Low resistivity transparent conducting ZnxCd1-xO films were deposited on flexible Polyethylene Terephthalate(PET) substrates by DC magnetron sputtering. Structural, electrical, and optical properties of the films with different Zn concentrations were investigated. XRD results show that for x0.5, the structure of the film is in CdO phase, while for x>0.5, oriented ZnO phase is dominant. Hall results shows that the ZnxCd1-xO films has very high carrier concentration when x≤0.5, and the electrical resistivitiy of the films is at the order of 10-3Ω·cm. Carrier mobility shows a maximum value at x=0.5. The transmittance of the ZnxCd1-xO films in the visible range is much higher than that of pure CdO film. It’s concluded that x=0.5 is the optimal value at which low electrical resistive, high visible transmittance ZnxCd1-xO films can be deposited at low temperature on flexible substrates.
JI Zhen-Guo
,
CHEN Ming-Mei
,
ZHANG Pin
,
ZHOU Qiang
. Deposition of Low Resistive Transparent Conducting ZnxCd1-xO Films on Flexible PET Substrate at Low Temperature[J]. Journal of Inorganic Materials, 2008
, 23(2)
: 361
-363
.
DOI: 10.3724/SP.J.1077.2008.00361
[1] Shan F K, Yu Y S. J. Eur. Ceram. Soc., 2004, 24 (6): 1869--1872.
[2] Schmid W, Barsan N, Weimar U. Sensors and Actuators B, 2003, 89 (3): 232--236.
[3] Lee Seung-Chul, Lee Jae-Ho, Oh Tae-Sung, et al. Solar Energy Materials and Solar Cells, 2003, 75 (3-4): 481--487.
[4] Raghunath Reddy S, Mallik A K, Jawaleker S R. Thin Solid Films, 1986, 143 (2): 113--118.
[5] 李巍, 靳正国, 刘志锋, 等(LI Wei, et al). 无机材料学报(Journal of Inorganic Materials), 2006, 21 (2): 473--480.
[6] de Carvalho CN, Luis A, Lavareda G, et al. Surface and Coatings Technology, 2002, 151: 252--256.
[7] Wonsuk Chung, Michael O. Thompson. Thin Solid Films, 2004, 460 (1-2): 291--294.
[8] Yang T L, Zhang D H, Ma J, et al. Thin Solid Films, 1998, 326 (1-2): 60.
[9] Fortunato E, Nunes P, Costa D, et al. Vacuum, 2002, 64 (3-4): 233--236.
[10] Nomura K, Ohta H, Takagi A, et al. Nature, 2004, 432 (7016): 488--492.
[11] Lee J G, Seol Y G, Lee N E. Thin Solid Films, 2006, 515 (2): 805--809.
[12] Grego Sonia, Lewis Jay, Vick Erik, et al. Thin Solid Films, 2007, 515 (11): 4745--4752.
[13] Zhou Qiang, Ji Zhenguo, Hu Binbin, et al. Materials Letters, 2007, 61 (2): 531--534