Adv. Search
Journal of Inorganic Materials

Journal of Inorganic Materials >

2007 , Vol. 22 >Issue 5: 937 - 942

DOI: https://doi.org/10.3724/SP.J.1077.2007.00937

Research Paper

Influence of Factors on Porous TiO2 Films Prepared at Room Temperature

  • SHEN Qian-Hong ,
  • CAI Zhen-Qian ,
  • GAO Ji-Wei ,
  • YANG Hui
Expand
  • (1. College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, China; 2. Green Construction Materials and Applied Technology Engineering Research Center, Zhejiang University, Hangzhou 310027, China)

Received date: 2006-10-17

  Revised date: 2006-11-19

  Online published: 2007-09-20

Fold

Abstract

A solution consisting of styrene-acrylate spheres and anatase TiO2 colloidal particles was synthesized. The films were
prepared from resultant solution by a dip-coating technique, and then styrene-acrylate spheres were preferentially dissolved in toluene, and the porous anatase TiO2 films were obtained at room temperature. Transmission electron microscope (TEM)
and scanning electron microscope (SEM) were adopted to analyze the influence of the styrene-acrylate emulsion consumption, the dosage of TiO2 sol, the aging time of the solutions and the conditions of eliminating styrene-acrylate spheres
on the morphology of the films. The results show that the mass ratio of TiO2 sol and styrene-acrylate emulsion affects the morphology of the pores; the aging time is a dominant factor for the formation of the dense pores on the surface;
styrene-acrylate spheres can be eliminated effectively by the ultrasonic oscillation. The results also indicate that the appropriate proportion is: 15g TiO2 sol+0.2g styrene-acrylate emulsion+10g H2O; the solutions are aged for 15d, and the films are soaked into toluene and vibrated by ultrasonic for 10min.

Key words： titania film; porosity; styrene-acrylate emulsion; room-temperature preparation

Cite this article

SHEN Qian-Hong , CAI Zhen-Qian , GAO Ji-Wei , YANG Hui . Influence of Factors on Porous TiO2 Films Prepared at Room Temperature[J]. Journal of Inorganic Materials, 2007 , 22(5) : 937 -942 . DOI: 10.3724/SP.J.1077.2007.00937

References

[1] Wark M, Tschirch J, Bartels O, et al. Microporous Mesoporous Mat., 2005, 84 (1-3): 247--253.
[2] Guo B, Liu Z L, Hong L, et al. Surf. Coat. Technol., 2005, 198 (1-3): 24--29.
[3] 何 俣, 朱永法, 喻 方(He Yu, et al). 无机材料学报(Journal of Inorganic Materials), 2004, 19 (2): 385--390.
[4] Trapalis C C, Keivanidis P, Kordas G, et al. Thin Solid Films, 2003, 433 (1-2): 186--190.
[5] Yusuf M M, Imai H, Hirashima H. J. Non-Cryst Solids, 2001, 285 (1-3): 90--95.
[6] 余家国, 赵修建(YU Jia-Guo, et al). 无机材料学报(Journal of Inorganic Materials), 2000, 15 (2): 347--355.
[7] Liu K S, Fu H G, Shi K Y, et al. J. Phys. Chem. B., 2005, 109 (40): 18719--18722.
[8] Hsu C S, Lin C K, Chan C C, et al. Thin Solid Films, 2006, 494 (1-2, 3): 228--233.
[9] Tatsuma T, Lkezawa A, Ohko Y, et al. Adv. Mater., 2000, 12 (9): 643--646.
[10] 胡行方, 快素兰, 于 云, 等(HU Xing-Fang, et al). 无机材料学报(Journal of Inorganic Materials), 2005, 20 (6): 1463--1466.
[11] Doherty S, Fitzmaurice D. J. Phys. Chem., 1996, 100 (25): 10732--10738.
[12] Stathatos E, Lianos P, Falaras P, et al. Langmuir, 2000, 16 (5): 2398--2400.
[13] Karuppuchamy S, Nonomura K, Yoshida T, et al. Solid State Ionics, 2002, 151 (1-4): 19--27.
[14] Subramanian G, Manoharan V N, Thorne J D, et al. Adv. Mater., 1999, 11 (15): 1261--1265.
[15] Kuai S L, Badilescu S, Bader G, et al. Adv. Mater., 2003, 15 (1): 73--75.
[16] Shimizu K, Imai H, Hirashima H, et al. Thin Solid Film, 1999, 351 (1-2): 220.
[17] Gutiérrez-Tauste D, Zumeta I, Vigil E, et al. J. Photochem. Photobiol. A-Chem., 2005, 175 (2-3): 165--171.
[18] Zhang D S, Yoshida T, Minoura H. Adv. Mater., 2003, 15 (10): 814--817.
[19] 方 明, 高基伟, 申乾宏, 等(FANG Ming, et al). 硅酸盐学报(Journal of the Chinese Ceramic Society), 2006, 34 (4): 438--441.
[20] 杨 辉, 申乾宏, 高基伟. 催化学报, 2005, 26 (10): 839--841.
Options
Outlines

/

〈 〉