Journal of Inorganic Materials

• Research Paper • Previous Articles     Next Articles

Low Vacuum Measurement of Zirconia-Based Oxygen Sensor for an Evacuated (Air) System

SUN Cheng-Wen; CHEN Shen; YANG Zhi-Zhou   

  1. Shanghai Institute of Ceramics; Chinese Academy of Sciences; Shanghai 200050; China
  • Received:1998-11-30 Revised:1999-02-10 Published:1999-12-20 Online:1999-12-20

Abstract: The cell EMFs of oxygen in an evacuated (air) system (105~103Pa) versus atmospheric oxygen were measured from 600℃ to 800℃ by an
oxygen concentration cell with a solid electrolyte of yttria stabilized zirconia. The experimental results showed that there is a linear relationship between the cell
EMF and the logarithm of residual atmospheric pressure p in an evacuated (air) system. The produced EMF is given by the eqution E=(RT/4F)ln(pair/p),
in which it’s slope is close to theoretic value and error less than 5%. The sensibility of measured EMF increases with the pressure decrease and may be suitable for low
vacuum measurement.

Key words: low vacuum measurement, yttria stabilized zirconia, zirconia oxygen sensor, zirconia oxygen concentration cell

CLC Number: