纳米铌镁酸铅机械化学法低温快速合成
收稿日期: 2009-10-14
修回日期: 2009-12-14
网络出版日期: 2010-05-12
Fast Mechanochemical Synthesis of Nanostructured PMN at Low Temperature
Received date: 2009-10-14
Revised date: 2009-12-14
Online published: 2010-05-12
吴 皓1,2, 陈 诚1, 蒋丹宇2, 李 强1 . 纳米铌镁酸铅机械化学法低温快速合成[J]. 无机材料学报, 2010 , 25(5) : 541 -545 . DOI: 10.3724/SP.J.1077.2010.00541
Nanoscale lead magnesium niobate (PMN) powders of perovskite phase were synthesized by the screw grinder for 3h starting from raw materials of oxides. The influences of reaction conditions on products, such as weight of raw materials, grind power and grind time, were studied in detail. The results show that high grind power can reduce the synthesis time, improve the purity of products and decrease the particle size. The mechanochemical mechanism of PMN synthesis is confirmed via cross reaction experiments between raw materials. Magnesium niobate is firstly formed through mechanochemical reaction between MgO and Nb2O5, then reacted with PbO to get the PMN finally.
[1]Zhao J B, Qu S B, Du H L, et al. Preparation and temperature dependence of electrostriction properties for PMNbased composite ceramics.Mater. Sci. Eng. B,2009, 162(1):9-13
[2]Stojanovic Biljana D. Mechanochemical synthesis of ceramic powders with perovskite structure.Journal of Materials Processing Technology,2003, 143-144:78-81
[3]Moetakef P, Nemati Z A. Synthesis of PMN pyrochlore free ceramics via a modified mixed oxide method.J. Electroceramics,2007, 19(2/3):207-213
[4]Lu YiQing, Li Yong-Xiang, Xiong Yu-Hong, et al. SrAl2O4∶Eu2+, Dy3+ phosphors derived from a new SolGel route.Microelectronics Journal,2004, 35(4):379-382
[5]王 歆, 庄志强, 齐雪君(WANG Yun, et al). PMN-PT弛豫铁电粉体的溶胶凝胶法的制备及其性质．无机材料学报(Journal of Inorganic Materials), 2002, 17(2)： 306-310.
[6]Chang Cheng-Kang, Yuan Zhao-Xin, Mao Da-Li. Eu2+ activated long persistent strontium aluminate nano scaled phosphor prepared by precipitation method.Journal of Alloys and Compounds,2006, 415(1/2):220-224
[7]李晓云, 陆天长, 梁 爽. 铝酸锶系长余辉发光粉的制备及其光学性能. 南京化工大学学报, 2001, 23（2）： 32-35.
[8]Peng Tian-You, Yang Huan-Ping, Pu Xu-Li, et al. Combustion synthesis and photoluminescence of SrAl2O4∶Eu,Dy phosphor nanoparticles.Materials Letters,2004, 58(3/4):352-356
[9]Yoona K H, Parka H S, Choa J Y, et al. Microwave dielectric properties of (Pb0.4Ca0.6)(Fe0.5Ta0.5)O3 ceramics prepared by mechanochemical processing. Journal of the European Ceramic Society, 2003, 23(14): 2579-2582.
[10]Mahajan Sandeep, Prakash Chandra, Thakur O P. Piezoelectric properties of 0.5(PbNi1/3Nb2/3)O3 -0.5Pb(Zr0.32Ti0.68)O3 ceramics prepared by solid state reaction and mechanochemical activationassisted method. J. Alloys Comp., 2009, 471(1/2): 507-510.
[11]Chang Chun-Chieh, Kumta Prashant N. Mechano chemical synthesisof LiNO2.Materials Science and Engineering B,2005, 116(3):341-345
[12]李 强. 一种螺杆研磨机. 中国, B02C19/22, CN101185911A. 2008.05.28.
[13]Halliiyal A, Kumar U, Neanham R E, et al. Stabilization of perovskite phase and dielectric properties of ceramics in the Pb(Zn1/3Nb2/3)O3-BaTiO3 system. Am. Ceram. Soc. Bull., 1987, 66(4): 671-676.
[14]Inda M. Analysis of the formation process of the piezoelectric PCM ceramics. Jpn. Nat. Tech. Rept., 1977, 27(1): 95-102.
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