氧化锌纳米线/管阵列的溶胶-凝胶模板法制备与表征

无机材料学报

氧化锌纳米线/管阵列的溶胶-凝胶模板法制备与表征

于美; 刘建华; 李松梅; 韦巍

北京航空航天大学材料科学与工程学院, 北京 100083

收稿日期:2004-11-01 修回日期:2004-12-14 出版日期:2005-11-20 网络出版日期:2005-11-20

Fabrication and Characterization of Highly Ordered Zinc Oxide Nanowire/Tube Arrays by Sol-Gel Template Method

YU Mei; LIU Jian-Hua; LI Song-Mei; WEI Wei

School of Materials Science and Engineering; Beijing University of Aeronautics and Astronautics; Beijing 100083, China

Received:2004-11-01 Revised:2004-12-14 Published:2005-11-20 Online:2005-11-20

摘要/Abstract

摘要： 用溶胶-凝胶法在氧化铝模板中制备了直径约为15、30、50、60nm的有序氧化锌纳米线/管阵列.用扫描电镜(SEM)、透射电镜(TEM)和X射线衍射仪(XRD)对氧化锌纳米线/管的形貌、结构以及相组成进行了分析.结果发现,纳米线的形貌依赖于氧化铝模板中孔洞的形貌,纳米线的长度受控于氧化铝模板的厚度,外径与氧化铝模板的孔径相等.通过控制溶胶的浓度以及氧化铝模板在溶胶中的浸泡时间可以制备出纳米管.

关键词: 氧化铝模板, 溶胶-凝胶, 氧化锌纳米线/管

Abstract: Highly ordered zinc oxide nanowire/tube arrays were prepared by a sol-gel method in the pores of anodic alumina membranes (AAM). The morphology and crystalloid structure of zinc oxide nonawire/tube arrays were characterized by scanning electron microscope(SEM), transmission electron microscope (TEM) and X-ray diffraction (XRD). The results show that zinc oxide nonawires are very uniformly assembled and parallel to each other in the pores of the AAM template. The length and diameter of nanowires are dependen on the thickness and hole diameter of AAM. Zinc oxide nanotube arrays can be controlled by changing immersing time, temperature and concentration of the sol.

Key words: anodic alumina membrane, sol-gel, zinc oxide nanowire/tube arrays

中图分类号:

O614
TB383

于美,刘建华,李松梅,韦巍. 氧化锌纳米线/管阵列的溶胶-凝胶模板法制备与表征[J]. 无机材料学报.

YU Mei,LIU Jian-Hua,LI Song-Mei,WEI Wei. Fabrication and Characterization of Highly Ordered Zinc Oxide Nanowire/Tube Arrays by Sol-Gel Template Method[J]. Journal of Inorganic Materials.

参考文献

[1] Hu J T, Odom T W, Lieber C M. Ace. Chem. Res., 1999, 32: 435.
[2] 赵启涛, 候立松, 黄瑞安. 物理化学学报(Acta Chim. Sinica), 2003, 61 (10): 1671-1674.
[3] Chu S Z, Wada K, Inoue S, et al. Electrochimica Acta, 2003, 48: 3147-3153.
[4] Rahman I Z, Razeeb K M, Rahman M A, et al. J. Magnetism and Magnetic Mater., 2003, 262: 166-169.
[5] Forrer P, Schlottig F, Siegenthaler H, et al. J. Appl. Electrochem., 2000, 30: 533-541.
[6] Xu Hui, Qin Dong-Huan, Yang Zhi, et al. Mater. Chem. and Phys., 2003, 80: 524-528.
[7] Limmer S J, Seraji S, Wu Yun. Adv. Func. Mater., 2002, 1: 59-64.
[8] Zheng M J, Zhang L D, Li G H, et al. Chemical Physics Letters, 2002, 363: 123-128.
[9] Li Y, Cheng G S, Zhang L D. J. Mater. Res., 2000, 15 (11): 2305-2308.
[10] 苏轶坤, 王臻, 力虎林. 高等学校化学学报(Chem. J. Chinese Universities), 2002, 23 (5): 944-946.
[11] 周晓红, 赵秀琴. 安庆师范学院学报 (自然科学版)(Journal of Anqing Teachers College (Nature Science)), 2003, 9 (2): 4-6.
[12] 沈茹娟, 贾殿赠, 梁凯, 等. 无机化学学报(Chinese Journal of Inorganic Chemistry), 2000, 16 (6): 906-910.
[13] 彭忠东, 杨建红, 邓朝阳, 等. 中国有色金属学报(the Chinese Journal of Nonferrous Metals), 2000, 10 (4): 579-583.
[14] 刘建华, 孙杰, 李松梅, 等. 复合材料学报(Acta Matariae Compositae Sinica), 2003, 20 (6): 121-124.
[15] 陈尔凡, 田雅娟, 程远杰, 等. 高等学校化学学报(Chemical Journal of Chinese University), 2000, 21 (2): 172-176.
[16] 宋旭春, 徐铸德, 陈卫祥, 等(SONG Xu-Chun, et al). 无机?化学学报(Chinese Journal of Inorganic Chemistry), 2004, 20 (2): 186-190.
[17] 何顺爱, 周双喜, 张兰, 等. 桂林工学院学报(Journal of Guilin Institute of Technology), 2004, 24 (1): 80-83.
[18] Brinda B L, Peter K D, Charles R M. Chem. Mater., 1997, 9: 857-862.
[19] Hiheki M, Kenji F. Science, 1995, 268: 1466-1468.
[20] Hideki M, Haruki Y, Masahiro S, et al. Appl. Phys. Lett., 1997, 71 (19): 2770-2772.
[21] Brinda B L, Charles J P, Charles R M. Chem. Mater., 1997, 9: 2544-2550.