Synthesis of New Zn-containing Derivative by Multi-step Ion-exchanges

doi:10.3724/SP.J.1077.2010.00806

Abstract

Abstract:

A new material, Zn-containing derivative from SrBi₂Nb₂O₉, was synthesized by multi-step ion-exchanges with H⁺/(BiO)⁺, TMA+ (tetramethylammonium ions)/H⁺, and Zn(NH₃)₄²⁺/TMA⁺ step by step. X-ray diffraction (XRD) patterns exhibite the difference in the layered structures among the precursor SrBi2Nb2O9 (SBN), its protonated product (HSN), and Zn-containing derivative (ZSN). The compositional analyses reveal the extraction of most of the bismuth atoms and the loss of a small part of the strontium atoms after protonation. The UV-Vis (ultraviolet-visible) absorption edge of the Zn-containing derivative shifts markedly to high energy compared with that of the precursor and its protonated product.

Key words: SrBi₂Nb₂O₉, protonation, ion-exchange, UV-Vis absorption

CLC Number:

O613

CHEN Yu-Feng, ZHOU Song-Hua, YANG Xiao-Jing. Synthesis of New Zn-containing Derivative by Multi-step Ion-exchanges[J]. Journal of Inorganic Materials, 2010, 25(8): 806-810.

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