一维高导热C/C复合材料的制备研究

doi:10.3724/SP.J.1077.2013.13110

无机材料学报 ›› 2013, Vol. 28 ›› Issue (12): 1338-1344.DOI: 10.3724/SP.J.1077.2013.13110 CSTR: 32189.14.SP.J.1077.2013.13110

一维高导热C/C复合材料的制备研究

林剑锋¹, 袁观明¹, 李轩科¹, 董志军¹, 张江¹, 张中伟², 王俊山²

(1. 武汉科技大学化学工程与技术学院, 武汉430081; 2. 航天材料及工艺研究所, 北京100076)

收稿日期:2013-03-01 修回日期:2013-04-25 出版日期:2013-12-20 网络出版日期:2013-11-15
作者简介:林剑锋(1986-), 男, 硕士研究生. E-mail:linjianfeng20066@126.com
基金资助:
国家自然科学基金 (91016003, 51372177); 深圳市热管理重点实验室开放基金

Preparation of 1D C/C Composites with High Thermal Conductivity

LIN Jian-Feng¹, YUAN Guan-Ming¹, LI Xuan-Ke¹, DONG Zhi-Jun¹, ZHANG Jiang¹, ZHANG Zhong-Wei², WANG Jun-Shan²

(1. School of Chemical Engineering and Technology, Wuhan University of Science and Technology, Wuhan 430081, China; 2. Aerospace Research Institute of Materials and Processing Technology, Beijing 100076, China)

Received:2013-03-01 Revised:2013-04-25 Published:2013-12-20 Online:2013-11-15
About author:LIN Jian-Feng. E-mail:linjianfeng20066@126.com
Supported by:
National Natural Science Foundation of China (91016003, 51372177); Key Laboratory of Thermal Management and Materials of Shenzhen

摘要/Abstract

摘要： 以三种沥青作为基体前驱体, 实验室自制的AR中间相沥青基纤维为增强体, 通过500℃热压成型, 随后经炭化和石墨化处理制备出一维炭/炭(C/C)复合材料。研究了前驱体沥青种类和热处理温度对复合材料导热性能的影响, 并采用扫描电子显微镜和偏光显微镜对其石墨化样品的形貌和微观结构进行表征。结果表明; C/C复合材料在沿纤维轴向的室温热扩散系数和导热率均随热处理温度的升高而逐渐增大; 由AR沥青作为基体前驱体所制备的C/C复合材料具有更加明显的沿纤维轴向取向的石墨层状结构以及最好的导热性能, 其3000℃石墨化样品沿纤维轴向的室温热扩散系数和导热率分别达到594.5 mm²/s和734.4 W/(m·K)。

关键词: 一维高导热C/C复合材料, 热扩散系数, 导热率

Abstract: Three kinds of pitches were used as matrix precursors, the self-fabricated mesophase (AR) pitch-based carbon fibers were used as the reinforcing agent, one dimension (1D) carbon/carbon (C/C) composites were prepared by a hot-pressing molding method at about 500℃ and subsequent carbonization as well as graphitization treatments. The influence of precursor pitches and heat-treatment temperatures (HTTs) on the thermal conductive properties of the C/C composites were investigated. The morphology and microstructure of graphitized C/C composites were characterized by scanning electron microscope and polarized-light microscope. The results show that both of the thermal diffusivities and the thermal conductivities of C/C composites along the longitudinal direction of fibers gradually increase with HTT. The C/C composite prepared by using AR pitch as a matrix precursor possesses obvious graphite-like layer structure, exhibiting the highest thermal conductivity. The room-temperature thermal conductivity and thermal diffusivity of the C/C composite treated at 3000℃ along the longitudinal direction of fibers are 734.4 W/(m·K) and 594.5 mm²/s, respectively.

Key words: 1D C/C composite with high thermal conductivity, thermal diffusivity, thermal conductivity

中图分类号:

TB332

林剑锋, 袁观明, 李轩科, 董志军, 张江, 张中伟, 王俊山. 一维高导热C/C复合材料的制备研究[J]. 无机材料学报, 2013, 28(12): 1338-1344.

LIN Jian-Feng, YUAN Guan-Ming, LI Xuan-Ke, DONG Zhi-Jun, ZHANG Jiang, ZHANG Zhong-Wei, WANG Jun-Shan. Preparation of 1D C/C Composites with High Thermal Conductivity[J]. Journal of Inorganic Materials, 2013, 28(12): 1338-1344.

参考文献

[1] Luedtke A. Thermal management materials for high-performance application. Adv. Eng. Mater., 2004, 6(3): 142-144.

[2] Zweben C. High performance thermal management materials. Adv. Packaging, 2006, 15(2): 1-5.

[3] Gao X Q, Guo Q G, Liu L, et al. The study progress on carbon materials with high thermal conductivity. Journal of Functional Materials, 2006, 37(2): 173-177.

