N/I silicon thin films were deposited on amorphous silicon thin film coated quartz substrate by radio frequency plasma enhanced chemical vapor deposition(RF-PECVD)system at low temperature, and subsequently annealed by two-step rapid thermal processing (RTP). Through Raman scattering, X-Ray diffraction (XRD), scanning electron microscope(SEM) and transmittance electron microscope (TEM) measurement, the crystallization and morphologies of the sample were investigated. The results show that the crystallinity of the N/I silicon thin films reaches about 94% after being annealed. The cross sectional morphology of the N/I silicon thin films is of columnar grains and the average grain size of the sample is about 30nm while the biggest grain cluster is about 1.5μm in landscape orientation.
ZHANG Li-Wei
,
ZHOU Ling-Li
,
LI Rui
,
LI Hong-Ju
,
LU Jing-Xiao
. Fabrication of Polycrystalline Silicon Films with Columnar Grains Structure on Quartz[J]. Journal of Inorganic Materials, 2008
, 23(2)
: 369
-372
.
DOI: 10.3724/SP.J.1077.2008.00369
[1] 王宗畔, 董贵元, 杨连华, 等. 中国太阳能光伏进展. 成都: 西南交通大学出版社, 2006, 119--121.
[2] Green M A. Solar Energy, 2003, 74: 181--192.
[3] Cuevas A, Macdonald D. 15th international Photovoltaic Science and Engineering Conference, Shanghai China, 2005. 521--524.
[4] Widenborg P I, Armin G A. Journal of Crystal Growth, 2002, 242: 270--282.
[5] Armin G. A. Journal of Crystal Growth, 2006, 287: 386--390.
[6] Kondo M. Solar Energy Materials and Solar Cells, 2003, 78: 543--566.
[7] Matsuyama T, Terada N, Baba T, et al. Journal of Non-Crystalline Solids, 1996, 198--200: 940--944.
[8] CzigaAny Zs, RadnoAczi G. Thin Solid Films, 1999, 347: 133--145.
[9] JIN Rui-Min, LU Jing-xiao, FENG Tuan-hui, et al. Journal of Synthetic Crystals, 2006, 35 (1): 104--106.
[10] Terry M L, Straub A, Inns D, et al. Conference Record of the 31{ st IEEE Photovoltaic Specialists Confenrence, 2005. 971--974.
[11] 董会宁, 杜开瑛, 谢茂浓. 四川大学学报(自然科学版), 1995, 32 (1): 95--97.
[12] 卢景霄, 张宇翔, 王海燕, 等. 太阳能学报, 2006, 27 (5): 444--449.
[13] 张丽伟, 卢景霄, 李 瑞, 等. 人工晶体学报, 2005, 34 (5): 940--943.
[14] 张丽伟, 赵新蕖, 卢景霄, 等. 人工晶体学报, 2006, 35 (5): 1159--1162.
[15] Zhang Li-wei, Lu Jing-xiao, Li Rui, et al. 15th international Photovoltaic Science and Engineering Conference, Shanghai China, 2005. 792--793.
[16] 冯团辉, 卢晶霄, 张宇翔, 等. 人工晶体学报, 2005, 34 (2): 353--358.
[17] 李青山, 张金朝, 宋 鹏, 等.华东理工大学学报, 2002, 28 (2): 184--224.