高级检索
无机材料学报

无机材料学报 >

2009 , Vol. 24 >Issue 2: 367 - 370

DOI: https://doi.org/10.3724/SP.J.1077.2009.00367

研究论文

Tb1-xDyxFe2-y-BaTi0.99Cr0.01O3-δ多层复合结构中的磁电效应

  • 高剑森 ,
  • 张 宁
展开
  • 1.江苏省宿迁学院 基础教学部, 宿迁 223800； 2.南京师范大学 磁电子学实验室，南京 210097

收稿日期: 2008-05-19

  修回日期: 2008-08-16

  网络出版日期: 2009-03-20

收起

Magnetoelectric Effect in Laminate Composites Tb1-xDyxFe2-y-BaTi0.99Cr0.01O3-δ

  • GAO Jian-Sen，ZHANG Ning
Expand
  • 1.Basic Teaching Department, Suqian College of Jiangsu Province, Suqian 223800, China; 2.Magnetoelectronic Lab, Nanjing Normal University, Nanjing 210097, China

Received date: 2008-05-19

  Revised date: 2008-08-16

  Online published: 2009-03-20

Fold

摘要

采用溶胶凝胶法制备了Cr掺杂BaTiO3陶瓷片.X射线衍射显示Cr掺杂BaTiO3依然为四方相钙钛矿结构.差热分析显示，Cr掺杂BaTiO3的居里温度及相变潜热均比纯净BaTiO3 的同类参量略低.将所得BaTi0.99Cr0.01O3-δ陶瓷片与Tb1-xDyxFe2-y粘结成磁电双层及三层复合结构材料.研究了双层Tb1-xDyxFe2-y-BaTi0.99Cr0.01O3-δ和三层Tb1-xDyxFe2-y-BaTi0.99Cr0.01O3-δ-Tb1-xDyxFe2-y复合材料的磁电效应.在28 kA/m 的磁场下，两者的横向ME电压系数均达其峰值，为732.5和2753mV/A.该两数值分别是采用BaTiO3制备的同类双层及三层复合结构的同类数值的1.54及1.56倍.由于掺杂钛酸钡不含铅、锆等有害物质，因此采用掺杂BaTiO3替代锆钛酸铅做为“绿色”压电材料制备磁电效应器件具有研究和应用价值.

关键词： 掺杂钛酸钡; 绿色压电体; 磁致伸缩材料; 磁电效应

本文引用格式

高剑森 , 张 宁 . Tb1-xDyxFe2-y-BaTi0.99Cr0.01O3-δ多层复合结构中的磁电效应[J]. 无机材料学报, 2009 , 24(2) : 367 -370 . DOI: 10.3724/SP.J.1077.2009.00367

Abstract

Chromiun doped BaTiO3 was synthesized with sol-gel technique. The Cr-doped BaTiO3 was still in the structure of tetragonal perovskite by X-ray diffraction, and its transformation point of ferroelectric to paraelectric as well as the latent heat of the transformation were observed a little less than those of pure BaTiO3, respectively, by the tests of differential scanning calorimetry. Layered composites Tb1-xDyxFe2-y and BaTi1-zCrzO3-δ were fabricated by bonding the discs of the doped BaTiO3 and rare earth alloy Tb1-xDyxFe2-y. The magnetoelectric (ME) effect of the layered samples was investigated. The transverse ME voltage coefficient for the bilayer Tb1-xDyxFe2-y-BaTi1-zCrzO3-δ and the trilayer Tb1-xDyxFe2-y-BaTi1-zCrzO3-δ-Tb1-xDyxFe2-y reach 732.5 and 2753mV/A, respectively, under a bias magnetic field 28kA/m at room temperature, which are about 54% and 56% larger than those for the bilayer and trilayer composed by pure BaTiO3, respectively. Since Cr-doped BaTiO3 does not contain injurants, such as lead and zirconium, it can replace lead zirconium titanite as a “green” piezoelectric material for ME composites.

Key words： doped BaTiO3; green piezoelectrics; magnetostrictive material; magnetoelectric effect

参考文献

［1］Ilene J. Busch-Vishniac, Phys. Today,1998, 51(7): 28-34.
［2］Fujimura N, Ishida T, Yoshimura T, et al. Appl. Phys. Lett., 1996,69(7): 1011-1013.
［3］Dzyaloshinskii I E. J.Exptl. Theoret. Phys. (U.S.S.R), 1960, 37: 881-892.
［4］Folen V J, Rado G T, Stalder E W. Phys. Rev. Lett., 1961, 6(11): 607-608.
［5］Nan C W. Phys. Rev. B, 1994,50(9): 6082-6088.
［6］Kothale M B, Patankar K K, Kadam S L, et al. Materials Chemistry and Physics, 2003, 77(3): 691-696.
［7］Srinivasan G, DeVreugd C P, Flattery C S, et al. Appl. Phys. Lett., 2004,85(13): 2550-2552.
［8］Wan J G, Wang X W, Wu Y J, et al. Appl. Phys. Lett., 2005,86(12): 122501-1-3.
［9］Srinivasan G, Rasmussen E T, Hayes R. Phys. Rev. B, 2003,67(1): 014418-1-10.
［10］Dong S, Li J F, Viehland D, et al. Appl. Phys. Lett., 2004,85(16): 3534-3536.
［11］Wan J G, Liu J M, Chand H L W, et al. J. Appl. Phys., 2003, 93(12): 9916-9919.
［12］Srinivasan G, Rasmussen E T, Levin B J, et al. Phys. Rev. B, 2002,65(13): 134402-1-7.
［13］Ren Xiaobing, Otsuka Kazuhiro. Phys. Rev. Lett., 2004, 85(5): 1016-1019.
［14］Ren Xiaobing. Nature Mater., 2004,3: 9194.
［15］Zhang L X, Chen W, Ren X. Appl. Phys. Lett., 2004, 85(23): 5658-5660.
［16］Zhang L X, Ren X. Phys. Rev. B, 2005, 71: 174108-1-8.
［17］Zhang N, Fan J F, Rong X F, et al. J. Appl. Phys., 2007,101(6): 063907-1-3.
［18］Buscaglia M T, Buscaglia V, Viviani M, et al. J. Euro. Ceram. Soc., 2000, 20(12):1997-2001.
［19］Hathaway K, Clark A E. MRS Bulletin, 1993,18(4): 34-41.
［20］Ravindranath V, Kim S H, Jeong J R, et al. J. Magn. Magn. Mater.,2007,310(2): e899-900.
［21］Kellogg R, Flatau A. J. Int. Mater. Sys. Struct., 2008, 19(5): 583-595.
［22］Srinivasan G, Rasmussen E T, Gallegos J, et al. Phys. Rev. B, 2001, 64(21): 214408-1-6.
［23］Cao H X, Zhang N, Wei J J. Journal of Alloys and Compounds, DOI: 10.1016/j.jallcom. 2008.04.060.
Options
文章导航

/

〈 〉