吡啶硫酮锌/蒙脱土的制备及其抗菌性能研究

doi:10.3724/SP.J.1077.2010.00512

无机材料学报 ›› 2010, Vol. 25 ›› Issue (5): 512-516.DOI: 10.3724/SP.J.1077.2010.00512 CSTR: 32189.14.SP.J.1077.2010.00512

吡啶硫酮锌/蒙脱土的制备及其抗菌性能研究

王云斌, 杨晋涛, 费正东, 陈枫, 钟明强

浙江工业大学化学工程与材料学院, 杭州 310014

收稿日期:2009-09-30 修回日期:2009-11-19 出版日期:2010-05-20 网络出版日期:2010-05-12

Preparation and Antibacterial Performance of Zinc Pyrithione/Montmorillonite

WANG Yun-Bin, YANG Jin-Tao, FEI Zheng-Dong, CHEN Feng, ZHONG Ming-Qiang

College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, China

Received:2009-09-30 Revised:2009-11-19 Published:2010-05-20 Online:2010-05-12

摘要/Abstract

摘要：

以载锌蒙脱土为前驱体, 在蒙脱土的层间, 引入吡啶硫酮阴离子, 原位制备了新型的吡啶硫酮锌/蒙脱土（ZPT/MMT）抗菌材料. 采用XRD、FT-IR、TG、DSC和UV-Vis DRS对材料的插层结构、耐光、耐热性能进行分析,结果表明, 蒙脱土层间的吡啶硫酮阴离子以吡啶硫酮锌的形式存在, 致使层间距d₀₀₁值由1.29nm增至1.85nm, 并且ZPT/MMT具有较好的耐光性和耐热性（热分解温度高于240℃）.抗菌试验结果表明, ZPT/MMT对大肠杆菌和金黄色葡萄球菌具有较好的抗菌活性.

关键词: 吡啶硫酮阴离子, 蒙脱土, 插层, 抗菌活性

Abstract:

A novel antibacterial composite, zinc pyrithione/montmorillonite(ZPT/MMT) was in situ prepared by introducing pyrithione anion into the galleries of zinc-exchanged montmorillonite. The results of XRD, FT-IR, TG, DSC and UV-Vis DRS show that pyrithione anion exists in the form of zinc pyrithione, resulting in an increase of basal spacing of montmorillonite (d₀₀₁ value) from 1.29nm to 1.85nm, and the ZPT/MMT has a favorable light and thermal stability (the decomposition temperature is above 240℃). Antibacterial assays indicate that ZPT/MMT has an excellent antibacterial activity against Gram-negative Escherichia coli and Gram-positive Staphylococcus aureus.

Key words: pyrithione anion, montmorillonite, intercalation, antibacterial activity

中图分类号:

TB34

王云斌, 杨晋涛, 费正东, 陈枫, 钟明强. 吡啶硫酮锌/蒙脱土的制备及其抗菌性能研究[J]. 无机材料学报, 2010, 25(5): 512-516.

WANG Yun-Bin, YANG Jin-Tao, FEI Zheng-Dong, CHEN Feng, ZHONG Ming-Qiang. Preparation and Antibacterial Performance of Zinc Pyrithione/Montmorillonite[J]. Journal of Inorganic Materials, 2010, 25(5): 512-516.

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吡啶硫酮锌/蒙脱土的制备及其抗菌性能研究

Preparation and Antibacterial Performance of Zinc Pyrithione/Montmorillonite

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