[4] 高晓晴. 高导热炭/炭复合材料的制备及其性能和结构的研究. 北京: 中国科学院研究生院博士论文, 2005.

[5] Ohno H. High PerformancePitch Based Carbon Fibers and Their Application. Verbundwerkstoffe: 17 Symposium Verbundwerkstoffe und Werkstoffverbunde, 2009: 265-269.

[6] Nysten B, Issi J P. Composites based on thermally hyperconductivecarbon fiber. Composites, 1990, 21(4): 339-343.

[7] Ting J M, Lake M L. Vapor-grown carbon-fiber reinforced carbon composites. Carbon, 1995, 33(5): 663-667.

[8] Ting J M, Lake M L, Dufrfy D R. Composites based on thermally hyper-conductive vapor grown carbon fiber. Journal of Materials Research, 1995, 10(6): 1478-1484.

[9] Yuan G M, Li X K, Dong Z J, et al. Preparation and characterization of highly oriented ribbon shape pitch-based carbon fibers. Journal of Inorganic Materials, 2011, 26(10): 1026-1030.

[10] Adams P M, Katzman H A, Rellick G S, et al. Characterization of high thermal conductivity carbon fibers and a self-reinforced graphite panel. Carbon, 1998, 36(3): 233-245.

[11] Nysten B, Issi J P, Barton R D, et al. Determination of lattice defects in carbon fibers by means of thermal-conductivity measurements. Phys. Rev. B, 1991, 44(5): 2142-2148.

[12] Heremans J, Beetz C P. Thermal conductivity and thermopower of vapor-grown graphite fibers. Physi. Rev. B, 1985, 32(4): 1981-1988.

[13] Edie D D. Pitch and mesophase fibers. Carbon fibers Filaments and Composites. Kluwer Academic Publishers, Dordrecht, Netherlands, 1990: 43-72.

[14] Edie D D, Fox N K, Barnett B C, et al. Melt-spun non-circular carbon fibers. Carbon, 1986, 24(4): 447-482.

[15] Endo M. Structure of mesophase pitch-based carbon fiber. Journal of Materials Science, 1988, 23(2): 598-605.

[16] Edie D D, Stoner E G. Effect of Microstructure and Shape on Carbon Fiber Properties. Carbon Materials and Composites. Noyes Publishing. 1992: 41-69.

[17] Blanco C, Appleyard S P, Rand B. Study of carbon fibers and carbon carbon composites by scanning thermal microscopy. Journal of Microscopy, 2002, 205(1): 21-32.

[18] Chen Y M, Ting J M. Ultra high thermal conductivity polymer composites. Carbon, 2002, 40(3): 359-362.

[19] Edie D D. The effect of processing on the structure and properties of carbon fibers. Carbon, 1988, 36(4): 345-362.

[20] Paiva M C, Bernardo C A, Nardin M. Mechanical surface and interfacial characterization of pitch and PAN-based carbon fibers. Carbon, 2000, 38(9): 1323-1337.

[21] Inagaki M, Shiraishi M, Nakamizo M et al. The evaluation of graphitization degree. Carbon Techniques, 1991(5): 38-43.

[22] He F, Yang Y G. Super thermal conductivity mesophase pitch-based carbon fibers. Hi-Tech Fiber & Application, 2003, 28(5): 28-31.

[23] Zhao J G, Li K Z, Li H J, et al. Research on the thermal conductivity of C/C composites. Acta Aeronautica et Astronautica Sinica, 2005, 26(3): 501-504.

[24] Manocha L M, Warrier A, Manocha S, et al. Thermophysical properties of densified pitch based carbon/carbon materials-I. Unidirectional composites. Carbon, 2006, 44(3): 480-487.

一维高导热C/C复合材料的制备研究

Preparation of 1D C/C Composites with High Thermal Conductivity

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 4

编辑推荐

Metrics

本文评价

[1]	张硕, 付前刚, 张佩, 费杰, 李伟. C/C多孔体的高温热处理对C/C-SiC复合材料摩擦磨损行为的影响[J]. 无机材料学报, 2023, 38(5): 561-568.
[2]	陈弘毅, 史迅, 陈立东, 仇鹏飞. Cu₂S相变过程中热扩散系数的精确测量和解析[J]. 无机材料学报, 2019, 34(10): 1041-1046.
[3]	王召兵,蔡岸,奚同庚,张庆礼,孙敦陆,殷绍唐. Nd^3+_:Gd₃Ga₅O₁₂晶体的热物理性能研究[J]. 无机材料学报, 2007, 22(1): 170-172.
[4]	谢华清,罗军,奚同庚,王锦昌,范世Qi,刘岩,吴清仁. Ca₂YO(BO₃)₃晶体的热物理性质研究[J]. 无机材料学报, 2002, 17(2): 225-229.