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无机材料学报

无机材料学报

• 研究论文 • 上一篇    下一篇

Ce3+掺杂YAG透明陶瓷的制备与光性能研究

石 云, 潘裕柏, 冯锡淇, 李 江, 郭景坤   

  1. (中国科学院 上海硅酸盐研究所 透明光功能无机材料重点实验室, 上海 200050)
  • 收稿日期:2009-05-13 修回日期:2009-07-24 出版日期:2010-02-20 网络出版日期:2010-02-20

Fabrication and Luminescence Study of Ce3+-doped YAG Transparent Ceramics

SHI Yun, PAN Yu-Bai, FENG Xi-Qi, LI Jiang, Guo Jin-Kun   

  1. (Key Laboratory of Transparent Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China)
  • Received:2009-05-13 Revised:2009-07-24 Published:2010-02-20 Online:2010-02-20

PDF (PC)

2331

被引次数

13

摘要： 采用高纯微米级商业原料（≥99.99％）α-Al2O3、 Y2O3和CeO2, 用固相反应法制备了0.3at % Ce3+∶YAG透明陶瓷. 粉体经行星式球磨, 陶瓷素坯在1750℃真空烧结10h, 真空度10-3Pa, 双面抛光后, 厚度为1.2mm的透明陶瓷试样在可见光区500～900nm的直线透过率可达80％左右, 光学均匀性良好. 荧光光谱分析表明, 发射峰位于500～700nm之间, 这是Ce3+的特征发射. 结果表明, Ce∶YAG透明陶瓷的发光性能与相应的单晶相当, 有望作为闪烁材料应用于中低能量射线（α、β粒子等）的探测.

关键词: 固相反应法, Ce∶YAG, 闪烁透明陶瓷

Abstract: 0.3at％ Ce∶YAG (Y3Al5O12) transparent ceramics was fabricated by a solid state reaction method, with the high pure (≥99.99%) commercial powders α-Al2O3, Y2O3, CeO2 using as raw materials. The ceramic green bodies were sintered in 1750℃ for 10h in vacuum. The linear transmission of the prepared Ce∶YAG ceramics in visible range 500-900nm reaches about 80% homogeneously (1.2mm thick, double polished). Photoluminescence properties show that the emitting band of the Ce∶YAG ceramics lies in 500-700nm, which is the characteristic emitting of Ce3+. It is concluded that the Ce∶YAG transparent ceramics is a promising scintillator materials especially for middle-low energy ray detecting.

Key words: solid state reaction method, Ce∶YAG, scintillator transparent ceramics

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