关键词: Al₂O₃/不锈钢微滤膜, 烧结应力, 过渡层, 共烧结

Abstract: Based on porous stainless-steel disks, three methods were used to fabricate microporous Al₂O₃/stainless-steel membranes by coating Al₂O₃ powder with a mean particle diameter size of 0.5 μm. The surface and cross-sectional morphologies were characterized by scanning electron microscople (SEM) and metallographic microscople, respectively. Pore size distribution of the Al₂O₃/stainless-steel membranes was measured by capillary flow method. The membrane adhesion was tested by means of ultrasonic shocking treatment. It is found that the problem of membrane peeling can be solved by introducing an intermediate layer of stainless-steel fine powder between the substrate and the alumina layer and then performing a co-sintering treatment. The microporous Al₂O₃/stainless-steel membranes with a thickness of 40-50 μm were successfully achieved. Such an intermediate layer not only helps to modify the substrate surface but also buffers the thermal expansion and sintering shrinkage stresses in the Al₂O₃ layer during the heat-treatment. Moreover, it can also bond the Al₂O₃ layer onto the substrate and therefore enhances the membrane adhesion. The co-sintering approach introduced in this study simplifies fabrication process and saves energy. During co-sintering period the sintering, temperature plays a key role in membrane adhesion and pore size distribution. After being co-sintered at 1100, 1150, 1200 and 1250℃, the mean pore sizes of the Al₂O₃/stainless-steel membranes are 0.2, 0.3, 0.5 and 3.9 μm, respectively, and the pure water fluxes of the membranes are 3.8, 4.1, 6.9 and 20.5 m³/(m²·h·bar), respectively.

Key words: microporous Al₂O₃/stainless-steel membrane, sintering stress, intermediate layer, co-sintering