(An-co-oAs)/GO composites maintain good lamellar structure, and the interlayer spacing of GO is enlarged with the increase of the added amount of P(An-co-oAs). The electrical conductivity of the composites is 2 to 3 orders of magnitude higher than that of the GO. The intercalation of P(An-co-oAs) also has a pronounced effect on the electrochemical properties of the GO.

Cite this article

YE Jian-Kun , WANG Geng-Chao , YAO Bin , LI Xing-Wei . Effect of Content of Poly(aniline-co-o-anisidine) on Structure and Properties of Intercalated Graphite Oxide Composites[J]. Journal of Inorganic Materials, 2008 , 23(5) : 945 -949 . DOI: 10.3724/SP.J.1077.2008.00945

References

[1] Wu C G, DeGroo D C, Marcy H O. Chem. Mater., 1996, 8 (8): 1992--2004.
[2] Leroux F, Goward G, Power W P. J. Electrochem. Soc., 1997, 144 (11): 3886--3895.
[3] Wu C G, DeGroot D C, Marcy H O, et al. J. Am. Chem. Soc., 1995, 117 (12): 9229--9242.
[4] Huguenin F, dos Santos D S, Bassi A, et al. Adv. Funct. Mater., 2004, 14 (10): 985--991.
[5] Li Z F, Ruckenstein E. Langmuir, 2002, 18 (18): 6956--6961.
[6] Huguenin F, Torresi R M, Buttry D A. J. Electrochem. Soc., 2002, 149 (5): A546--553.
[7] Zhao J, Wang G C, Li X W, et al. J. Appl. Polym. Sci., 2007, 103 (4): 2569--2574.
[8] Higashika S, Kimura K, Matsuo Y, et al. Carbon, 1999, 37 (2): 351--358.
[9] Liu Z H, Wang Z M, Yang X, et al. Langmuir, 2002, 18 (12): 4926--4932.
[10] Liu P, Gong K, Xiao P, et al. J. Mater. Chem., 2000, 10 (4): 933--935.
[11] Matsuo Y, Hatase K, Sugie Y. Chem. Mater., 1998, 10 (8): 2266--2269.
[12] 刘平桂, 龚克成. 高分子学报, 2000, (4): 492--495.
[13] Cassagneau T, Fendler J H. Adv. Mater., 1998, 10 (11): 877--881.
[14] Wang G C, Yang Z Y, Li X W, et al. Carbon, 2005, 43 (12): 2564--2570.
[15] Cao Y, Andriatta A, Heeger A J, et al. Polymer, 1989, 30 (12): 2305--2311.
[16] Hummers W S, Offeman R E. J. Am. Chem. Soc., 1958, 80 (6): 1339.
[17] Sasaki T, Watanabe M. J. Am. Chem. Soc., 1998, 120 (19): 4682--4689.
Outlines

/