Journal of Inorganic Materials

• Research Paper • Previous Articles     Next Articles

Oxidation Kinetics and Mechanism of SiC Coating/3-dimensional Carbon Fiber Braid

GAO Peng-Zhao; WANG Hong-Jie; JIN Zhi-Hao   

  1. State Key Laboratory for Mechanical Behavior of Materials; Xi an Jiaotong University; Xi an 710049; China
  • Received:2004-02-23 Revised:2004-05-18 Published:2005-03-20 Online:2005-03-20

Abstract: The in situ reaction method was used to prepare SiC coating on 3-D carbon fiber braid (RB). XRD, SEM, isothermal oxidation-weight loss and non-isothermal TG were used to
study the oxidation process and oxidation reaction mechanism of SiC coating/3-D carbon fiber braid (CB). The results showed that coating was
coated symmetrically and combined well with every fiber of braid. The oxidation process of CB in isothermal condition was reaction-controlled
in the first step, gas diffusion and reaction-controlled in the second step. The oxidation process of CB in non-isothermal condition exhibited a
self-catalytic characteristic, the oxidation mechanism was random nucleation, the kinetic parameters were: lgA=10.299min-1; Ea=156.29kJ·mol-1.

Key words: in situ reaction method, 3-D carbon fiber braid, non-isothermal TG, oxidation kinetics and mechanism

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