采用热压烧结法制备了致密的短切碳纤维增强碳化硅 (Csf/SiC) 复合材料.借助热重分析、XRD、SEM等手段对该材料等温氧化性能进行了研究.研究结果表明,该复合材料在900℃氧化时失重最为严重;之后,随着氧化温度升高,失重率逐渐减少;在1450℃以上则表现为增重.复合材料在低于900℃氧化时,主要是由于碳纤维氧化造成的失重;在900~1450℃氧化区间,复合材料表面的短切碳纤维被氧化,基体生成保护性的氧化膜,材料内部的短切碳纤维受到基体和氧化膜的有效保护,能够继续发挥增韧作用.因此,Csf/SiC复合材料在此温度范围内具有良好的抗氧化能力;当复合材料在1600℃氧化时,氧化反应剧烈,材料破坏严重,失去了抗氧化能力.
Short carbon fiber reinforced SiC (Csf/SiC) composite was prepared by hotpressing method. XRD, SEM and isothermal oxidation test were used to study the isothermal oxidation property of Csf/SiC composite. The results show that the oxidation weight loss of the composite is the most at 900℃. The weight loss decreases with the oxidation temperatures rising. Below 900℃, the oxidation weight loss of the composites is caused by the carbon fibers oxidation. Above 1450℃, the composites gain weight. Between 900-1450℃, short carbon fibers on the composite surface are oxidized and the SiC matrix forms a protecting film. The inner short carbon fibers still have the strengthen effect for the oxidation layer and matrix protecting them from oxidation, and the composites have good self-resistance oxidation property. When the composites oxide at 1600℃, the composite surface is destroyed badly and lose the resistance oxidation capacity.
[1]堂山昌男, 山本良一(邝心湖译). 尖端材料. 北京:电子工业出版社, 1987:189-192.
[2]Andreas Sonntag. Am. Ceram. Soc. Bull., 1997,76(11):51-54.
[3]Schwetz Karl A(王元化译).国外耐火材料, 1990, (4):1-8.
[4]Clarke R K. J. Am. Ceram. Soc., 1992,75(4):739-758.
[5]Lee Jae-seol, Imai M, Yano T. Mater. Sci. Eng., 2003, A339(1-2): 90-95.
[6]Friedrich Raether, Jurgen Meinhardt,Andreas Kienzle.J. Euro. Ceram. Soc., 2007, 27(2-3):1217-1221.
[7]Ju C P, Wang C K, Cheng H Y,et al. J. Mater. Sci., 2000, 35(17): 4477-4484.
[8]冉丽萍, 易茂中, 黄伯云. 粉末冶金材料科学与工程, 2004, 9(3): 248-253.
[9]Evans A G. J. Am. Ceram. Soc., 1990, 73(2):187-206.
[10]Jian Ke, Chen Zhao-Hui, Ma Qing-Song, et al. Ceram. Int., 2007, 33(1): 73-76.