不同晶态纳米Fe2O3的盐控合成

doi:10.3724/SP.J.1077.2010.09879

无机材料学报 ›› 2010, Vol. 25 ›› Issue (7): 780-784.DOI: 10.3724/SP.J.1077.2010.09879 CSTR: 32189.14.SP.J.1077.2010.09879

• 研究快报 • 上一篇

不同晶态纳米Fe₂O₃的盐控合成

宋军¹, 马振叶^1,2, 李成¹, 吴如军²

(1. 南京工业大学材料化学工程国家重点实验室, 南京210009; 2. 南京师范大学化学与环境科学学院, 南京210097)

收稿日期:2009-12-20 修回日期:2010-03-02 出版日期:2010-07-20 网络出版日期:2010-06-10
基金资助:
National Natural Science Foundation of China (50702025); Natural Science Foundation of Jiangsu province (BK2009473); Natural Science Foundation of the Jiangsu Higher Education Institutions of China (08KJB430009); Youth Foundation of Nanjing University of Technology (39071014); Foundetion of State Key Laboratory of Materials-Oriented Chemical Engineering (KL09-13)

Synthesis of Ferric Oxide Nanoparticles with Controllable Crystal Phases by Salt-assisted Combustion Method

SONG Jun¹, MA Zhen-Ye^1,2, LI Cheng¹, WU Ru-Jun²

(1. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China,2. College of Chemistry and Environment Science, Nanjing Normal University, Nanjing 210097, China)

Received:2009-12-20 Revised:2010-03-02 Published:2010-07-20 Online:2010-06-10
Supported by:
National Natural Science Foundation of China (50702025); Natural Science Foundation of Jiangsu province (BK2009473); Natural Science Foundation of the Jiangsu Higher Education Institutions of China (08KJB430009); Youth Foundation of Nanjing University of Technology (39071014); Foundetion of State Key Laboratory of Materials-Oriented Chemical Engineering (KL09-13)

摘要/Abstract

摘要：

以Fe(NO₃)₃·9H₂O为氧化剂, 聚乙二醇(PEG2000)为燃料, 采用KCl盐助燃烧法制备了不同晶态的纳米Fe₂O₃粒子, 并用HRTEM、XRD、LRS和BET对其形貌和结构进行了表征. 结果表明, 纳米Fe₂O₃的晶态(包括纯α-Fe₂O₃、纯γ-Fe₂O₃以及α-Fe₂O₃和γ-Fe₂O₃混晶)可以通过调整KCl/NO^3-的摩尔比来控制合成. 将惰性盐KCl引入到燃烧反应中, 可以制得粒径小、比表面大、均匀分散的γ-Fe₂O₃纳米粒子. 另外, 本实验也探索了惰性盐KCl的作用机理.

关键词: 纳米Fe₂O₃, 盐助燃烧法, 晶态

Abstract:

The salt-assisted combustion method was applied in synthesis of Fe₂O₃ nanoparticles by using Fe(NO₃)₃·9H₂O, polyethylene glycol (PEG2000) and KCl as oxidant, fuel and salt, respectively. The products were characterized by HRTEM, XRD, LRS and N₂adsorption. It is found that the crystal phase (including α-Fe₂O₃, γ-Fe₂O₃ and the mixed phases of α-Fe₂O₃ and γ-Fe₂O₃) of Fe₂O₃ nanoparticles can be adjusted by changing the KCl/NO^3- molar ratio. Addition of soluble inert KCl in the redox mixture solution for combustion synthesis results in the formation of well-dispersed γ-Fe₂O₃nanoparticles and a drastic increase in the specific surface area from 21.96 to 102.35 m²/g. A mechanism was proposed to illustrate the possible formation process of different crystal phase nanoparticles with different character.

Key words: Fe₂O₃ nanoparticles, salt-assisted combustion, crystal phase

中图分类号:

TQ138

宋军, 马振叶, 李成, 吴如军. 不同晶态纳米Fe₂O₃的盐控合成[J]. 无机材料学报, 2010, 25(7): 780-784.

SONG Jun, MA Zhen-Ye, LI Cheng, WU Ru-Jun. Synthesis of Ferric Oxide Nanoparticles with Controllable Crystal Phases by Salt-assisted Combustion Method[J]. Journal of Inorganic Materials, 2010, 25(7): 780-784.

