高级检索
无机材料学报

无机材料学报 >

2009 , Vol. 24 >Issue 3: 507 - 511

DOI: https://doi.org/10.3724/SP.J.1077.2009.00507

研究论文

含季鏻阳离子的抗菌改性蒙脱土的制备及表征

  • 谭绍早 ,
  • 郑 佳 ,
  • 陈 茵 ,
  • 谢瑜珊 ,
  • 施庆珊 ,
  • 欧阳友生 ,
  • 陈仪本
展开
  • 1. 暨南大学 化学系， 广州 510632； 2. 广东省微生物研究所， 广州 510070

收稿日期: 2008-07-21

  修回日期: 2008-10-12

  网络出版日期: 2009-05-20

收起

Preparation and Characterization of the Antibacterial Modified Montmorillonites Containing Quaternary Phosphonium Cations

  • TAN Shao-Zao ,
  • ZHENG Jia ,
  • CHEN Yin ,
  • XIE Yu-Shan ,
  • SHI Qing-Shan ,
  • OUYANG You-Sheng ,
  • CHEN Yi-Ben
Expand
  • 1. Department of Chemistry, Jinan University, Guangzhou 510632, China; 2. Guangdong Institute of Microbiology, Guangzhou 510070，China

Received date: 2008-07-21

  Revised date: 2008-10-12

  Online published: 2009-05-20

Fold

摘要

采用离子交换法将十六烷基三苯基插入到钠基蒙脱土的层间得到4种不同季鏻阳离子含量的改性蒙脱土，通过热重分析（TGA）、X射线衍射法（XRD）和扫描电镜（SEM）表征了结构，并测试了其Zeta电位和抗菌活性. 发现4种改性蒙脱土中季鏻阳离子的热分解起始温度都高于230℃，具有较好的热稳定性. 并且随着改性蒙脱土中季鏻阳离子含量的增加，其层间距变大、Zeta电位升高、抗菌活性增强. 钠基蒙脱土为片状结构，粒子之间相互缠绕在一起，而改性蒙脱土显示不规则形状. 对季鏻阳离子含量为23.55wt%的QPC/MMT3样品，其对大肠杆菌（E.coli）和金黄色葡萄球菌（S.aureus）的最低抑菌浓度（MICs）分别为1.2和0.1g/L；与细菌接触24h后，1.0g/L的样品可杀死99.9%以上的E.coli，0.1g/L的样品可杀死所有的S.aureus. QPC/MMT3还具有较好的耐水性能.

关键词： 季鏻阳离子; 改性蒙脱土; 制备; 表征; 抗菌活性

本文引用格式

谭绍早 , 郑 佳 , 陈 茵 , 谢瑜珊 , 施庆珊 , 欧阳友生 , 陈仪本 . 含季鏻阳离子的抗菌改性蒙脱土的制备及表征[J]. 无机材料学报, 2009 , 24(3) : 507 -511 . DOI: 10.3724/SP.J.1077.2009.00507

Abstract

Four kinds of modified montmorillonites were prepared by introducing different content of hexadecyltriphenyl phosphonium cations into sodium montmorillonite (Na/MMT) through an ion-exchange method, and characterized using thermogravimetry (TGA), X-ray diffraction (XRD) and scanning electron microscope (SEM). Also the Zeta potentials and antibacterial activity of the modified montmorillonites were investigated. The onset temperatures of the decomposition for quaternary phosphonium cations in modified montmorillonites are all higher than 230℃, which have good thermal stability. For the montmorillonites, the interlayer spacings enlarge, the Zeta potentials increase and the antibacterial activity improves with the increase of the content of quaternary phosphonium cations. Na/MMT displays flake shape with the particles adhered and interwinded each other, while the modified montmorillonites are in irregular shape. QPC/MMT3 containing 23.55wt% quaternary phosphonium cations, possesses the minimal inhibitory concentration (MICs) against E.coli and S.aureus of 1.2g/L and 0.1g/L, respectively. After contacting the bacteria for 24h, 1.0g/L of QPC/MMT-3 is able to kill more than 99.9% E.coli, and nearly all the E.coli. Moreover, QPC/MMT-3 has good water resistance.

Key words： quaternary phosphonium cation; modified montmorillonite; preparation; characterization; antibacterial activity

参考文献

［1］ Ayben T, Semra U. Applied Clay Science, 2004, 27(1-2):13-19.
［2］Tan S Z, Ding L C, Liu Y L, et al. Chinese Chemical Letters, 2007, 18(1): 85-88.
［3］River-Garza M, Olguín M T, García-Sosa I, et al. Microporous and Mesoporous Materials, 2000, 39(3): 431-444.
［4］Zhang L, Yu J C, Yip H Y, et al. Langmuir, 2003, 19(24): 10372-10380.
［5］Kwolek T, Hodorowicz M, Stadnicka K, et al. Journal of Colloid and Interface Science, 2003, 264(1): 14-19.
［6］Fan L P, Chen M, Zhang Y G, et al. Chinese Journal of Chemistry,2007, 25(5): 666-669.
［7］Saso N, Yamamoto T, Umemura Y, et al. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2008, 317(1-3): 309-315.
［8］Herrera P, Burghardt R C, Phillips T D. Veterinary Microbiology, 2000, 74(3): 259-272.
［9］张葵花, 谭绍早, 刘应亮. 硅酸盐学报, 2006, 34(1): 87-93.
［10］张葵花, 谭绍早, 刘应亮. 化工新型材料, 2005, 33(11): 44-47.
［11］谭绍早, 张葵花, 李笃信, 等. 中南大学学报 (自然科学版), 2006, 37(2): 280-285.
［12］Tan S Z, Zhang L L, Huang L H, et al. Journal of the Ceramic of Society of Japan, 2007, 115(4): 269-271.
［13］谭绍早, 张葵花, 刘应亮. 复合材料学报, 2006, 23(3): 82-86.
［14］Xie W, Gao Z M, Pan W P, et al. Chemistry of Materials, 2001, 13(9): 2979-2990.
［15］Viva R A, Teukolsky R K, Giannelis E P. Chemistry of Materials, 1994, 6(7): 1017-1022.
［16］柯扬船.［美］皮特.斯壮. 聚合物无机纳米复合材料. 北京: 化学工业出版社, 2003: 65-76.
［17］王艳萍，赵虎山. 化妆品微生物学. 北京: 中国轻工业出版社, 2002： 24-27.
［18］El-Nahhal Y Z, Safi J U. Applied Clay Science, 2004, 24(3-4):129-136.
Options
文章导航

/

〈 〉