Near-infrared Luminescence Properties of Bi2O3-SiO2 Glasses and Glass Ceramics

doi:10.15541/jim20130604

Abstract

Abstract:

Bi₂O₃-SiO₂glasses and glass ceramics were prepared by melting method. Infrared and VIS luminescence spectra, excitation spectra and fluorescence decay curves were measured. Near infrared (NIR) luminescence of Bi₂O₃-SiO₂glasses and glass ceramics was observed under 808 nm Laser Diode pumping. When the content of Bi₂O₃ is low (30mol%, 40mol%, 50mol%), NIR luminescence peak at 1336 nm (or 1300 nm) with full width at half maximum (FWHM) about 200 nm is observed. With the increase of Bi₂O₃ content, another peak at about 1070 nm with narrow FWHM appears and becomes the main peak, while the FWHM of the NIR emission centered at 1336 nm (or 1300 nm) decreases to only tens of nanometer. Two emission bands have different excitation bands and lifetime. We propose NIR emissions located at 1070 nm and 1336 nm (or 1300 nm) originate from different bismuth centers. The infrared emission peaked at about 1336 nm (or 1300 nm) derives from low valence Bi ions.

Key words: near infrared emission, Bi ions, glass ceramics

CLC Number:

TB321

LIU Jun-Fang, SU Liang-Bi, XU Jun. Near-infrared Luminescence Properties of Bi₂O₃-SiO₂Glasses and Glass Ceramics[J]. Journal of Inorganic Materials, 2014, 29(8): 859-863.

Figures/Tables 6

Fig. 1 XRD patterns of Bi2O3 -SiO2 glass-ceramics

Fig. 2 Emission spectra of Bi2O3-SiO2 glasses and glass- ceramics under excitation at 808 nm

Fig. 3 Dependence of I1070/I1336 on the Bi2O3 concentration

Fig. 4 Excitation spectra for emission at 1300 nm in 30Bi2O3-70SiO2 glass and 1063 nm in 70Bi2O3-30SiO2 glass ceramics and the absorption spectrum of 30Bi2O3-70SiO2 glass

Fig. 5 Fluorescence decay curves of 30Bi2O3-70SiO2 glass at 1300 nm (a) and 70Bi2O3-30SiO2 glass ceramics at 1063 nm (b)

Fig. 6 Luminescence spectrum of 70Bi2O3-30SiO2 glass- ceramics excited by 330 nm

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Near-infrared Luminescence Properties of Bi₂O₃-SiO₂Glasses and Glass Ceramics

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