参考文献

[1]ZHENG Yuan-hui, CHENG Yao, WANG Yuan-sheng, et al. Quasicubic α-Fe2O3 nanoparticles with excellent catalytic performance. The Journal of Physical Chemistry B, 2006, 110(7): 3093-3097.
[2]Bailey J K, Brinker C J, Mecartney M L. Growth mechanisms of iron oxide particles of differing morphologies from the forced hydrolysis of ferric chloride solutions. Journal of Colloid and Interface Science, 1993, 157(1): 1-13.
[3]Hamada S, Matijevic E. Preparation of uniform cubic hematite particles by hydrolysis of ferric chloride in alcohol-water solutions. Journal of Colloid and Interface Science, 1981, 84(1): 274-277.
[4]Hamada S, Matijevic E. Formation of monodispersed colloidal cubic hematite particles in ethanol + water solutions. Journal of the Chemical Society. Faraday Transactions, 1982, 178: 2147-2156.
[5]Ozaki M, Kratohvil S, Matijevic E. Formation of monodispersed spindle-type hematite particles. Journal of Colloid and Interface Science, 1984, 102(1): 146-151.
[6]Park G S, Shino D, Waseda Y, et al. Internal structure analysis of monodispersed pseudocubic hematite particles by electron microscopy. Journal of Colloid and Interface Science, 1996, 177(1): 198-207.
[7]Sugimoto T, Muramatsu A, Sakata K, et al. Characterization of hematite particles of different shapes. Journal of Colloid and Interface Science, 1993, 158(2): 420-428.
[8]Sugimoto T, Sakata K. Preparation of monodisperse pseudocubic α-Fe₂O₃particles from condensed ferric hydroxide gel. Journal of Colloid and Interface Science, 1992, 152(2): 587-590.
[9]Sugimoto T, Sakata K, Muramatsu A. Formation mechanism of monodisperse pseudocubic α-Fe₂O₃ particles from condensed ferric hydroxide gel. Journal of Colloid and Interface Science, 1993, 159(2): 372-382.
[10]KAN Shi-hai, YU San, PENG Xiao-gang, et al. Formation process of nanometer-sized cubic ferric oxide single crystals. Journal of Colloid and Interface Science, 1996, 178(2): 673-680.
[11]KAN Shi-hai, ZHANG Xin-tong, YU San, et al. Synthesis of uniform ferric oxide particles from deionized colloids. Journal of Colloid and Interface Science, 1997, 191(2): 503-509.
[12]Kandori K, Ishikawa T. TPD-MS-TG study of hematite particles produced by the forced hydrolysis reaction. Physical Chemistry Chemical Physics, 2001(3): 2949-2954.
[13]Kandori K, Okamoto N, Ishikawa T. Preparation of nanoporous micrometer-scale hematite particles by a forced hydrolysis reaction in the presence of polyethylene glycol. Langmuir, 2002, 18(7): 2895-2900.
[14]Kandori K, Ishikawa T. Preparation and microstructural studies on hydrothermally prepared hematite. Journal of Colloid and Interface Science, 2004, 272(1): 246-248.
[15]Konishi Y, Kawamura T, Asai S. Microstructural and magnetic studies on hydrothermally prepared hematite. Metallurgical and Materials Transactions B, 1994, 25(2): 165-170.
[16]Sahu K K, Rath C, Mishra N C, et al. Microstructural and magnetic studies on hydrothermally prepared hematite. Journal of Colloid and Interface Science, 1997, 185(2): 402-410.
[17]SHANG Yu-xing, Weert G V. Iron control in nitrate hydrometallurgy by autoclave hydrolysis of iron (III) nitrate. Hydrometallurgy, 1993, 33(3): 273-290.
[18]Hiroshi Shiho, Nobuo Kawahashi. Iron compounds as coatings on polystyrene latex and as hollow spheres. Journal of Colloid and Interface Science, 2000, 226(1): 91-97.
[19]MA Zhen-ye, LI Feng-sheng, CUI Ping, et al. Preparation of nanometer-sized Fe₂O₃ and its catalytic performance for ammonium perchlorate decomposition. Chinese Journal of Catalysis, 2003, 24(10): 795-798. (In Chinese)
[20]Basavaraja S, Vijayanand H, Venkataraman A. Characterization of γ-Fe₂O₃nanoparticles synthesized through self-propagating combustion route. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 2007, 37(6): 409-412.
[21]CHEN Wei-Fan, LI Feng-Sheng, YU Ji-Yi. Combustion synthesis and characterization of nanocrystalline CeO₂-based powders via ethylene glycol-nitrate process. Materials Letters, 2006, 60(1): 57-62.
[22]Chick L A, Maupin G D, Pederson L R. Glycine-nitrate synthesis of a ceramic-metal composite. Nanostructured Materials, 1994, 4(5): 603-615.
[23]CHEN Wei-Fan, LI Feng-Sheng, YU Ji-Yi, et al. Novel salt-assisted combustion synthesis of high surface area ceria nanopowders by an ethylene glycol-nitrate combustion process. Journal of Rare Earths, 2006, 24(4): 434-439.
[24]JIAO Huan, WEI Ling-qi, ZHANG Na, et al. Melting salt assisted sol-gel synthesis of blue phosphor Y₂SiO₅: Ce. Journal of the European Ceramic Society, 2007, 27(1): 185-189.
[25]LI Li, SHI Li-yi, CAO Shao-mei, et al. LiNO₃molten salt assisted synthesis of spherical nano-sized YSZ powders in a reverse micro- emulsion system. Materials Letters, 2008, 62(12/13): 1909-1912.
[26]ZHANG Xiao-juan, JIANG Wei, SONG Dan, et al. Salt-assisted combustion synthesis of highly dispersed super paramagnetic CoFe₂O₄ nanoparticles. Journal of Alloys and Compounds, 2009, 475(1/2): L34-L37.
[27]Varadwaj K S K, Panigrahi M K, Ghose J. Effect of capping and particle size on Raman laser-induced degradation of γ-Fe₂O₃ nanoparticles. Journal of Solid State Chemistry, 2004, 117(11): 4286-4292.
[28]Xia B, Lenggoro I W, Okuyama K. Novel route to nanoparticle synthesis by salt-assisted aerosol decomposition. Advanced Materials, 2001, 13(20): 1579-1582.
[29]Sena D, Deb P, Mazumder S, et al. Microstructural investigations of ferrite nanoparticles prepared by non-aqueous precipitation route. Materials Research Bulletin, 2000, 35(8): 1243-1250.
[30]CHEN Wei-fan, LI Feng-sheng, Yu Ji-yi, et al. Rapid synthesis of mesoporous ceria–zirconia solid solutions via a novel salt-assisted combustion process. Materials Research Bulletin, 2006, 41(12): 2318-2324.
[31]LI Yong-xiu, CHEN Wei-fan, ZHOU Xue-zhen, et al. Synthesis of CeO₂ nanoparticles by mechanochemical processing and the inhibiting action of NaCl on particle agglomeration. Materials Letters, 2005, 59(1): 48-52.

