Journal of Inorganic Materials

• Research Paper •     Next Articles

Model of Solute Surface Tension Convection and Its Analysis for Space Experiment

JIN Wei-Qing; PAN Zhi-Lei; CAI Li-Xia; LIU Zhao-Hua; LIANG Xin-An   

  1. Shanghai Institute of Ceramics; Chinese Academy of Sciences; Shanghai 200050; China
  • Received:1999-06-08 Revised:1999-07-08 Published:2000-06-20 Online:2000-06-20

Abstract: Space High Temperature In Situ Observation Instrument “SHITISOI” was dedicated to visualize and record the
whole KNbO3 cellular growth process in Li2B4O7 flux. The dependence of buoyancy and surface tension convections on the cellular
growth was studied. In space, the streamlines of the steady surface tension convections in the Li2B4O7 flux were observed. The steady
convections occur in the form of a mirror symmetric pattern. Due to the surface tension convection, the KNbO_3 grains grow and fill the whole
solution homogeneously. On the ground, the buoyancy drive flow in direction opposite to that of surface tension flow can reduce the cellular growth
and the distribution of KNbO3 solute grains is inhomogeneous in the Li2B4O7 flux. A theoretical model of cellular growth was also
accounted. A pivotal feature in this model is the initiation of the surface tension convection on the interface of KNbO3 grain. This is initiated
by KNbO3 solute surface tension gradient which is caused by less rapid diffusion of KNbO3 solutes. Direct comparison of the model predictions
and experimental observed phenomena demonstrates the predictive capability of this model.

Key words: KNbO3 cellular growth, high temperature solution, surface tension convection, in situ observation, microgravity material science, electron-microprobe analyses

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