Journal of Inorganic Materials

• Research Paper • Previous Articles     Next Articles

Spectroscopic Properties and Thermal Stability of Er3+-Doped FluorideLead Silicate Glasses

XU Shi-Qing; YANG Zhong-Min; DAI Shi-Xun; HU Li-Li; JIANG Zhong-Hong   

  1. Shanghai Institute of Optics and Fine Mechanics; Chinese Academy of Sciences; Shanghai 201800; China
  • Received:2003-01-13 Revised:2003-02-28 Published:2004-01-20 Online:2004-01-20

Abstract: Er3+-doped fluoride lead silicate glasses were fabricated. The physical properties, thermal properties, absorption
spectra, fluorescence spectra and fluorescence lifetimes of the samples were investigated. The absorption and stimulated
emission cross-sections of 4I13/2→4I15/2 transition of the samples were calculated by McCumber theory.
The results show that densities, refractive indices, thermal stability, absorption and stimulated emission cross-sections of
the samples decrease, but the fluorescence full width at half max maximum and fluorescence lifetimes of the 4I13/2
level of Er3+ increase. Compared with other glass hosts, the gain bandwidth property of Er3+-doped 50SiO2-50PbF2
glass is close to those of tellurite and bismuth glasses, and has advantage over those of silicate, phosphate and germante lasses, which shows that Er3+-doped fluoride lead silicate glasses can be as host materials for broadband optical amplifier.

Key words: fluoride lead silicate glasses, spectral properties, optical fiber amplifier, Er3+ ion

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