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2010 , Vol. 15 >Issue 2: 125 - 128

DOI: https://doi.org/10.3724/SP.J.1077.2010.00125

研究论文

Ce3+掺杂YAG透明陶瓷的制备与光性能研究

  • 石 云 ,
  • 潘裕柏 ,
  • 冯锡淇 ,
  • 李 江 ,
  • 郭景坤
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  • (中国科学院 上海硅酸盐研究所 透明光功能无机材料重点实验室, 上海 200050)

收稿日期: 2009-05-13

  修回日期: 2009-07-24

  网络出版日期: 2010-02-20

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Fabrication and Luminescence Study of Ce3+-doped YAG Transparent Ceramics

  • SHI Yun ,
  • PAN Yu-Bai ,
  • FENG Xi-Qi ,
  • LI Jiang ,
  • Guo Jin-Kun
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  • (Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China)

Received date: 2009-05-13

  Revised date: 2009-07-24

  Online published: 2010-02-20

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摘要

采用高纯微米级商业原料（≥99.99％）α-Al2O3、 Y2O3和CeO2, 用固相反应法制备了0.3at % Ce3+∶YAG透明陶瓷. 粉体经行星式球磨, 陶瓷素坯在1750℃真空烧结10h, 真空度10-3Pa, 双面抛光后, 厚度为1.2mm的透明陶瓷试样在可见光区500～900nm的直线透过率可达80％左右, 光学均匀性良好. 荧光光谱分析表明, 发射峰位于500～700nm之间, 这是Ce3+的特征发射. 结果表明, Ce∶YAG透明陶瓷的发光性能与相应的单晶相当, 有望作为闪烁材料应用于中低能量射线（α、β粒子等）的探测.

关键词： 固相反应法; Ce∶YAG; 闪烁透明陶瓷

本文引用格式

石 云 , 潘裕柏 , 冯锡淇 , 李 江 , 郭景坤 . Ce3+掺杂YAG透明陶瓷的制备与光性能研究[J]. 无机材料学报, 2010 , 15(2) : 125 -128 . DOI: 10.3724/SP.J.1077.2010.00125

Abstract

0.3at％ Ce∶YAG (Y3Al5O12) transparent ceramics was fabricated by a solid state reaction method, with the high pure (≥99.99%) commercial powders α-Al2O3, Y2O3, CeO2 using as raw materials. The ceramic green bodies were sintered in 1750℃ for 10h in vacuum. The linear transmission of the prepared Ce∶YAG ceramics in visible range 500-900nm reaches about 80% homogeneously (1.2mm thick, double polished). Photoluminescence properties show that the emitting band of the Ce∶YAG ceramics lies in 500-700nm, which is the characteristic emitting of Ce3+. It is concluded that the Ce∶YAG transparent ceramics is a promising scintillator materials especially for middle-low energy ray detecting.

Key words： solid state reaction method; Ce∶YAG; scintillator transparent ceramics

参考文献

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