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TiO2纳米管负载纳米金的制备及其在紫外光下的光电性能

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  • 射线束技术与材料改性教育部重点实验室,北京师范大学 核科学与技术学院, 北京 100875

收稿日期: 2009-11-10

  修回日期: 2009-12-21

  网络出版日期: 2010-05-12

Development of Titania Nanotubes Loaded with Au Nanoparticles and their Opto-electronic Response under UV Light

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  • Key Laboratory of Radiation Beam Technology and Material Modification of Ministry of Education, Department of Materials Science & Engineering, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875, China

Received date: 2009-11-10

  Revised date: 2009-12-21

  Online published: 2010-05-12

摘要

利用直流磁控溅射法制备纳米金颗粒表面改性TiO2纳米管,并通过XRD,FESEM对其结构进行表征.在紫外光下测试其光电效应,结果发现在定电位和动电位下,纳米金改性后的TiO2纳米管产生的光电流都要比未改性的TiO2纳米管大.在定电位下(1.0V),Au/TiO2纳米管产生的光电流为0.4mA,是TiO2纳米管的1.8倍.在动电位下(-1.5~1.5V),当电位达1.5V时,Au/TiO2纳米管产生的光电流为0.75mA,是TiO2纳米管的3.75倍.

本文引用格式

罗 军, 廖 斌, 陈一鸣, 刘安东, 刘培生 . TiO2纳米管负载纳米金的制备及其在紫外光下的光电性能[J]. 无机材料学报, 2010 , 25(5) : 557 -560 . DOI: 10.3724/SP.J.1077.2010.09777

Abstract

Au nanoparticles surfacemodified titania nanotubes were produced by direct current (DC) magnetic sputtering technology. The morphology of the nanotubes was characterized by X-ray diffractometry (XRD) and field emission scanning electron microscope (FESEM). Opto-electronic properties were tested under UV light. Comparing with original titania nanotubes, Au/TiO2 nanotubes can generate the photocurrent with great improvements in constant potential and dynamic potential. At constant potential (1.0V) test under UV light, the photovoltaic current generated by Au/TiO2 is 0.4mA, 1.8-fold of original nanotubes’. While at dynamic photocurrent (-1.5V to 1.5V) test, the photocurrent has reached 0.75mA, which is 3.75-fold of that for original nanobubes under the scan voltage of 1.5V.

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