不同晶态纳米Fe₂O₃的盐控合成

Synthesis of Ferric Oxide Nanoparticles with Controllable Crystal Phases by Salt-assisted Combustion Method

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 11

编辑推荐

Metrics

本文评价

[1]	王婧, 崔春月, 田侠, 张雪, 王颖, 辛言君. 非晶态Pd-P/聚吡咯/泡沫Ni电极对五氯苯酚的催化还原[J]. 无机材料学报, 2020, 35(10): 1157-1162.
[2]	张涛, 徐智谋, 武兴会, 刘斌昺. 室温下制备非晶ZnO薄膜及其电阻开关特性研究[J]. 无机材料学报, 2014, 29(11): 1161-1166.
[3]	于方丽, 白宇, 秦毅, 岳冬, 罗才军, 杨建锋. PECVD下基底温度对SiC薄膜形态、成分及生长速度的影响[J]. 无机材料学报, 2013, 28(2): 201-206.
[4]	卢国锋, 乔生儒, 张程煜, 焦更生. 化学气相沉积法制备的块体Si-C-N陶瓷的热行为[J]. 无机材料学报, 2011, 26(7): 779-784.
[5]	刘元刚,唐致远,徐强,李昌盛. Al代α-Ni(OH)₂的高温电化学性能[J]. 无机材料学报, 2008, 23(2): 291-294.
[6]	邸永江,江建军,何华辉. 不同直径玻璃包覆非晶微丝的制备及其磁性能[J]. 无机材料学报, 2007, 22(6): 1187-1191.
[7]	王之建,贾卫民. 非晶ZnO八面体笼式结构研究[J]. 无机材料学报, 2005, 20(4): 827-830.
[8]	乔玉卿,赵敏寿,朱新坚,曹广益. 机械合金化制备Mg-Ni合金氢化物电极材料的研究进展[J]. 无机材料学报, 2005, 20(1): 33-41.
[9]	史鸿运,邓洁,张云黔,董俊. 电沉积法制备钴与镧、铈的非晶态合金及其晶化动力学研究[J]. 无机材料学报, 2002, 17(6): 1124-1128.
[10]	蔡红,王贞尧,张干诚,吴梅梅,黄毓敏. 石英微粉表面结构对硬硅钙石中空二次粒子形貌的影响[J]. 无机材料学报, 1999, 14(3): 431-436.
[11]	古堂生,林光明. 非晶态和晶态纳米氧化铝粉的相变与红外光谱[J]. 无机材料学报, 1997, 12(6): 840-844.